山东省S波段与C波段天气雷达回波强度的对比分析

山东省济南市的S波段天气雷达与泰山山顶处的C波段雷达相距67 km。为了定量分析两部雷达扫描观测的回波强度在不同个例中的差异程度,从2007—2010年两部雷达观测中选出10次有明显回波的个例,对3个高度的CAPPI及相同观测区域的格点化回波强度资料进行对比分析。结果表明:10次个例的整体对比中,两部雷达在3个高度(2、3、4 km)的CAPPI回波强度资料的概率密度有较好的相似性;两部雷达回波强度均值随着选取高度增加而增大,每个高度上S波段均值较C波段大2 dBz左右。其中,6次降雨个例3 km的CAPPI资料对比中,一次平均强度小于30 dBz的降水过程,且强回波所占比例较小,C波段雷达衰减小,两部雷达测量回波强度一致性最好;其余5次过程中,S波段雷达测量的平均回波强度值均在30 dBz以上,且强回波所占比例较多,C波段由于衰减等原因,两部雷达的测量存在不同程度的差异。     

Effects of common groundwater ions on chromate removal by magnetite: importance of chromate adsorption

Background

Reductive precipitation of hexavalent chromium (Cr(VI)) with magnetite is a well-known Cr(VI) remediation method to improve water quality. The rapid (<a few hr) reduction of soluble Cr(VI) to insoluble Cr(III) species by Fe(II) in magnetite has been the primary focus of the Cr(VI) removal process in the past. However, the contribution of simultaneous Cr(VI) adsorption processes in aged magnetite has been largely ignored, leaving uncertainties in evaluating the application of in situ Cr remediation technologies for aqueous systems. In this study, effects of common groundwater ions (i.e., nitrate and sulfate) on Cr(VI) sorption to magnetite were investigated using batch geochemical experiments in conjunction with X-ray absorption spectroscopy.

Results

In both nitrate and sulfate electrolytes, batch sorption experiments showed that Cr(VI) sorption decreases with increasing pH from 4 to 8. In this pH range, Cr(VI) sorption decreased with increasing ionic strength of sulfate from 0.01 to 0.1 M whereas nitrate concentrations did not alter the Cr(VI) sorption behavior. This indicates the background electrolyte specific Cr(VI) sorption process in magnetite. Under the same ionic strength, Cr(VI) removal in sulfate containing solutions was greater than that in nitrate solutions. This is because the oxidation of Fe(II) by nitrate is more thermodynamically favorable than by sulfate, leaving less reduction capacity of magnetite to reduce Cr(VI) in the nitrate media. X-ray absorption spectroscopy analysis supports the macroscopic evidence that more than 75 % of total Cr on the magnetite surfaces was adsorbed Cr(VI) species after 48 h.

Conclusion

This experimental geochemical study showed that the adsorption process of Cr(VI) anions was as important as the reductive precipitation of Cr(III) in describing the removal of Cr(VI) by magnetite, and these interfacial adsorption processes could be impacted by common groundwater ions like sulfate and nitrate. The results of this study highlight new information about the large quantity of adsorbed Cr(VI) surface complexes at the magnetite-water interface. It has implications for predicting the long-term stability of Cr at the magnetite-water interface.

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Graphical abstract Effects of background anions (sulfate and nitrate) on the Cr(VI) surface coverage at the magnetite-waterinterface at pH 4 and 9

     

Geochemistry of eclogites from the Dabie–Sulu terrane, eastern China: New insights into protoliths and trace element behaviour during UHP metamorphism

The major and trace element compositions of nine eclogites from the Dabie–Sulu ultrahigh pressure (UHP) metamorphic terrane in eastern China were determined for both whole rock and the main constituent minerals, garnet and clinopyroxene. The results indicate that the eclogite protoliths originated from a basaltic magma, which formed in a continental setting as shown by isotopic and immobile element data. Based on the garnet REE characteristics, the eclogites can be roughly divided into two groups. Group 1 has LREE enrichment with no Eu anomaly for whole rock, and smooth LREE depletion but HREE enrichment pattern for garnet, whereas group 2 shows a depletion of LREE with a pronounced positive Eu anomaly and flat HREE pattern for both whole rock and garnet. From these features, we suggest that the protoliths for group 2 are Fe–Ti–gabbros with relatively high cumulus plagioclase and Fe–Ti oxide, whereas the group 1 eclogites are probably from basalts. Therefore, the unusual garnet REE pattern observed in group 2 can be considered as an important signature for identifying gabbro protoliths for eclogites. The identification of gabbro protoliths from the eclogites in the Dabie–Sulu terrane provides evidence for Neoproterozoic rift magmatism in the northern margin of the Yangtze craton. During ultrahigh pressure metamorphism in the Dabie–Sulu terrane, LILEs (including Ba, Rb, Th, U, K) had high mobility, but REEs and HFSEs were immobile, and trace element distribution equilibrium was approached between garnet and clinopyroxene. An estimate of mass balance indicates that garnet and clinopyroxene host the majority of HREEs and Y, and clinopyroxene is a significant host for Sr, but minor and accessory minerals predominantly account for LREEs, Th, U, and Zr.     

高温干旱复合胁迫对夏玉米生长发育及产量形成的影响

为探究不同生育期不同程度复合高温干旱胁迫对夏玉米生长发育及产量形成的影响,以夏玉米品种“登海685”为试验材料,于2022年6—9月在衡水农业气象试验站开展夏玉米高温干旱田间胁迫试验。在拔节—抽雄和抽雄—乳熟两个生育期分别进行试验。干旱处理设置为轻旱和重旱两个水平。通过增温箱分别在两个生育期进行高温处理,这样每个生育期有轻旱、轻旱高温、重旱、重旱高温四种胁迫处理,各处理有两个重复。此外设置全生育期增温无旱处理和对照组,共10个处理,对株高、叶面积、干物质重及产量构成要素进行观测。结果显示,夏玉米全生育期增温会增加株高和叶面积,但会降低干物质积累导致产量下降;夏玉米在拔节—抽雄和抽雄—乳熟期发生严重的干旱可显著降低株高,但干旱复合高温后影响程度变弱;两个时期发生高温复合干旱与单一干旱相比对玉米叶面积的降低程度更明显;两个时期发生高温干旱胁迫对玉米植株干物质的降低主要由果实干物质降低带来;这两个阶段高温干旱胁迫均会影响产量形成,但拔节—抽雄期干旱对产量形成的影响更大,而抽雄—乳熟期高温的影响更大。     

1961—2020年长江下游地区夏季降水趋势分析

近几十年来长江下游地区夏季(6—8月)降水量呈现出显著上升的变化趋势,利用1961—2020年夏季台站降水资料,通过降水项分解法,定量分析了该降水趋势的可能影响因素。结果表明:1)长江下游地区夏季降水的上升趋势主要是由日降水量显著增加造成,而日降水量显著增加主要与整层水汽垂直梯度增大和垂直上升速度增强所导致的降水增加有关;2)长江下游地区对流层低层大气温度因地面升温的加热作用而显著上升,高层大气温度受亚太振荡相位正转负的影响而下降,使得高、低层大气的温差变大,低层大气比湿升高、高层大气比湿降低,导致整层水汽垂直梯度增加,为局地降水的增强提供了充沛的水汽条件;低层大气异常辐合加之显著增长的不稳定能量为垂直上升运动的增强和对流性降水的增加提供了有利的动力和热力条件,从而造成了长江下游地区夏季降水的显著上升趋势。     

通痹颗粒治疗类风湿关节炎临床疗效及对氧化应激的影响

目的：观察通痹颗粒治疗气血亏虚、痰瘀互结型类风湿关节炎（RA）的临床疗效及对氧化应激的影响。方法：将60 例气血亏虚、痰瘀互结型RA患者随机分为治疗组和对照组,每组各30 例。对照组予甲氨蝶呤联合美洛昔康治疗,治疗组在对照组基础上加通痹颗粒治疗,2组疗程均为8周。比较2组综合疗效,中医证候积分,血清学指标［血沉（ESR）、C反应蛋白（CRP）］水平,氧化应激指标［超氧化物歧化酶（SOD）、丙二醛（MDA）］水平及不良反应。结果：总有效率治疗组为83.33%（25/30）,对照组为60.00%（18/30）,组间比较,差异有统计学意义（P<0.05）;治疗后2组中医证候积分与ESR、CRP、MDA水平均较治疗前降低,SOD水平较治疗前升高,且治疗组改善程度优于对照组（P<0.05或P<0.01）。结论：通痹颗粒可改善气血亏虚、痰瘀互结型RA患者的临床症状、体征、实验室指标,并能调节氧化应激状态,且不良反应少,值得临床推广应用。     

自然资源定义、分类，观测监测及其在国土规划治理中的应用

【研究目的】为摸清中国资源家底、认清资源变化规律、管好国土用途，解决现有自然资源内涵不一、分类上存在差异、在数据获取上不统一、资源管理分属不同部门导致的资源在空间管理上交叉重叠等问题。【研究方法】本文采用文献综述法对自然资源的定义、分类及有关资源观测监测指标的相关文献进行梳理。【研究结果】（1）明确了观测监测体系下的自然资源是自然状态或未被加工的状态下通过生产能够产生价值的资源，可将其分为气候资源、地表覆盖资源及地下水资源3类开展研究；（2）总结得到自然资源综合观测与监测的对象、内容及观测方法；（3）分析自然资源观测监测在资源间及资源与环境间、资源资产管理、生态环境修复上的具体作用。【结论】文章最后指出自然资源观测监测是研究资源间、资源与环境间作用，资源资产管理以及生态环境修复中不可缺少的技术手段。创新点：（1）明确了自然资源的定义，解决自然资源在部门管理上、分类上以及数据获取上不统一的问题；（2）分析自然资源观测与监测的内容和指标，结合系统调查、观测实验、预测模拟、监测评价“四位一体”的探测技术，有效掌握自然资源家底、进行资源资产管理，研究资源间、资源与环境的相互关系，在国土规划治理中发挥作用。     

黑海西北部多瑙河峡谷北侧陆坡沉积特征及其与古气候的关系

【研究目的】在末次冰期，全球气候变化以千年尺度的快速、大幅度温度波动旋回为特征，这种波动变化在两极冰芯、深海沉积、中国黄土和洞穴石笋等诸多地质样品中均有记录。黑海位于北大西洋与东亚季风区过渡带，具有极有代表性的沉积记录。本文旨在通过对黑海沉积序列的研究，建立起其区域环境变化与北大西洋及东亚季风气候域气候变化的联系。【研究方法】研究对取自黑海西北部罗马尼亚陆坡区多瑙河峡谷北侧GAS-CS12钻孔的长22.0 m的岩芯样品，进行了粒度、矿物成分、主量元素、有机碳、总氮及碳氮同位素等分析。【研究结果】揭示出该段岩芯沉积于末次冰期中后期“Neoeuxine”湖相阶段，可划分为5个沉积单元，对应于北大西洋H4、H3、H1气候变化事件、末次冰盛期（LGM）及Bolling-Allerod气候变暖事件。【结论】建立起了其沉积序列及区域环境变化与北大西洋及东亚季风气候域气候变化的联系，印证了末次冰期千年尺度的气候变化事件在北大西洋、东亚季风区及两者过渡带上具有高度的一致性。创新点：建立了黑海西北沉积序列与区域环境变化的关系；补充了北大西洋与东亚季风区两者过渡带上气候波动事件的可靠时标。