Effects of alkali and alkaline-earth cations on the high-pressure sound velocities of aluminosilicate glasses

Physics and Chemistry of Minerals - A black tourmaline sample from Seagull batholith (Yukon Territory, Canada) was established to be a schorl with concentrations of Fe2+ among the highest currently...     

The Application of GIS in Education Administration: Protecting Students from Hazardous Roads

Though enrolment by proximity is an official educational policy in Iran, the lack of clearly defined school attendance areas has resulted in an informal open enrolment system where parents may choose public schools outside their residential areas. Two major consequences of parental choice are longer commutes to schools and increased use of motor vehicle transport. To delineate school attendance areas for public female junior high schools in the city of Rasht in Northern Iran, this research used the multiplicatively weighted Voronoi diagram (MWVD) technique to construct school attendance areas. The approach was shown to be useful in developing countries like Iran where accident fatalities are not only disproportionately high but the public school system lacks sufficient educational diversity to offset the societal costs of opting out of neighbourhood schools. A GIS-based specialist package was used for constructing the proposed school attendance areas. Given the MWVD utility in demarcating spaces so that all journeys within them are closest to a chosen point, the research concluded that proposed school attendance areas can result in shorter and more convenient commutes on foot for students. This can eliminate the need to travel by vehicle for the overwhelming majority of students and thus make their journeys more convenient and safer.     

A GIS Approach to Estimation of Building Population for Micro-spatial Analysis

Population data used in GIS analyses is generally assumed to be homogeneous and planar (i.e. census tracts, townships or prefectures) due to the public unavailability of building population data. However, information on building population is required for micro-spatial analysis for improved disaster management and emergency preparedness, public facility management for urban planning, consumer and retail market analysis, environment and public health programs and other demographic studies. This article discusses a GIS approach using the Areametric and Volumetric methods for estimating building population based on census tracts and building footprint datasets. The estimated results were evaluated using actual building population data by visual, statistical and spatial means, and validated for use in micro-spatial analysis. We have also implemented a standalone GIS tool (known as 'PopShape GIS') for generating new building footprint with population attribute information based on user-defined criteria.     

Transport of nutrients and organic matter in a mangrove swamp

Field observations of the tidal transport of nutrients and organic matter in a mangrove swamp on Ishigaki Island, Okinawa, Japan revealed that groundwater flow from the swamp plays a significant role in increasing concentration of dissolved inorganic phosphorous and organic matter in a major channel. In contrast, dissolved inorganic nitrogen is transported from the mangrove swamps via surface water flow in the small channels of the swamp.     

The Southern Annular Mode and opposite-phased Basin Mode of the Southern Ocean circulation

Over the Southern Ocean the dominant modes of the atmospheric field are known as the Southern Annular Mode (SAM) or Antarctic Oscillation, and the Pacific South American (PSA) pattern. Statistical analysis of sea surface wind (SSW) from satellite observation revealed two leading modes of SAM-like and PSA patterns. In the high latitudes, the SAM-like pattern of the SSW had a large amplitude over the Bellingshausen Basin and Australian-Antarctic Basin, with opposite phase between the two basins. On the intraseasonal time scale, large-scale sea surface height (SSH) also had notable variability, showing a basin-scale anti-phase mode over the two basins. To explain the response of oceanic variations to these atmospheric modes, we analyzed the relationship between the dominant modes of wind stress and large-scale SSH on the intraseasonal time scale. The SAM-like pattern of wind stress was correlated with the SSH variation over the two basins. The SSH basin mode was most simply explained by a simple barotropic response to the SAM-like mode of wind stress, with the curl of opposite phase between the two basins. We conclude that the zonal asymmetry of the wind field of the SAM plays an important role in driving the antiphase SSH basin modes.     

《卫生宝鉴》中治疗脾胃病方剂用药规律

目的：基于数据挖掘分析《卫生宝鉴》中治疗脾胃病方剂的用药规律。方法：运用中医传承辅助平台（TCMISS）V2.5,采用频次统计、关联规则和聚类分析等数据挖掘方法,对《卫生宝鉴》中所载脾胃病的用药规律进行分析。结果：共收集处方151首,中药168味。频次≥17次的中药有21味,排前5位的依次是陈皮、白术、炙甘草、木香、干姜;温性中药使用频次最高,其次是寒性、平性中药;辛味药出现最多,其次是苦味、甘味药;排前5位的中药归经依次是脾、胃、肺、大肠、心经;频次≥14次的中药组合24个,对药物组合进行关联规则分析得到中药组合17个;聚类分析得到新方聚类的中药组合5组,对应新方组合5组。结论：通过中医传承辅助平台分析得出,《卫生宝鉴》中所载治疗脾胃病的处方注重甘辛温补、健脾消滞,慎用苦寒药,该研究结果可为临床治疗脾胃病开发新药物提供一定的参考     

Isotope systematics of Li, Sr, Nd, and volatiles in Indian Ocean MORBs of the Rodrigues Triple Junction: Constraints on the origin of the DUPAL anomaly

The DUPAL anomaly, a radiogenic isotope anomaly discovered in the Indian Ocean mantle, has been interpreted as due to a large-scale mantle heterogeneity. To provide new constraints on the DUPAL origin, we analyzed isotope ratios of Li, Sr, and Nd in fresh N-MORB glasses recovered from the Rodrigues Triple Junction in the Indian Ocean, and from the North Atlantic. The Li isotopic compositions of the Indian Ocean DUPAL N-MORBs were comparable to those of the North Atlantic non-DUPAL N-MORBs. The source of the DUPAL signature in Indian Ocean MORBs and the E-MORB-type enriched mantle source have quite different Li isotopic compositions. The ¹⁴³Nd/¹⁴⁴Nd values of both sources are significantly lower than those of the North Atlantic N-MORBs. The δ⁷Li values of most oceanic island basalts with similar low ¹⁴³Nd/¹⁴⁴Nd signatures are also higher than those of the North Atlantic N-MORBs, except for several Koolau lavas. The Li isotope results support the recent proposal that significant amounts of recycled lower continental crust might produce the radiogenic isotope signatures of the Indian Ocean DUPAL source.     

Uranyl adsorption and surface speciation at the imogolite-water interface: Self-consistent spectroscopic and surface complexation models

Macro- and molecular-scale knowledge of uranyl (U(VI)) partitioning reactions with soil/sediment mineral components is important in predicting U(VI) transport processes in the vadose zone and aquifers. In this study, U(VI) reactivity and surface speciation on a poorly crystalline aluminosilicate mineral, synthetic imogolite, were investigated using batch adsorption experiments, X-ray absorption spectroscopy (XAS), and surface complexation modeling. U(VI) uptake on imogolite surfaces was greatest at pH ∼7-8 (I = 0.1 M NaNO₃ solution, suspension density = 0.4 g/L [U(VI)]_i = 0.01-30 μM, equilibration with air). Uranyl uptake decreased with increasing sodium nitrate concentration in the range from 0.02 to 0.5 M. XAS analyses show that two U(VI) inner-sphere (bidentate mononuclear coordination on outer-wall aluminol groups) and one outer-sphere surface species are present on the imogolite surface, and the distribution of the surface species is pH dependent. At pH 8.8, bis-carbonato inner-sphere and tris-carbonato outer-sphere surface species are present. At pH 7, bis- and non-carbonato inner-sphere surface species co-exist, and the fraction of bis-carbonato species increases slightly with increasing I (0.1-0.5 M). At pH 5.3, U(VI) non-carbonato bidentate mononuclear surface species predominate (69%). A triple layer surface complexation model was developed with surface species that are consistent with the XAS analyses and macroscopic adsorption data. The proton stoichiometry of surface reactions was determined from both the pH dependence of U(VI) adsorption data in pH regions of surface species predominance and from bond-valence calculations. The bis-carbonato species required a distribution of surface charge between the surface and β charge planes in order to be consistent with both the spectroscopic and macroscopic adsorption data. This research indicates that U(VI)-carbonato ternary species on poorly crystalline aluminosilicate mineral surfaces may be important in controlling U(VI) mobility in low-temperature geochemical environments over a wide pH range (∼5-9), even at the partial pressure of carbon dioxide of ambient air (p_CO2 = 10^−3.45 atm).     

Rocket observation of energy spectrum of diffuse hard X-rays

The energy spectrum of diffuse hard X-rays measured in the range 10–40 keV shows a rather sharp change of slope. The logarithmic derivative of the spectrum changes around 20–30 keV by the increment significantly greater than 0.5 within an interval smaller than 50 keV.