A catalytic oxidation method for the determination of total nitrogen dissolved in seawater

A detailed examination of a high-temperature catalytic oxidation method for liquid samples in the analysis of total nitrogen dissolved in seawater is reported. The nitrogenous compounds in liquid samples are oxidized on a platinum catalyzer at 680°C under oxygen atmosphere and the generated NO₂ is absorbed into a chromogenic reagent, followed by a spectrophotometric determination. The results of this method are much higher than those of wet oxidation methods. Molecular size dependency of the results clearly indicates that the above discrepancy is caused by the low oxidation capacity of the wet oxidation method against high-polymer organic matter dissolved in seawater. The results revealed that the concentration of total nitrogen in seawater is nearly constant from surface to bottom, ranging from 30 to 40 μM 1^?1, which organic nitrogen concentration higher in the surface layer, and a rapid decrease with depth. An examination of molecular size distribution indicates that the concentration of high-polymer organic nitrogen decreases rapidly from surface to deeper layers, with molecular sizes ranging from 5 × 10³ to 3 × 10⁴. Because of the well-defined principle of the oxidation process, its reliability, ease of sample handling and of analytical procedure on board or in the land laboratory, the present method is much more suitable for the marine analytical chemistry of total and organic nitrogen than the other previous methods.     

A 100 m laser strainmeter system installed in a 1 km deep tunnel at Kamioka, Gifu, Japan

We have installed a laser strainmeter system in a deep tunnel about 1,000 m below the ground surface at Kamioka, Gifu, Japan. The system consists of three types of independent interferometers: (1) an EW linear strainmeter of the Michelson type with unequal arms, (2) an NS-EW differential strainmeter of the Michelson type with equal arms and (3) a NS absolute strainmeter of the Fabry–Perot type. These are configured in L-shaped vacuum pipes, each of which has a length of 100 m. (1) and (2) are highly sensitive (order of 10⁻¹³ strain) and have wide dynamical range (10⁻¹³–10⁻⁶). Observations with strainmeters (1) and (2) started on June 11, 2003. (3) is a new device for absolute-length measurements of the order of 10⁻⁹ of a long-baseline (100 m) Fabry–Perot cavity by the use of phase-modulated light. This third strainmeter will be ready for operation before the end of 2004. The laser source of strainmeters (1) and (2) is a frequency-doubled YAG laser with a wavelength of 532 nm. The laser frequency is locked onto an iodine absorption line and a stability of 2 × 10⁻¹³ is attained. The light paths of the laser strainmeter system are enclosed in SUS304 stainless steel pipes. The inside pressure is kept to be 10⁻⁴ Pa. Consequently, quantitative measurement of crustal strains of the order of 10⁻¹³ can be attained by employing the laser strainmeter system of (1) and (2) at Kamioka. This resolving power corresponds to that of a superconducting gravimeter. Using the laser strainmeter system, we expect to determine parameters related to fluid core resonance, core modes and core undertone as well as other geodynamic signals such as slow strain changes caused by silent earthquakes or slow earthquakes.     

Evolution history of the Hidaka-oki (offshore Hidaka) basin in the southern central Hokkaido, as revealed by seismic interpretation, and related tectonic events in an adjacent collision zone

Off the southern coast of Hokkaido the Hidaka-oki (offshore Hidaka) basin has developed on the western flank of a collision suture under the influence of long-standing compressional plate motion and provoked tectonic stresses around the northwestern Pacific rim throughout the late Cenozoic. The basin forming history of the Japan arc and Kuril arc collision zone is described on the basis of seismic reflection data interpretation. We identify two stages of basin formation: the older (late Oligocene-Miocene) faulted en echelon graben (pull-apart basin) and younger (Plio-Pleistocene) regional downwarping. Paleoenvironmental changes recorded within the fore-arc sediments indicate that the older basin filled up by the late Miocene. We inferred the volumes of the distinctive basins from the depth-conversion of seismic data, which suggest episodic uplifts and massive erosion of the Hidaka Mountains in the middle-late Miocene and the Plio-Pleistocene. Estimated sediment supply rates into the basins have a similar level for the both stages. Cause of an episodic uplift in the older stage is attributed to the delayed opening of the Japan Sea. The eastern Eurasian margin underwent N-S right-lateral faulting at 25 Ma as a result of rifting of the Kuril back-arc basin. Formation of the Japan Sea back-arc basin since the early Miocene (ca. 20 Ma) caused eastward motion of the western Hokkaido block and transpressive regime along the pre-existing N-S shear deformation zone.     

Piezomagnetic fields produced by dislocation sources

Tectonomagnetic modeling based on the linear piezomagnetic effect is reviewed with special attention to dislocation models. Stacey's scheme was the prototype for such modeling, as proposed in his first seismomagnetic calculations in 1964. The linear piezomagnetic law is presented, in which the stress-induced magnetization is expressed as a linear combination of stress components. The Gauss law for magnetic field and the Cauchy-Navier equation for static elastic equilibrium are combined through linear piezomagnetism and the Hooke law to yield the basic equation for piezomagnetic potential. A representation theorem for its solution is given by surface integrals of the displacement and its normal derivative over the strained body.A Green's function method is developed to compute the piezomagnetic field produced by a dislocation surface in an elastic half-space. Volterra's formula for piezomagnetic potential is derived by modifying Stacey's scheme for tectonomagnetic modeling. The Green's functions for the problem are called elementary piezomagnetic potentials, which are defined as potentials produced by elementary dislocations. Special consideration is required to construct the elementary piezomagnetic potentials, because the stress field around a point dislocation has a singularity of orderr ^–3. The integral representing elementary piezomagnetic potentials is not uniformly convergent. Owing to inappropriate convergency, the Green's functions obtained in an earlier study led to a puzzling outcome. Revised Green's functions give consistent results with those obtained so far by numerical integrations. Generally the piezomagnetic field produced by dislocation sources is weak in the case of a homogeneous earth model. Two enhancement effects for piezomagnetic signals are suggested: one due to inhomogeneous magnetization and the other via bore-hole observations.     

Two-dimensional effective stress analysis of liquefaction of irregular ground including soil–structure interaction

An effective stress method is presented for analysis of seismic response and liquefaction of irregular ground including soil–structure interaction, based on an implicit–explicit finite element method. A pore water pressure is computed with iteration from the total stress considering an undrained condition. The simulated pore water pressure is in reasonably good agreement with the experimental data. The proposed method of analysis is compared with other well-known methods for a one-dimensional model, which is in good agreement. The present effective stress method is also applied to liquefaction problems involving a two-dimensional soil–structure model. The structure is modelled by not only a rigid model but also as a multi-degree-of-freedom system with bi-linear springs. The numerical results are considered to be significant from the viewpoint of earthquake engineering.     

The characterization and distribution of aerosol and gaseous species in the winter monsoon over the western pacific ocean

During the winters of 1981 and 1982, measurements were taken on two Japanese islands of the aerosol and gaseous species which had been carried by northwesterly monsoons over the Pacific Ocean. The aerosols were characterized as sea-salt particles; soil particles, and as particles of sulfate, nitrate, organics and elemental carbon. At Chichi-jima island, which is about 800 km away from the main islands of Japan, it was found that the level of the anthropogenic components of the aerosols was considerably higher than their background level. The mean concentrations of the species on the islands are given in tabular forms. According to a survey made on board a ferry boat, the aerosol and gaseous species were fairly uniformly distributed along the southern coast of the main Japanese islands.     

Estimability analysis of variance and covariance components

Although variance and covariance components have been extensively investigated and a number of elegant formulae to compute them have been derived, nothing is known, without any ambiguity, about their estimability in the case of a fully unknown variance–covariance matrix. We prove that variance and covariance components in this case are not estimable, thus clarifying the ambiguity of the literature on the topic and correcting some erroneous statements in the literature. We also give a new theorem on the estimability of a linear function of variance and covariance components. Then we propose a new method to estimate the variance–covariance matrix with special structure, which can presumably be represented by, at most, r(r + 1)/2 independent parameters to guarantee its estimability in such a subspace, by directly implementing the positive definiteness of the matrix as constraint to the restricted maximum likelihood method, where r is the number of redundant measurements. Therefore, our estimates of the variance and covariance components always reconstruct a positive definite matrix and are always physically meaningful.     

A New Species of Huaxiapterus （Pterosauria： Pterodactyloidea） from the Lower Cretaceous of Western Liaoning, China with Comments on the Systematics of Tapejarid Pterosaurs

A new species of tapejarid pterosaur, Huaxiapterus coroUatus sp. nov. is erected on the basis of a nearly complete skull and postcranial skeleton from the Lower Cretaceous Jiufotang Formation of Liaoning Province, China. Huaxiapterus coroUatus sp. nov. is characterized by a hatchet-shaped rectangular process on the premaxilla, whose short axis is perpendicular to the anterior margin of the premaxillae. Except for this process, other characters of the skull such as the breadth of the snout between the anterior margin of the nasoantorbital fenestra and the anterior margin of the premaxilla are similar to that of Huaxiapterus jii. Huaxiapterus and a second Chinese tapejarid, Sinopterus, share several unique cranial characters in common with Tapejara and these three genera appear to be more closely related to each other than to other azhdarchoids. The Chinese tapejarids （Sinopterus and Huaxiapterus） have relatively elongate skulls and weakly developed cranial crests and seem to be less derived than Tapejara, with its shorter, deeper skull and large cranial crest. Tupuxuarids （Tupuxuara and Thalassodromeus） have often been associated with tapejarids in the family Tapejaridae, but this relationship is controversial because some phylogenetic analyses have supported the pairing of tupuxuarids with Azhdarchidae. We propose that Tapejaridae be restricted to Tapejara, Sinopterus and Huaxiapterus.     

Development of a flood water level estimation method using satellite images and a digital elevation model for the Mekong floodplain

We have developed a flood water level estimation method that only employs satellite images and a DEM. The method involves three steps: (1) discriminating flood areas and identifying clumps of each flood area, (2) extracting the edges of the identified flood area using a buffering technique, and (3) performing spatial interpolation to transform the extracted elevation to flood water levels. We compared the estimated flood water levels with the observed ones. The RMSE using the RADARSAT was 1.99 and 1.30 m at river and floodplain points, respectively, whereas the RMSE using the MODIS was 4.33 and 1.33 m at the river and floodplain points, respectively. Given that most errors are attributed to the DEM, the method exhibited good performance. Furthermore, the method reproduced the flow directions and flood water level changes during the flooding period. Thus, we demonstrated that the characteristics of flood inundation can be understood even when ground observation data cannot be obtained.