Estimation of lead sources in a Japanese cedar ecosystem using stable isotope analysis

Anthropogenic Pb affects the environment worldwide. To understand its effect on forest ecosystem, Pb isotope ratios were determined in precipitation, various components of vegetation, the forest floor, soil and parent material in a Japanese cedar (Cryptomeria japonica D. Don) forest stand. The average ²⁰⁶Pb/²⁰⁷Pb ratio in bulk precipitation was 1.14 ± 0.01 (mean ± SD), whereas that in the subsoil (20–130 cm) was 1.18 ± 0.01. Intermediate ratios ranging from 1.15 to 1.16 were observed in the vegetation, the forest floor, and the surface soil (0–10 cm). Using the ²⁰⁶Pb/²⁰⁷Pb ratios, the contribution of anthropogenic sources to Pb accumulated in the forest were estimated by the simple binary mixing model. Sixty-two percent of the Pb in the forest floor, 71% in the vegetation, and 55% in the surface soil (0–10 cm) originated from anthropogenic sources, but only 16% in the sub-surface soil (10–20 cm) was anthropogenic. These results suggest that internal Pb cycling occurs mainly between surface soil and vegetation in a Japanese cedar ecosystem, and that anthropogenic Pb strongly influences Pb cycling. Although the Japanese cedar ecosystem has a shallow forest floor, very little atmospherically derived Pb migrated downward over 10 cm in depth.     

Variance Component Estimation in Linear Inverse Ill-posed Models

Regularization has been applied by implicitly assuming that the weight matrix of measurements is known. If measurements are assumed to be heteroscedastic with different unknown variance components, all regularization techniques may not be proper to apply, unless techniques of variance component estimation are directly implemented. Although variance component estimation techniques have been proposed to simultaneously estimate the variance components and provide a means of regularization, the regularization parameter is treated as if it were also an extra variance component. In this paper, we assume no prior information on the model parameters and do not treat the regularization parameter as an extra variance component. Instead, we first analyze the biases of estimated variance components due to the regularization parameter and then propose bias-corrected variance component estimators. The results have shown that they work very well. Finally, we propose and investigate through simulations an iterative scheme to simultaneously estimate the variance components and the regularization parameter, in order to eliminate the effect of regularization parameter on variance components and the effect of incorrect prior weights or initial variance components on the regularization parameter.     

Dark inclusions in CO3 chondrites: new indicators of parent-body processes

A petrographic and scanning electron microscopic study of the four CO3 chondrites Kainsaz, Ornans, Lancé, and Warrenton reveals for the first time that dark inclusions (DIs) occur in all the meteorites. DIs are mostly smaller in size than those reported from CV3 chondrites. They show evidence suggesting that they were formed by aqueous alteration and subsequent dehydration of a chondritic precursor and so probably have a formation history similar to that of DIs in CV3 chondrites. DIs in the CO3 chondrites consist mostly of fine-grained, Fe-rich olivine and can be divided into two types on the basis of texture. Type I DIs contain rounded, porous aggregates of fine grains in a fine-grained matrix and have textures suggesting that they are fragments of chondrule pseudomorphs. Veins filled with Fe-rich olivine are common in type I DIs, providing evidence that they experienced aqueous alteration on the parent body. Type II DIs lack rounded porous aggregates and have a matrix-like, featureless texture. Bulk chemical compositions of DIs and mineralogical characteristics of olivine grains in DIs suggest that these two types of DIs have a close genetic relationship.The DIs are probably clasts that have undergone aqueous alteration and subsequent dehydration at a location different from the present location in the meteorites. The major element compositions, the mineralogy of metallic phases, and the widely dispersed nature of the DIs suggest that their precursor was CO chondrite material. The CO parent body has been commonly regarded to have been dry, homogeneous, and unprocessed. However, the DIs suggest that the CO parent body was a heterogeneous conglomerate consisting of water-bearing regions and water-free regions and that during asteroidal heating, the water-bearing regions were aqueously altered and subsequently dehydrated. Brecciation may also have been active in the parent body.The DIs and the matrices are similarly affected by thermal metamorphism in their own host CO3 chondrites (petrologic subtypes 3.1 to 3.6), but the degree of the secondary processing (aqueous alteration and subsequent dehydration) of the DIs has no apparent correlation with the petrologic grades of the host chondrites. These observations suggest that the DIs had been incorporated into the host chondrites before the thermal metamorphism took place and that the secondary processes that affected the DIs largely occurred before the thermal metamorphism.     

Geochemical Features of Vein Anhydrite from the Kakkonda Geothermal System, Northeast Japan

Abstract. Cathodoluminescence (CL) color, rare earth element (REE) content, sulfur and oxygen isotopes and fluid inclusions of anhydrite, which frequently filled in hydrothermal veins in the Kakkonda geothermal system, were investigated to elucidate the spatial, temporal and genetical evolution of fluids in the deep reservoir. The anhydrite samples studied are classified into four types based on CL colors and REE contents: type-N (no color), type-G (green color), type-T (tan color) and type-S (tan color with a high REE content). In the shallow reservoir, only type-N anhydrite is observed. In the deep reservoir, type-G anhydrite occurs in vertical veins whereas type-T and -N in lateral veins. Type-S anhydrite occurs in the heat-source Kakkonda Granite. The CL textures revealed that type-G anhydrite deposited earlier than type-T in the deep reservoir, implying that fracture system was changed from predominantly vertical to lateral.
Studies of fluid inclusions and δ³⁴S and δ¹⁸O values of the samples indicate that type-N anhydrite deposited from diluted fluids derived from meteoric water, whereas type-G, -T and -S anhydrites deposited from magmatic brines derived from the Kakkonda Granite with the exception of some of type-G with recrystallization texture and no primary fluid inclusion, which deposited from fossil seawater preserved in the sedimentary rocks. Type-G, -T and -S anhydrites exhibit remarkably different chondrite-normalized REE patterns with a positive Eu anomaly, with a convex shape (peak at Sm or Eu) and with a negative Eu anomaly, respectively. The difference in the patterns might result from the different extent of hydrothermal alteration of the reservoir rocks and contribution of the magmatic fluids.     

Active strike–slip faulting and macroscopically nonrigid deformation of volcanic rocks in central Japan inferred from a paleomagnetic study

Detailed paleomagnetic investigation of a pyroclastic flow deposit has clarified the deformation mode around an active fault. In central Japan, the early Quaternary Nyukawa Pyroclastic Flow Deposit is cut by the active dextral Enako fault. Activity level of the fault is evaluated on the basis of geological and geomorphological surveys. Then, paleomagnetic samples are collected from 22 sites at exposures located on a lineament that is adjoining and parallel to the Enako fault. Stable thermoremanent magnetization (TRM) of the pyroclastic deposit is isolated through progressive thermal and/or alternating field demagnetization tests. Untilted site-mean directions of the TRMs simultaneously acquired during initial cooling indicate significant clockwise vertical-axis rotation. The lineament was then activated with right-lateral motions through the early Quaternary. Together with the late Quaternary activities along the adjoining Enako fault evaluated by our study, the present result exemplifies a migration of active segments within a fault system during the Quaternary. Paleomagnetic directions on the strike–slip fault are not concordant with uniform deformation predicted by the model of rotation of rigid blocks aligned on a master fault, but suggestive of a periodic deformation as a result of intense fracturing and differential rotation of blocks bounded by nested parallel faults.     

Benthic ecosystem development in an artificial tidal flat constructed from dredged spoil

Dredged spoil (DS) was used as a silt and clay additive in the construction of artificial tidal flats from mountain sand (MS). As the ratio of DS in the sediment media increased, the number of emerging macrobenthos increased. The composition of the macrobenthic community was also affected by the addition of DS, and the changes might be dependent on the ratio of DS to MS. In addition, the macrobenthos in the artificial tidal flats was more abundant than that in the control tidal flat, which was constructed with natural tidal flat sediment. With a silt and clay content of 25%, polychaetes Ceratonereis erythraeensis and Capitella sp. and the gastropod Batillaria cumingii were dominant, whereas no bivalves were present. With less silt and clay (5% and 10%), the bivalves Ruditapes philippinarum and Musculista senhousia were observed in the artificial flats, while their numbers in the control tidal flat were lower.     

Simultaneous Analysis of Natural Free Estrogens and Their Conjugates in Wastewater by GC‐MS

A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L^–1, respectively. However, only E1 was detected at a high concentration of 44 ng L^–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent.     

Relativistic corrections to the multiple scattering effect on the Sunyaev–Zel'dovich effect in the isotropic approximation

We extend the formalism for the calculation of the relativistic corrections to the Sunyaev–Zel'dovich effect for clusters of galaxies and include the multiple scattering effects in the isotropic approximation. We present the results of the calculations by the Fokker–Planck expansion method as well as by the direct numerical integration of the collision term of the Boltzmann equation. The multiple scattering contribution is found to be very small compared with the single scattering contribution. For high-temperature galaxy clusters of     the ratio of both the contributions is −0.2 per cent in the Wien region. In the Rayleigh–Jeans region the ratio is −0.03 per cent. Therefore the multiple scattering contribution is safely neglected for the observed galaxy clusters.     

Mechanical structure of JNLT

The Japanese National Large Telescope (JNLT) requires mechanical performance of high tracking accuracy to achieve good image quality and a mechanical configuration to provide several kinds of focus modes. Under these requirements, a conceptual design for the JNLT mechanical structure has been performed. This paper presents the results of the conceptual design currently under consideration.Paper presented at the symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2, 1988.     

Low energy neutral atom imaging on the Moon with the SARA instrument aboard Chandrayaan-1 mission

This paper reports on the Sub-keV Atom Reflecting Analyzer (SARA) experiment that will be flown on the first Indian lunar mission Chandrayaan-1. The SARA is a low energy neutral atom (LENA) imaging mass spectrometer, which will perform remote sensing of the lunar surface via detection of neutral atoms in the energy range from 10 eV to 3 keV from a 100km polar orbit. In this report we present the basic design of the SARA experiment and discuss various scientific issues that will be addressed. The SARA instrument consists of three major subsystems: a LENA sensor (CENA), a solar wind monitor (SWIM), and a digital processing unit (DPU). SARA will be used to image the solar wind-surface interaction to study primarily the surface composition and surface magnetic anomalies and associated mini-magnetospheres. Studies of lunar exosphere sources and space weathering on the Moon will also be attempted. SARA is the first LENA imaging mass spectrometer of its kind to be flown on a space mission. A replica of SARA is planned to fly to Mercury onboard the BepiColombo mission.