巢湖水-气界面N2O通量排放特征及影响因素

湖泊是温室气体氧化亚氮(N₂O)的潜在排放源,但由于自然环境以及人类活动的差异,其N₂O排放规律也存在特殊性和地域性。为探究巢湖N₂O排放通量的时空特征,利用静态暗箱-气相色谱法于2018年3月至2019年12月对巢湖不同区域(东、中、西)N₂O的排放进行观测。结果表明,巢湖水体N₂O年均排放通量为(25.14±55.01)μg/(m²·h),表现为N₂O的“源”,且具有较为明显的时空分布规律。在时间分布上,季节变化趋势呈现“M”形模式,7月出现最小值且表现为N₂O的“汇”((-12.97±16.32)μg/(m²·h)),在6月和8月为峰值,全年最大值出现在8月((68.25±78.05)μg/(m²·h)),极值均出现在夏季。在空间分布上,东、中、西3个湖区N₂O排放通量差异显著(P=0.03),N₂O排放通量最大值((4...     

滇东北地区地震弱活动前兆异常特征研究

以鲁甸M_S6.5地震震中附近的鲁甸大坪子泉水氡、 水质观测资料为基础, 通过对其地震前后的异常特征进行差异性对比, 分析认为震前地震活动丛集, 水氡、 水质异常持续时间较长, 幅度较大, 表现为破年变异常现象; 震后为小震群弱活动, 水氡、 水质异常幅度相对较小, 持续时间较短, 多次出现同步转折, 表现为介质弱化区的前兆异常特征。 从水样测试结果, GNSS位移观测资料、 GPS时间序列曲线及地震活动性等方面分析了鲁甸水氡、 水质的异常机理, 认为鲁甸的水质离子组分群体异常, 与区域的变形活动有关, 局部应力的不断积累, 加剧了地下深部物质活动及构造活动; 近期的同步转折现象属于介质弱化区应力调整状态下的前兆异常。     

地震力学成因及前兆机理研究——再“读”唐山地震有感

简述弹性回跳学说、板块构造模型及岩浆活动型地震等地震力学成因的现有观点,并对其进行了讨论。通过分析唐山震区的壳幔深部结构、前兆异常时空演化等资料,进一步论证了唐山地震力学成因为岩浆活动的观点。在此基础上对唐山地震前兆机理进行了研究,指出岩浆活动既是该地震发生的成因,也是各类前兆异常的成因,它们是岩浆活动这枚硬币的两面。最后指出只有正确认识地震和前兆的成因,才有可能用前兆资料对地震三要素做出较好的预报。     

Influence of Fluctuating Groundwater Table on Volatile Organic Chemical Emission Flux at a Dissolved Chlorinated-Solvent Plume Site

Groundwater elevation fluctuation has been recognized as one mechanism causing temporal indoor air volatile organic chemical (VOC) impacts in vapor intrusion risk assessment guidance. For dissolved VOC sources, groundwater table fluctuation shortens/lengthens the transport pathway, and delivers dissolved contaminants to soils that are alternating between water saturated and variably saturated conditions, thereby enhancing volatilization potential. To date, this mechanism has not been assessed with field data, but enhanced VOC emission flux has been observed in lab-scale and modeling studies. This work evaluates the impact of groundwater elevation changes on VOC emission flux from a dissolved VOC plume into a house, supplemented with modeling results for cyclic groundwater elevation changes. Indoor air concentrations, air exchange rates, and depth to groundwater (DTW) were collected at the study house during an 86-d constant building underpressurization test. These data were used to calculate changes in trichloroethylene (TCE) emission flux to indoor air, during a period when DTW varied daily and seasonally from about 3.1 to 3.4 m below the building foundation (BF). Overall, TCE flux to indoor air varied by about 50% of the average, without any clear correlation to changes in DTW or its change rate. To complement the field study, TCE surface emission fluxes were simulated using a one-dimensional model (HYDRUS 1D) for conditions similar to the field site. Simulation results showed time-averaged surface TCE fluxes for cyclic water-table elevations were greater than for stationary water-table conditions at an equivalent time-averaged water-table position. The magnitudes of temporal TCE emission flux changes were generally less than 50% of the time-averaged flux, consistent with the field site observations. Simulation results also suggested that TCE emission flux changes due to groundwater fluctuation are likely to be significant at sites with shallow groundwater (e.g., < 0.5 m BF) and permeable soil types (e.g., sand).     

Ediacaran integrative stratigraphy and timescale of China

Ediacaran successions occur widely in various depositional facies in South China and yield a series of fossil Lagerst?tten, providing a complete fossil record for the evolution of marine ecosystems after the terminal Cryogenian global glaciation. Carbonate-dominated Ediacaran successions in shallow water facies in South China record a nearly complete δ~(13)C profile that may reflect variations of marine carbon isotopic composition during the Ediacaran Period. The Ediacaran fossils andδ~(13)C profiles from South China permit stratigraphic correlation and subdivision of the Ediacaran strata. Based on biostratigraphic, chemostratigraphic, and geochronometric data from the Ediacaran successions in South China, we propose that the Ediacaran System in China can be subdivided into two series, with three stages in each series. The lower series is characterized by acanthomorphic acritarchs and the upper series by Ediacara-type macrofossils, and the two series are separated by the declining limb of a pronounced δ~(13)C negative excursion(EN3) in the upper Doushantuo Formation. The basal boundary of Stage1 is the same as the basal boundary of Ediacaran System, which has been defined at the base of the cap carbonate unit. Stage 2 represents the first radiation of Ediacaran microscopic organisms, with δ~(13)C feature representing by positive values(EP1). The base of the Stage 2 is placed at the first appearance level of a spiny acritarch species. Stage 3 is characterized by the occurrence of more diverse acritarchs and δ~(13)C feature EP2, with its basal boundary defined by a δ~(13)C negative excursion(EN2) occurring in the middle Doushantuo Formation. The basal boundary of Stage 4 is the same as the upper series. Stage 5 is marked by the occurrence of macrfossils of Miaohe biota, and its lower boundary can be placed at the level where δ~(13)C values transition from positive to negative in MNE, or the first appearance level of macrofossils of the Miaohe biota. Stage 6 is characterized by the occurrences of Ediacara-type Shibantan biota and Gaojiashan biota, with its lower boundary defined by the first appearance level of Conotubus hemiannulatus. The formal establishment of the aforementioned series and stages requires further and more detailed integrative stratigraphic study on the Ediacaran successions in China. Some of the Ediacaran successions in South China have great potential to become global standards in Ediacaran subdivision.     

地震观测仪器自动监控软件设计与实现

结合地震地球物理观测台网台站监测工作实际,研制一款地震观测仪器自动监控软件。该软件适用于不同网络环境下IP类仪器设备的网络实时或定时自动监控,地球物理观测类仪器时钟、状态和观测数据的定时自动监控,能自动识别当日观测数据中的无效数据、变幅异常、干扰、地震和限幅等信息,无需借助其他硬件和软件即可将告警信息以短信方式发送给值班人员和管理人员,可实现对仪器原始观测数据的自动备份和手动恢复,及对仪器的一键重启和校正时钟等控制类操作,无需跨平台操作即可查看当日观测数据曲线及分析数据的完整性和有效性,从而实现对仪器的统一高效管理。     

Application of Avaatech X-ray fluorescence core-scanning in Sr/Ca analysis of speleothems

Application of X-ray fluorescence core-scanning(XRF-CS) on both marine and lake sediments has achieved remarkable results. However, its application has not been widely extended to the research on speleothems. In this study, we measure the Sr abundance and the Sr/Ca ratios of three stalagmites(two aragonite stalagmites, one calcite stalagmite) using the state-of-the-art fourth-generation Avaatech high-resolution XRF core scanner. Through comparisons among different scan paths and among different scan resolutions, as well as comparisons with inductively coupled plasma optical emission spectrometer(ICP-OES), Itrax XRF, and Artax XRF results, we confirm that the Avaatech XRF core scanner could precisely, quickly, and nondestructively analyze the high-resolution Sr abundance of speleothems. Furthermore, we combine the stalagmite δ~(18)O records to explore the paleoclimatic significance of the measured stalagmite Sr/Ca.     

CO2 saturation estimates at Sleipner (North Sea) from seismic tomography and rock physics inversion

CO₂ saturations are estimated at Sleipner using a two-step imaging workflow. The workflow combines seismic tomography (full-waveform inversion) and rock physics inversion and is applied to a two-dimensional seismic line located near the injection point at Sleipner. We use baseline data (1994 vintage, before CO₂ injection) and monitor data that was acquired after 12 years of CO₂ injection (2008 vintage). P-wave velocity models are generated using the Full waveform inversion technology and then, we invert selected rock physics parameters using an rock physics inversion methodology. Full waveform inversion provides high-resolution P-wave velocity models both for baseline and monitor data. The physical relations between rock physics properties and acoustic wave velocities in the Utsira unconsolidated sandstone (reservoir formation) are defined using a dynamic rock physics model based on well-known Biot–Gassmann theories. For data prior to injection, rock frame properties (porosity, bulk and shear dry moduli) are estimated using rock physics inversion that allows deriving physically consistent properties with related uncertainty. We show that the uncertainty related to limited input data (only P-wave velocity) is not an issue because the mean values of parameters are correct. These rock frame properties are then used as a priori constraint in the monitor case. For monitor data, the Full waveform inversion results show nicely resolved thin layers of CO₂–brine saturated sandstones under intra-reservoir shale layers. The CO₂ saturation estimation is carried out by plugging an effective fluid phase in the rock physics model. Calculating the effective fluid bulk modulus of the brine–CO₂ mixture (using Brie equation in our study) is shown to be the key factor to link P-wave velocity to CO₂ saturation. The inversion tests are done with several values of Brie/patchiness exponent and show that the CO₂ saturation estimates are varying between 0.30 and 0.90 depending on the rock physics model and the location in the reservoir. The uncertainty in CO₂ saturation estimation is usually lower than 0.20. When the patchiness exponent is considered as unknown, the inversion is less constrained and we end up with values of exponent varying between 5 and 20 and up to 33 in specific reservoir areas. These estimations tend to show that the CO₂–brine mixing is between uniform and patchy mixing and variable throughout the reservoir.     

CHARACTERISTICS OF TECTONIC STRESS FIELD OF THE XIAOWAN RESERVOIR BEFORE AND AFTER THE IMPOUNDMENT

Using the seismic waveform data of Xiaowan seismic network and Yunnan seismic network, we determined the focal mechanisms of 36 earthquakes(M_L ≥ 3.0)from Jun. 2005 to Dec. 2008 and 51 earthquakes(M_L ≥ 2.5)from Jan. 2009 to Dec. 2015 by generalized polarity and amplitude technique. We inverted tectonic stress field of the Xiaowan reservoir before impounding, using the focal mechanisms of 36 earthquakes(M_L ≥ 3.0)from Jun. 2005 to Dec. 2008 and CAP solutions of 58 earthquakes(M_L ≥ 4.0)collected and the solutions in the Global Centroid Moment Tensor(GCMT)catalog; We inverted local stress field of the reservoir-triggered earthquake clustering area, using 51 earthquakes(M_L ≥ 2.5)from Jan. 2009 to Dec. 2015. Focal mechanisms statistics show that, the Weixi-Qiaohou Fault is the seismic fault. Focal mechanisms were strike-slip type in initial stage, but normal fault type in later stage. Focal depths statistics of 51 earthquakes(M_L ≥ 2.5)show that, the average value of focal depths in period Ⅰ, period Ⅱ and period Ⅲ are 8.2km, 7.3km and 7.8km respectively and the standard deviations are 4.3km, 3.5km and 6.0km respectively. The average value of focal depths is basically stable in different period, only the standard deviation is slightly different. Therefore, there is not positive connection between focal depth and deviation of focal mechanisms. What's more, there are 2 earthquakes(number 46 and number 47 in Fig.5 and Table 3)with almost the same magnitude, epicenter and focal depth, but they have different faulting types as normal and strike-slip. The focal mechanism of event No.46 is strike:302°, dip:40° and rake:-97° for plane Ⅰ, however, the focal mechanism of event No.47 is strike:292°, dip:82° and rake:140° for plane Ⅰ. Likewise, earthquake of number 3 and number 18 have similar characteristic. Therefore, the obvious focal mechanism difference of similar earthquake pair indicates the complexity of Weixi-Qiaohou Fault. Considering the quiet-active character of reservoir-triggered earthquakes, we discussed the change of local stress field in different period. The σ₁ of tectonic stress field was in the near-south direction, with a dip angle of 14° before the impoundment, however, the direction of σ₁ of local stress field changed continuously, with the dip angle getting larger after the impoundment. The direction of σ₁ of local stress field of reservoir-triggered earthquake clustering area is close to the strike of Weixi-Qiaohou Fault, and reservoir impoundment increased the shear stress in the fault, so the weakening of fault was beneficial to trigger earthquakes. Comprehensive analysis suggests that fluid permeation and pore pressure diffusion caused by the water impounding, and the weakening of fault caused by local stress field are the key factors to trigger earthquake in the Xiaowan reservoir.     

Dynamic amplification factors for a system with multiple-degrees-of-freedom

It is well-known that the responses of a structure are different when subjected to a static load or a sudden step load. The dynamic amplification factor (DAF), which is defined as the ratio of the amplitude of the vibratory response to the static response, is normally used to depict the dynamic effect. For a single-degree-of-freedom system (SDOF) subjected to a sudden dynamic load, the maximum value of DAF is 2. Many design guidelines therefore use 2 as an upper bound to consider the dynamic effect. For a civil engineering structure, which is normally a multiple-degrees-of-freedom (MDOF) system, the DAF may exceed 2 in certain circumstances. The adoption of 2 as the upper bond as suggested by the design guidelines therefore may lead to unsafe structural design. Very limited studies systematically investigate the DAF of a MDOF system. This study theoretically investigates the DAF of a MDOF system when it is subjected to a step load based on the fundamental theory of structural dynamics. The condition on which the DAF may exceed 2 is defined. Two numerical examples and one experimental study of a cable-stayed bridge subjected to sudden cable loss are presented to illustrate the problem.