钍—偶氮胂Ⅲ—乙醇体系显色反应的研究及应用

本文研究了在乙醇存在的体系中偶氮胂Ⅲ与Th的显色反应条件。当乙醇含量为48％时,Th与偶氮胂Ⅲ反应的最佳酸度为3.4—5.5mol/L HCl,其最大吸收波长为660nm,表观摩尔吸光系数为1.4×10~5L·mol~(-1)·cm~(-1),Th量在0—80μg/25ml范围服从比尔定律。探讨了乙醇的作用机理,并将方法用于岩石中痕量Th的测定,获得良好结果     

Experimental research on the effect of slope morphology on bank collapse in mountain reservoir

Farmers along the Amazon River each year face multiple natural hazards that threaten crop production and limit the potential for agricultural development of the expansive floodplain and active channel. In this paper we report the findings of a study of natural hazard-related risk associated with rice production on silt bars in the active channel of the Amazon River near Iquitos, Peru. Data were gathered in four rice producing communities in 2014 using household surveys (n = 83 households), focus group discussions, surveying of land elevations along the Amazon River, and interpretation of remote sensing imagery. The probability, extent, and severity of rice crop shortfalls were estimated for recent production years and the economic losses to farming households were also assessed. Our findings point to a very high risk of crop shortfalls due to natural hazards, suggesting that a good year brings rice farmers bounty and a bad year, near penury. River stage reversals (repiquetes) and edaphic conditions were found to be more problematic than the often cited hazard of high and/or early floods. Also surprisingly, farmers’ perceptions of hazards and risk diverged markedly from actual shortfalls experienced during the production years studied. Our results provide the first quantitative estimates of risk due to the multiple natural hazards along the Amazon River and point to the need to assist lowland farmers with risk mitigation so as to unlock the considerable potential of Amazon floodlands for agricultural production.     

测井曲线旋回分析在碳酸盐岩层序地层研究中的应用*

在碳酸盐岩台地沉积层序的研究中,通过旋回计数和厚度测量,采用费希尔图解法解析高频米级旋回或副层序的叠置形式和空间结构,进而标定三级沉积层序的界面,是目前普遍采用的一个方法。但是,这一方法目前主要用于露头层序地层学研究,而在地下油气勘探区受到极大的限制。文中提出了一种新的计算方法,它可以根据测井资料求取任一地层段沉积旋回的个数和厚度。根据数值模拟,详细讨论了海平面变化周期和幅度与沉降速率、沉积速率的相关关系,提出高频沉积旋回的分布模式和叠加样式可以指示低频海平面变化的轨迹,这为划分三级沉积层序、标定层序界面提供了理论依据。最后,以川西北地区中三叠统雷口坡组为例,说明了应用自然伽马测井资料进行数据处理的流程和步骤,以及根据旋回厚度累积偏差曲线标定层序界面的位置、识别旋回谱系标志。     

利用经验正交函数数据插值法重构东中国海叶绿素a质量浓度场

利用经验正交函数数据插值法(Data INterpolating Empirical Orthogonal Functions)重构由MODIS-Aqua卫星提供的三级产品叶绿素a质量浓度,得到了从2003—2009年东中国海叶绿素a质量浓度的月平均场。东中国海近岸叶绿素a质量浓度7 a平均值明显高于外海。对叶绿素a质量浓度季节平均场进行分析研究表明,东中国海叶绿素a质量浓度主要受长江径流、海表水温和季风的影响。对叶绿素a质量浓度异常场进行EOF分析表明,第一模态方差贡献为37.8％,空间分布显示,在长江口东北部出现叶绿素a质量浓度异常高值区,时间变化以半年和半年以下周期为主;第二模态方差贡献为21.4％,空间分布显示,在长江口东部出现叶绿素a质量浓度异常高值区,时间系数主要表现为年际变化。     

水文时间系列周期分析方法探讨

以分析广东省降水周期变化规律为例，探讨了最大熵谱方法在提取水文时间系列的主次周期上以及小波变换方法在分析水文时间系列的多时间尺度演变规律上的应用。由计算结果分析得到广东省降水过程主要存在的周期特性和旱涝变化趋势，为广东省降水趋势预测提供了重要信息。     

城市土地集约利用与区域城市化的时空耦合协调发展评价——以环渤海地区城市为例

处于城市化不同发展水平的城市,其土地集约利用的利用强度、利用形式与利用类型存在显著差异,城市土地利用最佳集约度与城市化水平密切相关,而城市土地集约利用与城市化的耦合协调可有效推动城市可持续发展。基于城市土地集约利用与城市化的交互耦合作用机制,本文构建两者之间的耦合协调发展度模型,定量评价城市土地集约利用与城市化的耦合协...     

GNSS在线数据处理系统在工程控制网中的应用与分析

介绍目前几个主要的GNSS在线数据处理系统,着重利用其中5个GNSS在线数据处理系统对某工程控制网的观测数据进行多个方案的处理;对处理结果进行对比分析,检验其内符合精度;再利用框架和历元转换理论和方法,将多个系统处理获得的不同ITRF框架下2011即时历元的观测点坐标转换归算到CGCS2000坐标下进行对比,结果表明:GNSS在线数据处理系统完全能够满足工程控制网的数据处理、精度要求以及成果提交等需求。     

多普勒雷达降水产品优化

通过对雷达1h、3h降水产品进行应用检验，找出降水产品的局限性及其测量误差；利用反射率因子及自动站雨量资料，通过调整雷达混合扫描面弥补了降水产品因山脉等地物挡角大而缺测面大的缺陷；结合雨量站资料运用最优插值、卡尔曼滤波等方法对本地Z-I关系及降水产品进行调整优化；调整后的降水产品估测降水的误差明显减小，产品质量大为提高。     

Geographical distribution of ecological footprint and sustainability analysis for Liaoning Province

This paper presents the detailed results and analyses on the ecological footprints and bio-capacities of the individual cities and the province as a whole for the year 2001, providing a clear picture of sustainability for the province. Results show that the ecological footprints of most cities in Liaoning exceeded their respective bio-capacities, incurring high ecological deficits. The ecological deficit of the province as a whole was 1.31 ha/cap. Those cities with resources extraction and/or primary material-making as their major industries constitute the "ecologically black band", whose ecological deficits ranged from 2.45 to 5.23 ha/cap, the highest of all cities in the province. Fossil energy consumption was the major source of footprint amounting to 1.63 ha/cap at the provincial level, taking up 67.3% of the total. For cropland, modest ecological surpluses occurred in Jinzhou, Tieling, Huludao, and Panjin while modest ecological deficits in Dalian, Benxi, Fushun, and Dandong, resulting in an overall surplus for the province. Liaoning had a certain level of surplus in fishing ground (water area), mainly distributed in the coastal cities of Dalian, Panjin, Huludao, Yingkou, Jinzhou, and Dandong. Most cities had a small ecological deficit in pasture and all had a small ecological surplus in forest. The eco-efficiency, expressed as GDP value per hectare of footprint, exhibits high variations among the cities, with the highest (Shenyang) more than 10 times the lowest (Fuxin). Cities with manufacture, high-tech, and better developed service industries had high eco-efficiency, while those with resources extraction, primary material-making, and less developed service industries had low eco-efficiency. Based on the components and geographical distribution of ecological footprint, strategic policy implications are outlined for Liaoning's development toward a sustainable future.     

扎赉诺尔坳陷带砂体特征及找铀矿方向分析

扎赉诺尔坳陷带内诸凹陷具有不同的沉积特征和砂体特点,查干诺尔和克鲁伦凹陷砂体形成于粗粒冲积扇和扇三角洲沉积体系,砂体厚度变化大,相变快,有机质含量低,顶底板均不发育;呼伦湖凹陷以小型三角洲平原相砂体为主,具有较稳定的泥砂岩结构,有机质含量高,砂体厚度和横向延伸较稳定,但砂体铀含量较低;胡列也吐凹陷砂体以辫状河三角洲体系产出为主,砂体厚度大,延伸稳定,底板发育,顶板发育不完全,砂体铀含量高.扎赉诺尔坳陷带各凹陷砂体的不同特点,决定了它们具有不同的找矿潜力.通过砂体综合条件对比分析,笔者认为胡列也吐凹陷和克鲁伦凹陷砂体铀成矿条件较好,呼伦湖凹陷次之,查干诺尔凹陷较差.