Determination of molybdenum in soils and sediments with a modified zinc dithiol procedure

Molybdenum determination, in soils and sediments, by dithiol (Stanton, 1966) is difficult when an emulsified organic layer forms and interferes with the colorimetric analysis. Addition of small quantities of acetone is suggested for clarification of the organic phase.     

Geodynamic evolution of the Vulcan Sub‐basin,Timor Sea,northwest Australia: A pre‐compression New Guinea analogue?

The Vulcan Sub‐basin lies immediately inboard of the incipient arc‐continent collision in the Timor Sea and comprises part of the Bonaparte Basin system, the northernmost basin on Australia's North West Shelf. Given the high level of preservation of its extensional fabric, the region can provide important analogues for the likely pre‐orogeny architecture of New Guinea, which enables a better understanding of the onset of, and response to, orogenesis. Structural restoration of regional, depth‐converted 2–D seismic lines shows that although the Late Jurassic Swan Graben is significant and contains a thick source‐rock section, the principal phase of crustal extension took place in the Triassic to Middle Jurassic. Within the Vulcan Sub‐basin, the southern Tilted Fault Block Domain records ～10% Triassic to Middle Jurassic extension, whereas <5% upper crustal extension has been measured in the northern Hourglass Domain. Similarly, while Jurassic extension in the Tilted Fault Block Domain is both deep and focused, the Hourglass Domain is expressed as a broad sag to the northeast, indicating a strong underlying basement influence on compartmentalisation. The Vulcan Sub‐basin shows four principal stages of evolution: (i) regional, evenly spaced crustal faulting and subsidence in the Triassic ‐ Middle Jurassic; (ii) focused faulting in the Late Jurassic that created grabens with uplift of the shoulders; (iii) regional subsidence from the Middle Valanginian; and (iv) minor extensional and contractional reactivation in the Mio‐Pliocene. The measured brittle extension is much less than that suggested by modelling of lithospheric subsidence, which suggests long wavelength distribution of strain in the ductile lower crust, with upper crustal extension mainly focused along the continent‐ocean boundary. Along the North West Shelf and on a smaller scale within the Vulcan Sub‐basin per se, the obvious, basement‐involved, rectilinear compartments defined by prominent offsetting of both extensional fault systems and abyssal plains have important implications for the development of the New Guinea orogen. Similar scale compartments are recognised in New Guinea and display different structural styles and hydrocarbon prospectivity. The transfer zones separating the compartments are the sites of the major copper‐gold deposits in New Guinea. Using the Vulcan Sub‐basin ‐ Timor area as an analogue, it can be seen that an arc could originally collide with a promontory, such as what is now Timor, and reactivate the lineaments allowing local extension and mineralisation. In addition, interpretation of the structure of the New Guinea Fold Belt may be aided by considering the effects of compression on the geometry of the Vulcan Sub‐basin and of the similar Carnarvon Basin and adjacent extended and broken Exmouth Plateau.     

The distribution function of dark matter in massive haloes

We study the distribution function (DF) of dark matter particles in haloes of mass range  10¹⁴–10¹⁵ M_⊙  . In the numerical part of this work we measure the DF for a sample of relaxed haloes formed in the simulation of a standard Λ cold dark matter (ΛCDM) model. The DF is expressed as a function of energy E and the absolute value of the angular momentum L , a form suitable for comparison with theoretical models. By proper scaling we obtain the results that do not depend on the virial mass of the haloes. We demonstrate that the DF can be separated into energy and angular momentum components and propose a phenomenological model of the DF in the form     . This formulation involves three parameters describing the anisotropy profile in terms of its asymptotic values (β₀ and  β_∞  ) and the scale of transition between them ( L ₀). The energy part   f _E ( E )  is obtained via inversion of the integral for spatial density. We provide a straightforward numerical scheme for this procedure as well as a simple analytical approximation for a typical halo formed in the simulation. The DF model is extensively compared with the simulations: using the model parameters obtained from fitting the anisotropy profile, we recover the DF from the simulation as well as the profiles of the dispersion and kurtosis of radial and tangential velocities. Finally, we show that our DF model reproduces the power-law behaviour of phase-space density   Q =ρ( r )/σ³( r )  .     

Use of the Köppen–Trewartha climate classification to evaluate climatic refugia in statistically derived ecoregions for the People’s Republic of China

Changes in climate as projected by state-of-the-art climate models are likely to result in novel combinations of climate and topo-edaphic factors that will have substantial impacts on the distribution and persistence of natural vegetation and animal species. We have used multivariate techniques to quantify some of these changes; the method employed was the Multivariate Spatio-Temporal Clustering (MSTC) algorithm. We used the MSTC to quantitatively define ecoregions for the People’s Republic of China for historical and projected future climates. Using the Köppen–Trewartha classification system we were able to quantify some of the temperature and precipitation relationships of the ecoregions. We then tested the hypothesis that impacts to environments will be lower for ecoregions that retain their approximate geographic locations. Our results showed that climate in 2050, as projected from anthropogenic forcings using the Hadley Centre HadCM3 general circulation model, were sufficient to create novel environmental conditions even where ecoregions remained spatially stable; cluster number was found to be of paramount importance in detecting novelty. Continental-scale analyses are generally able to locate potentially static ecoregions but they may be insufficient to define the position of those reserves at a grid cell-by-grid cell basis.     

The impacts of sustained heavy grazing on plant diversity and composition in lowland and upland habitats across the Kamiesberg mountain range in the Succulent Karoo, South Africa

This study explored the impacts of sustained heavy grazing in six vegetation types across an altitudinal and rainfall gradient in the Kamiesberg mountain range in Namaqualand. The study was carried out across the fence separating the Leliefontein communal area and surrounding privately owned farms. The communal area has been stocked over decades at approximately twice the government recommended stocking rate, while adjacent privately owned farms have generally adhered to recommended rates. Plant community data were collected from 66, 0.1 ha modified Whittaker plots and analysed for diversity and compositional changes. Consideration of community-wide responses through NMDS ordination showed that heavy grazing did not result in the dominance of a few wide-spread, weedy species in communal areas. Species richness at the 0.1 ha scale was also not affected by different land use practices. However, there was a significant compositional shift away from large woody and succulent shrubs, and an associated increase in dwarf shrubs and herbaceous perennial plants on the communal areas. This shift was only evident on the sandy lowland habitats, while a reduction in perennial grass was recorded in the rocky upland habitats on the communal areas. Compositional shifts towards smaller and more ephemeral species in the communal area are indicative of a system more closely dependent on rainfall. This has implications for people's livelihoods in the region, particularly in light of predicted climate change.     

The NOAA Goes-12 Solar X-Ray Imager (SXI) 1. Instrument, Operations, and Data

The Solar X-ray Imager (SXI) was launched 23 July 2001 on NOAAs GOES-12 satellite and completed post-launch testing 20 December 2001. Beginning 22 January 2003 it has provided nearly uninterrupted, full-disk, soft X-ray solar images, with a continuous frame rate significantly exceeding that for previous similar instruments. The SXI provides images with a 1 min cadence and a single-image (adjustable) dynamic range near 100. A set of metallic thin-film filters provides temperature discrimination in the 0.6 – 6.0 nm bandpass. The spatial resolution of approximately 10 arcsec FWHM is sampled with 5 arcsec pixels. Three instrument degradations have occurred since launch, two affecting entrance filters and one affecting the detector high-voltage system. This work presents the SXI instrument, its operations, and its data processing, including the impacts of the instrument degradations. A companion paper (Pizzo et al., this issue) presents SXI performance prior to an instrument degradation that occurred on 5 November 2003 and thus applies to more than 420000 soft X-ray images of the Sun.