Sedimentary records of multidecadal-scale variability of diatom productivity in the Bungo Channel, Japan, associated with the Pacific Decadal Oscillation

In order to examine the responses of primary productivity in the southern coastal sea of Japan to the Pacific Decadal Oscillation (PDO) in the 20th century, sedimentary records of diatom productivity (diatom valve fluxes) were reconstructed using core samples from the Bungo Channel (BC) in southwest Japan. The record of the Thalassionema spp. flux—the best index of fall primary productivity in the BC—indicated a multidecadal-scale duration with a low flux (1943–1982) and those with a high flux (1913–1943 and 1982–2001); apparent shifts were recognized in 1943 and 1982. The shift in 1982 was also recognized in the flux records of other early summer to fall predominant genera in the BC and, previously, in the biogenic silica records from a broad region of the southeast BC. This indicates that in our records, this shift reflects a general trend in the primary production in the southeast BC. A comparison among the Thalassionema spp. flux records, meteorological data from an observatory adjacent to the core site, and the PDO index showed that the flux records were more similar to the PDO index than the other meteorological records, which suggests that the multidecadal-scale variability of the BC primary productivity may be associated with some marine-derived forcing. The bottom intrusions of nutrient-rich water that upwelled from the shelf slope into the BC, the axis movement or the transport of the Kuroshio Current off the BC, and a basin-scale wind stress in the North Pacific might play an important role in this forcing and mediate between the BC primary productivity and the PDO.     

Barotropic instability of a viscous boundary jet

The barotropic instability of a boundary jet on a beta plane is considered with emphasis on the effect of internal viscosity. An eigenvalue problem for the disturbance equations and its inviscid version are solved by the aid of numerical methods, and instability characteristics are determined as functions of the Reynolds numberR for various values of the beta-parameter. Typical disturbance structures (eigenfunctions) are also computed. Numerical examples show that the minimum critical Reynolds numberR _cr for instability is smaller than 100. At a Reynolds number of the order of hundreds, there appears a second mode of instability in addition to the first unstable mode originating atR _cr ; a kind of ‘resonance’ between the first and second eigenvalues occurs at the particular value ofR. The neutral stability curves are accordingly multi-looped. Although each of the two unstable modes asymptotically approaches its inviscid counterpart asR→∞, the asymptotic approach to the inviscid limit is rather slow and the effect of varyingR is conspicuous even atR∼O (10⁴). It is thus demonstrated that the Reynolds number is an essential stability parameter for real boundary jets. The main part of the material contained in this paper was presented at 1981-Autumn Assembly of the Oceanographical Society of Japan.     

Carbon dioxide in surface seawaters of the Seto Inland Sea,Japan

Observations were made of time variations of carbon dioxide in seawater, pCO₂, and in the atmosphere, PCO₂, in the Seto Inland Sea of Japan. The pCO₂ data showed well defined diurnal variation; high values at nighttime and low values during daylight hours. The pCO₂ correlated negatively with dissolved oxygen. These results denote that the diurnal variation of pCO₂ is associated with effects of photoplankton's activity in seawater. The pCO₂ measured in the Seto Inland Sea showed higher values than the PCO₂ during June to November, denoting transport of carbon dioxide from the sea surface to the atmosphere, and lower values during December to May, denoting transport of carbon dioxide from the atmosphere to the sea surface. The exchange rates of carbon dioxide were calculated using working formula given by Andriéet al. (1986). The results showed that the Seto Inland Sea gained carbon dioxide of 1.0 m-mol m^–2 d^–1 from the atmosphere in March and lost 1.7 m-mol m^–2 d^–1 to the atmosphere in August.     

Using HED meteorites to interpret neutron and gamma‐ray data from asteroid 4 Vesta

Here, we construct a comprehensive howardite, eucrite, and diogenite (HED) bulk chemistry data set to compare with Dawn data. Using the bulk chemistry data set, we determine four gamma‐ray/neutron parameters in the HEDs (1) relative fast neutron counts (fast counts), (2) macroscopic thermal neutron absorption cross section (absorption), (3) a high‐energy gamma‐ray compositional parameter (C_p), and (4) Fe abundance. These correspond to the four measurements of Vesta made by Dawn's Gamma Ray and Neutron Detector (GRaND) that can be used to discern HED lithologic variability on the Vestan surface. We investigate covariance between fast counts and average atomic mass (<A>) in the meteorite data set, where a strong correlation (r² = 0.99) is observed, and we demonstrate that systematic offsets from the fast count/<A> trend are linked to changes in Fe and Ni concentrations. To compare the meteorite and GRaND data, we investigate and report covariance among fast counts, absorption, C_p, and Fe abundance in the HED meteorite data set. We identify several GRaND measurement spaces where the Yamato type B diogenites are distinct from all other HED lithologies, including polymict mixtures. The type B's are diogenites that are enriched in Fe + pigeonite + diopside ± plagioclase, relative to typical, orthopyroxenitic diogenites. We then compare these results to GRaND data and demonstrate that regions north of ~70°N latitude on Vesta (including the north pole) are consistent with type B diogenites. We propose two models to explain type B diogenite compositions in the north (1) deposition as Rheasilvia ejecta, or (2) type B plutons that were emplaced at shallow depths in the north polar region and sampled by local impacts. Lastly, using principal component (PC) analysis, we identify unique PC spaces for all HED lithologies, indicating that the corresponding GRaND measurables may be used to produce comprehensive lithologic maps for Vesta.     

Comparative study of dissolved organic matter from groundwater and surface water in the Florida coastal Everglades using multi-dimensional spectrofluorometry combined with multivariate statistics

Dissolved organic matter (DOM) in groundwater and surface water samples from the Florida coastal Everglades were studied using excitation–emission matrix fluorescence modeled through parallel factor analysis (EEM-PARAFAC). DOM in both surface and groundwater from the eastern Everglades S332 basin reflected a terrestrial-derived fingerprint through dominantly higher abundances of humic-like PARAFAC components. In contrast, surface water DOM from northeastern Florida Bay featured a microbial-derived DOM signature based on the higher abundance of microbial humic-like and protein-like components consistent with its marine source. Surprisingly, groundwater DOM from northeastern Florida Bay reflected a terrestrial-derived source except for samples from central Florida Bay well, which mirrored a combination of terrestrial and marine end-member origin. Furthermore, surface water and groundwater displayed effects of different degradation pathways such as photodegradation and biodegradation as exemplified by two PARAFAC components seemingly indicative of such degradation processes. Finally, Principal Component Analysis of the EEM-PARAFAC data was able to distinguish and classify most of the samples according to DOM origins and degradation processes experienced, except for a small overlap of S332 surface water and groundwater, implying rather active surface-to-ground water interaction in some sites particularly during the rainy season. This study highlights that EEM-PARAFAC could be used successfully to trace and differentiate DOM from diverse sources across both horizontal and vertical flow profiles, and as such could be a convenient and useful tool for the better understanding of hydrological interactions and carbon biogeochemical cycling.     

Photoluminescence of baratovite and katayamalite

The photoluminescence (PL) and optical excitation spectra of baratovite in aegirine syenite from Dara-i-Pioz, Tien Shan Mts., Tajikistan and katayamalite in aegirine syenite from Iwagi Islet, Ehime, Japan were obtained at 300 and 80 K. Under short wave (253.7 nm) ultraviolet light, baratovite and katayamalite exhibited bright blue-white luminescence. The PL spectrum of baratovite at 300 K consisted of a wide band with a peak at approximately 406 nm and a full width at half maximum (FWHM) of approximately 6.32k cm⁻¹. The excitation spectrum of the blue-white luminescence from baratovite at 300 K consisted of a prominent band with a peak at approximately 250 nm. The PL and excitation spectra of katayamalite were similar to those of baratovite. The luminescence from these minerals was attributed to the intrinsic luminescence from the TiO₆ center.     

Paragenesis of sodic pyroxene-bearing quartz schists: implications for the P-T history of the Sanbagawa belt

Sodic pyroxene (jadeite content X _jd=0.1–0.3) occurs locally as small inclusions within, albite porphyroblasts and in the matrix of hematite-bearing quartz schists in the Sanbagawa (Sambagawa) metamorphic belt, central Shikoku, Japan. The sodic, pyroxene-bearing samples are characteristically free from chlorite and their typical mineral assemblage is sodic pyroxene+subcalcic (or sodic) amphibole+phengitic mica+albite+quartz+hematite+titanite±epidote. Spessartine-rich garnet occurs in Mn-rich samples. Sodic pyroxene in epidote-bearing samples tends to be poorer in acmite content (average X _Acm=0.26–0.50) than that in the epidote-free samples (X _Acm=0.45–0.47). X _Jd shows no systematic relationship to metamorphic grade, and is different among the three sampling regions [Saruta-gawa, Asemi-gawa and Bessi (Besshi)]. The average X _Jd of the Saruta-gawa samples (0.21–0.29) is higher than that of the Asemi-gawa (0.13–0.17) and Bessi (0.14–0.23). The P-T conditions of the Asemi-gawa and Bessi regions are estimated at 5.5–6.5 kbar, >360°C in the chlorite zone, 7–8.5 kbar, 440±15°C in the garnet zone and 8–9.5 kbar, 520±25°C in the albite-biotite zone. Metamorphic pressure of the Saruta-gawa region is systematically 1–1.5 kbar higher than that of the Asemi-gawa and Bessi regions, and materials of the Saruta-gawa region have been subducted to a level 3–5 km deeper than materials that underwent metamorphism at equivalent temperatures and are now exposed in the Asemi-gawa and Bessi regions. Pressure slightly increases toward the north (structurally high levels) through the Sanbagawa belt of central shikoku. Two types of zonal structure were observed in relatively coarse-grained sodic pyroxenes in the matrix. One type is characterized by increasing X _Jd from core to rim, the other type by decreasing X _Jd from core to rim. Both types of zoned pyroxenes show an increase in X _{Fe 2+}[=Fe²⁺/(Fe²⁺+Mg)] from core to rim. The first type of zoning was observed in a sample from the chlorite zone of lowest grade, whereas the latter occurs in the garnet and albite-biotite zones of higher grade. The contrast in zonal structure implies that dP/dT during prograde metamorphism decreased with increasing metamorphic grade and may have been negative in some samples from the higher-grade zones. The estimated dP/dT of the prograde stage of the chlorite zone is 3.2 kbar/100°C, and that of the garnet and albite-biotite zones is -1.8 to 0.9 kbar/100°C. The variation of dP/dT at shallow and deep levels of a subduction system probably reflects the difference of heating duration and/or change in thermal gradient of the subduction zone by continuous cooling of the surrounding mantle.     

Structure and Evolution of the East Antarctic Lithosphere: Tectonic Implications for the Development and Dispersal of Gondwana

Lithospheric evolution of the Antarctic shield is one of the keystones for understanding continental growth during the Earth's evolution. Architecture of the East Antarctic craton is characterized by comparison with deep structures of the other Precambrian terrains. In this paper, we review the subsurface structure of the Lower Paleozoic metamorphic complex around the Lützow-Holm area (LHC), East Antarctica, where high-grade metamorphism occurred during the Pan-African orogenic event. LHC is considered to be one of the collision zones in the last stage of the formation of Gondwana. A geoscience program named ‘Structure and Evolution of the East Antarctic Lithosphere (SEAL)’ was carried out since 1996-1997 austral summer season as part of the Japanese Antarctic Research Expedition (JARE). Several geological and geophysical surveys were conducted including a deep seismic refraction/wide-angle reflection survey in the LHC. The main target of the SEAL seismic transect was to obtain lithospheric structure over several geological terrains from the western adjacent Achaean Napier Complex to the eastern Lower Paleozoic Yamato-Belgica Complex. The SEAL program is part of a larger deep seismic profile, LEGENDS (Lithospheric Evolution of Gondwana East iNterdisciplinary Deep Surveys) that will extend across the Pan-African belt in neighboring fragments of Gondwana.