Raman spectroscopic and calorimetric observations on natural gas hydrates with cubic structures I and II obtained from Lake Baikal

This study reports measurements of the Raman spectra of Lake Baikal gas hydrates and estimations of the hydration number of methane-rich samples. The hydration number of gas hydrates retrieved from the southern Baikal Basin (crystallographic structure I) was approx. 6.1. Consistent with previous results, the Raman spectra of gas hydrates retrieved from the Kukuy K-2 mud volcano in the central Baikal Basin indicated the existence of crystallographic structures I and II. Measurements of the dissociation heat of Lake Baikal gas hydrates by calorimetry (from the decomposition of gas hydrates to gas and water), employing the hydration number, revealed values of 53.7–55.5?kJ?mol^–1 for the southern basin samples (structure I), and of 54.3–55.5?kJ?mol^–1 for the structure I hydrates and 62.8–64.2?kJ?mol^–1 for the structure II hydrates from the Kukuy K-2 mud volcano.     

Application of an ecosystem model for the environmental assessment of the reclamation and mitigation plans for seagrass beds in Atsumi Bay

An ecosystem model was used to evaluate the effects of reclaiming seagrass beds and creating artificial shallows with seagrass beds to mitigate the effects of the reclamation. The applied model can simulate the pelagic and benthic ecosystems including seagrass beds and tidal flats. The objectives of this study were (a) to investigate the likelihood of cultivating and maintaining seagrass beds in artificial shallows (Part 1), and (b) to understand the effects of the reclamation of seagrass beds and the creation of artificial shallows on the water quality in the estuary (Part 2). In Part 1, first, the nutrient turnover rates due to both biochemical and physical processes in the natural seagrass beds where reclamation is proposed were analyzed. Biological processes rather than physical processes were the most significant driving forces of nutrient cycles in seagrass beds. Second, the effects of filter feeding benthic fauna (suspension feeders) in the seagrass beds were analyzed. The scenario with suspension feeders resulted in higher transparency of the water column (8.7% decrease in the light attenuation coefficient) and an increase in nutrient supply (24.9% increase in NH₄-N in the water column) contributing to the high specific growth rate of seagrass. Third, the specific growth rate of seagrass on the proposed artificial shallows was measured. The value on the artificial shallows set at a depth of datum line minus 0.8 m (D.L. − 0.8 m) was approximately the same as that of the natural seagrass beds. In Part 2, first, water quality in the estuary was compared among the scenarios with/without natural seagrass beds and artificial shallows. Then, the defined values of the water purification capability of (a) artificial shallows with/without seagrass beds, and (b) natural seagrass beds per unit area were evaluated. The reclamation of the natural seagrass beds resulted in a decrease of the removal of phytoplankton and detritus from the pelagic system (i.e. resulted in a loss in the purification rate). In contrast, the creation of artificial shallows resulted in an increase of the removal of phytoplankton and detritus from the pelagic system (i.e. resulted in a gain in the purification rate). Based on an annual average, approximately twice as much phytoplankton was removed from the artificial shallows at the depth D.L. − 0.8 m, than at the depth, D.L. − 1.5 m, and the artificial shallows with seagrass beds removed pelagic DIN and DIP at a rate 120% higher than that without seagrass beds.     

CO<Subscript>2</Subscript> Flux Measurements over the Sea Surface by Eddy Correlation and Aerodynamic Techniques

The measurements of the vertical transport of CO₂ were carried out over the Sea of Japan using the specially designed pier of Kyoto University on September 20 to 22, 2000. CO₂ fluxes were measured by the eddy correlation and aerodynamic techniques. Both techniques showed comparable CO₂ fluxes during sea breeze conditions: −0.001 to −0.08 mg m⁻²s⁻¹ with the mean of −0.05 mg m⁻²s⁻¹. This means that the measuring site satisfies the fetch requirement for meteorological observations under sea breeze conditions. Moreover, the eddy diffusivity coefficient used in the aerodynamic technique is found to be consistent with the coefficient used in the eddy correlation technique. The present result leads us to conclude that the aerodynamic technique may be applicable to underway CO₂ flux measurements over the ocean and may be used in place of the bulk technique. The important point is the need to maintain a measuring accuracy of CO₂ concentration difference of the order of 0.1 ppmv on the research vessels or the buoys.     

Finite‐element analysis of laminated rubber bearing of building frame under seismic excitation

Finite element analysis is carried out for a building frame supported by laminated rubber bearings to simultaneously investigate global displacement and local stress responses under seismic excitation. The frame members and the rubber bearings are discretized into hexahedral solid elements with more than 3 million degrees of freedom. The material property of rubber is represented by the Ogden model, and the frame is assumed to remain in elastic range. It is shown that the time histories of non‐uniform stress distribution and rocking behavior of the rubber bearings under a frame subjected to seismic excitation can be successfully evaluated, and detailed responses of base and frame can be evaluated through large‐scale finite element analysis. Copyright © 2015 John Wiley & Sons, Ltd.     

Determination of Bromine and Iodine in Twenty-three Geochemical Reference Materials by ICP-MS

Trace amounts (from nanogram to microgram levels) of bromine and iodine were determined by inductively coupled plasma-mass spectrometry (ICP-MS) in twenty-three geochemical reference materials issued by the GSJ, USGS, IAEA etc. The pyrohydrolysis technique was used to separate bromine and iodine from samples analysed in the form of powder. The accuracy and precision of the experimental values were assessed by the comparative analysis of well established reference materials such as USGS AGV-1, BCR-1 and IGGE GBW07312. The measured values agreed well with reported values within a 10% error range. We also report reliable new data for these elements in these geochemical reference materials.     

InFOCμS Hard X-ray Imaging Telescope

InFOCμS is a new generation balloon-borne hard X-ray telescope with focusing optics and spectroscopy. We had a successful 22.5-hour flight from Fort Sumner, NM on September 16,17, 2004. In this paper, we present the performance of the hard X-ray telescope, which consists of a depth-graded platinum/carbon multilayer mirror and a CdZnTe detector. The telescope has an effective area of 49 cm² at 30 keV, an angular resolution of 2.4 arcmin (HPD), and a field of view of 11 arcmin (FWHM) depending on energies. The CdZnTe detector is configured with a 12 × 12 segmented array of detector pixels. The pixels are 2 mm square, and are placed on 2.1 mm centers. An averaged energy resolution is 4.4 keV at 60 keV and its standard deviation is 0.36 keV over 128 pixels. The detector is surrounded by a 3-cm thick CsI anti coincidence shield to reduce background from particles and photons not incident along the mirror focal direction. The inflight background is 2.9 × 10⁻⁴ cts cm⁻² sec⁻¹ keV⁻¹ in the 20–50 keV band.     

Observation of cosmic soft X-rays

Cosmic X-rays in the energy range between 0.210 keV were observed with polypropylene window proportional counters on board a sounding rocket. The field of view crossed the galactic plane in the Sgr region and reached galactic latitudes of 50° and –90°. A new soft X-ray source was found in the Aries-Taurus region. The soft X-ray flux from the direction of NGC 1275 was conspicuous, whereas that of Sgr region source were very weak. The distribution of the intensity of diffuse soft X-rays over the scanned region indicates the galactic emission of soft X-rays.     

Driftwood deposition from debris flows at slit-check dams and fans

Experience shows that debris flows containing large woody debris (driftwood) can be more damaging than debris flows without driftwood. In this study, the deposition process of debris flows carrying driftwood was investigated using numerical simulations and flume experiments. Debris-flow trapping due to driftwood jamming in a slit-check dam was also investigated. A numerical model was developed with an interacting combination of Eulerian expression of the debris flow and Lagrangian expression of the driftwood, in which the fluctuating coordinates and rotation of the driftwood were treated stochastically. The calculated shapes and thicknesses of a debris-flow fan and the positions and orientations of the deposited driftwood on a debris-flow fan were consistent with experimental flume results. The jamming of driftwood in a slit-check dam was evaluated based on geometry and probability. The simulated results of outflow discharge and the proportion of driftwood passed through the slit-check dam also agreed with the experimental results.     

Speciation of reduced C-O-H volatiles in coexisting fluids and silicate melts determined in-situ to ∼1.4 GPa and 800 °C

The structure of silicate melts in the system Na₂O·4SiO₂ saturated with reduced C-O-H volatile components and of coexisting silicate-saturated C-O-H solutions has been determined in a hydrothermal diamond anvil cell (HDAC) by using confocal microRaman and FTIR spectroscopy as structural probes. The experiments were conducted in-situ with the melt and fluid at high temperature (up to 800 °C) and pressure (up to 1435 MPa). Redox conditions in the HDAC were controlled with the reaction, Mo + H₂O = MoO₂ + H₂, which is slightly more reducing than the Fe + H₂O = FeO + H₂ buffer at 800 °C and less.The dominant species in the fluid are CH₄ + H₂O together with minor amounts of molecular H₂ and an undersaturated hydrocarbon species. In coexisting melt, CH₃ - groups linked to the silicate melt structure via Si-O-CH₃ bonding may dominate and possibly coexists with molecular CH₄. The abundance ratio of CH₃ - groups in melts relative to CH₄ in fluids increases from 0.01 to 0.07 between 500 and 800 °C. Carbon-bearing species in melts were not detected at temperatures and pressures below 400 °C and 730 MPa, respectively. A schematic solution mechanism is, Si-O-Si + CH₄?Si-O-CH₃+H-O-Si. This mechanism causes depolymerization of silicate melts. Solution of reduced (C-O-H) components will, therefore, affect melt properties in a manner resembling dissolved H₂O.