Evidence of Microbial Activity in the Formation of Manganese Wads at the Asahidake Hot Spring in Hokkaido, Japan

Abstract. Mt. Asahidake is an active volcano, with more than 90 active wells, in the Daisetsu volcanic group located in central Hokkaido, Japan. Wells along the Yukomanbetsu-sawa River showed high manganese concentrations and associated manganese deposits. These deposits consist of manganese oxides, and the concentration of iron is very low except for one sample collected from the upper reach of the river. Most of the wet samples showed basal diffraction characteristic of todorokite (9.6 Å). Cultivation tests showed that microorganisms were responsible for the oxidation of dissolved Mn²⁺ in the Asahidake hot spring. The dissolved Mn²⁺ concentration in the sterilized hot spring water was unchanged after four days, whereas the Mn²⁺ concentration in the sterilized hot spring water with a small amount of fresh manganese wad was decreased to zero after three days, and manganese oxide formed. This result implies that the activity of microorganism oxidizes dissolved Mn²⁺ and forms manganese oxide at the Asahidake manganese deposits. In addition to Komanoyu hot spring and Yunotaki Falls, this is the third report of microbial activity forming considerable deposits of manganese oxides in hot spring waters.     

Measurements of electric charge distribution in volcanic plumes at Sakurajima Volcano,Japan

Measurements of perturbations in the atmospheric potential gradient around volcanic plumes at multiple (from two to five) sites, and measurements of the charge-mass ratio of ash particles falling from volcanic plumes, were carried out at Sakurajima Volcano, Japan. Results from 28 and 29 October 1995, show that the nature of the perturbations depends on the intensity of plume activity. Although plume activity was vigorous on 28 October, negative perturbations were predominant. As plume activity peaked, the magnitude of negative perturbations decreased just below the plume and increased at an off-axis site. During the peak period, positively charged ash particles fell out from the plume. This suggests that the active plume dominantly contained negatively charged materials, and that positively and negatively charged materials were added to the lower and upper parts of the plume, respectively, during the peak period. On the other hand, as plume activity became less vigorous on 29 October, the perturbations were characterized by a positive anomaly followed by a negative anomaly. Because wind velocity increased with altitude that day, we infer that positive and negative charges were distributed in the upper and lower parts of the plume, respectively. The differences in perturbations observed on 28 and 29 October suggest that volcanic plumes are generally composed of three parts: an upper part with positively charged gas and aerosol, a middle part with negatively charged fine ash particles, and a lower part with positively charged coarse ash particles. The compilation of present and previous results from Sakurajima and other volcanoes indicates that the effect of the negative charge in the middle part was predominant in most cases, although positive perturbations caused by the upper part were observed around some weak plumes. The effect of positively charged particles in the lower part was observable only when plume activity was sufficiently strong because positively charged coarse particles tended to fall out near the vent.     

Correlation between dissolved He concentration and Cl in groundwater at Äspö, Sweden

Tunnel excavation at Äspö Island, Sweden, has caused severe groundwater disturbance, gradually extending deeper into the tunnel as present-day Baltic seawater intrudes through fractures connecting to the surface. However, the paleo-hydrogeochemical conditions have remained in the deep highly saline waters that have avoided mixing. A correlation has been observed between dissolved ⁴He concentration and Cl⁻ ion concentration, measured every two years from 1995 to 2001 at Äspö. Groundwater mixing conditions can be examined by the correlations between 1/Cl, ³⁶Cl/Cl, and ³H concentrations. Subsurface production is responsible for the majority of the ³⁶Cl and excess dissolved ⁴He of interstitial groundwater in fractures. The secular equilibrium ratio of ³⁶Cl/Cl in rock was theoretically estimated to be (5.05 ± 0.82) × 10⁻¹⁴ based on the neutron flux intensity, a value comparable to the measured ³⁶Cl/Cl ratio in rock and groundwater. The degassing crustal ⁴He flux was estimated to be 2.9 × 10⁻⁸  1.3 × 10⁻⁶ (ccSTP/cm²a) using the HTO diffusion coefficient for the Äspö diorite. The ⁴He accumulation rate ranges from 6.8 × 10⁻¹⁰ (for the in situ accumulation rate) to 7.0 × 10⁻⁹ (ccSTP/(g_water · a) considering both ⁴He in situ production and the degassing flux, assuming ⁴He is accumulated constantly in groundwater. By comparing the subsurface ³⁶Cl increase with ⁴He concentrations in groundwater, the ⁴He accumulation rate was determined from data for groundwater arriving at the secular equilibrium of ³⁶Cl/Cl. The ⁴He accumulation rate was found to be (1.83 ± 0.72) × 10⁻⁸ ccSTP/(g_water · a) without determining the magnitude of degassing ⁴He flux.     

Meteor Orbit Determinations with Multistatic Receivers Using the MU Radar

The MU radar of RISH (Research Institute for Sustainable Humanosphere, Kyoto University), which is a MST radar (46.5 MHz, 1 MW peak power), has been successfully applied to meteor studies by using its very high versatility. The system has recently renewed with 25 channel digital receivers which significantly improved the sensitivity and precision of interferometer used in meteor observation. The transmission is now synchronized to GPS signals, and two external receiving sites with a ranging capability has additionally been operated in order to determine the trajectories and speeds of meteoroids.     

Characterization of low-temperature pyroclastic surges that occurred in the northeastern Japan arc during the late 19th century

Three eruption events occurring in the central part of the northeastern Japan arc were investigated and compared: Adatara AD1900, Zao AD1895, and Bandai AD1888. Producing low-temperature (LT) pyroclastic surges, these events are characterized by steam eruptions ejecting no juvenile material. These eruptions' well-preserved eruptive deposits and facies facilitated granulometric analyses of the beds, which revealed the transport and deposition mechanisms of LT surges. Combining these results with those of investigations of documents reporting the events, we correlated each eruption to the relevant individual bed and reconstructed the LT surge development sequence. Important findings related to the transport and deposition modes are the following. (1) Bed sets consisting of thin, laminated ash and its overlying thick massive tuff were recognized in the Adatara 1900 proximal deposits. The bed set was probably produced by a strong wind that discharged and propagated quickly from the vent (leading wind) and a gravitationally segregated, highly concentrated flow originated from the eruption column, within a discrete eruption episode. A similar combination might have occurred during the first surge of the Bandai 1888 event. (2) Comparison of the proximal and distal facies for the largest eruption of Adatara 1900 event indicates that the initial turbulence of the eruption cloud decreased rapidly, transforming into a density-stratified surge with a highly concentrated part near the base. Similar surges occurred in the climatic stage of Zao 1895. (3) Bandai 1888 ejecta indicate massive beds deposited preferentially at topographic lows. Co-occurring planar beds showed no topographic affection, as indicated by the topographic blocking of a stratified surge. The observed facies–massive tuffs, crudely stratified tuffs, and thin bedded tuffs–are compatible with those for high-temperature surges. At Bandai, absence of dune bedded tuffs and commonly poorer sorting in the LT surge deposits might be attributable to poor thermally induced turbulence of eruption columns. Condensation of vapor in the surges might have contributed to the poor sorting. The estimated explosion energies were 6 × 10¹³ J for Adatara AD1900, 6.5 × 10¹⁰ J for Zao AD1895, and 6.5 × 10¹⁵ J for Bandai AD1888, implying that the three events were hydrothermal eruptions with distinctive eruptive mechanisms. Regarding eruption sources, the Adatara 1900 event was caused solely by thermal energy of the hydrothermal fluid, although magma intrusion likely triggered evolution of hydrothermal systems at Zao in 1895. Steam eruptions in the Bandai 1888 event occurred simultaneously with sudden exposure of the hydrothermal system, whose triggers require no internal energy.     

High resolution OSL dating back to MIS 5e in the central Sea of Okhotsk

Marine sediments contain important archives of past ocean and climate changes, but at high latitudes the absence of carbonate has prevented the construction of accurate chronological models. We have begun a study to (1) determine the accuracy of luminescence ages in deep-sea marine sediments, e.g. by comparison with marine oxygen isotope stratigraphy where possible, (2) describe changes in sedimentation rate through time, and (3) test whether it is possible to date back to marine isotope stage 5e (MIS 5e). We show here that optical dating of fine grains of quartz from the central Sea of Okhotsk is able to provide an accurate and precise chronology for the reconstruction of the palaeoceanic and palaeoclimatic environment at our site. The upper 6.5 m of the 18.42 m long core MR0604-PC07A is believed, based on its magnetic susceptibility and the oxygen isotope (δ¹⁸O) records to contain the last ～150 ka. Forty OSL samples were taken from this upper part of the core. The single-aliquot regenerative-dose (SAR) procedure is used for equivalent dose (D_e) determination. The luminescence characteristics of fine-grained quartz (4–11 μm) extracted from the core are described. The OSL signal is dominated by the fast component and a dose recovery test shows that we can accurately measure a known dose given in the laboratory prior to any heat treatment. Dose rates were determined using high-resolution gamma spectrometry, and vary between 0.4 and 1.6 Gy/ka. The OSL ages from this section lie between ～140 ka and ～15 ka and are in very good agreement with the δ¹⁸O stratigraphy up to MIS 5e. A clear change in sedimentation rate is identified: between ～139 and 110 ka, the sedimentation rate was ～0.09 m/ka, but then from ～110 to 15 ka, the sedimentation rate decreases to a constant value of ～0.04 m/ka. Our data confirm that OSL dating using widely distributed fine-grain quartz has great potential for dating deep-sea sediments. Because luminescence methods use clastic materials, they do not depend on the presence of biogenic carbonate. As a result it is now likely that we can establish a chronology in regions of the ocean that were previously undatable.     

Hahajima Seamount: An enigmatic tectonic block at the junction between the Izu–Bonin and Mariana Trenches

Abstract   The Hahajima Seamount, located at the junction between the Izu–Bonin and Mariana forearc slopes, is a notable rectangular shape and consists of various kinds of rocks. An elaborated bathymetric swath mapping with geophysical measurements and dredge hauls showed the Hahajima Seamount is cut by two predominating lineaments, northeast–southwest and northwest–southeast. These lineaments are of faults based on the topographic cross-sections and a 3-D view (whale's eye view). The former lineament is parallel to the transform faults of the Parece Vela Basin, whereas the latter is parallel to the nearby transform fault on the subducting Pacific Plate. The rocks constituting the seamount are ultramafic rocks (mostly harzburgite), boninite, basalt, andesite, gabbro, breccia and sedimentary rocks, which characterize an island arc and an ocean basin. Gravity measurement and seismic reflection survey offer neither a definite gravity anomaly at the seamount nor definite internal structures beneath the seamount. A northwest–southeast-trending fault and small-scale serpentine flows were observed during submersible dives at the Hahajima Seamount. The rectangular shape, size of the seamount, various kinds of rocks and geophysical measurements strongly suggest that the Hahajima Seamount is not a simple serpentine seamount controlled by various tectonic movements, as previously believed, but a tectonic block.     

Frictional discharge at fault asperities: Origin of fractal seismo-electromagnetic radiation

To investigate the relation between the rock friction and the fractal electromagnetic radiation before the main-shock of earthquakes, we conducted a friction experiment simulating the motion of an asperity on a fault plane, and observed photon emissions due to electric discharge by dielectric breakdown of ambient gases from friction contacts between rock minerals. This indicates that frictional discharges (plasma generations) could occur locally at microscopic asperities on fault surfaces. From concepts on the fractal size-distribution and temporal evolution of fault asperities, the frictional discharge occurring at asperities on the fault plane can be one of origins of the fractal electromagnetic radiation (Benioff electromagnetic radiation) prior to earthquakes.     

Comparison of stable isotopes,ratios of Cl/Cl and I/I in brine and deep groundwater from the Pacific coastal region and the eastern margin of the Japan Sea

Fifty-three samples, including brines associated with oil and natural gas reservoirs and groundwater samples from deep boreholes, were collected from the Pacific and Japan Sea coastal regions in Japan. The ¹²⁹I/¹²⁷I and ³⁶Cl/Cl ratios, and stable isotopes (δD and δ¹⁸O) are compared to investigate differences related to the geotectonic settings of the two regions. The δD and δ¹⁸O data indicate that brine and groundwater from the Pacific coastal region reflect mixing of meteoric water with connate seawater in the pores of sedimentary rocks. On the other hand, brine and groundwater from the Japan Sea coastal region have been hydrothermally altered. In particular, brines associated with petroleum accumulations at Niigata and Akita showed the same isotopic characteristics as fluids found in the Kuroko deposits of the Green Tuff region in northeastern Japan. There is little difference in the ³⁶Cl/Cl ratios in brine and groundwater from the Pacific and Japan Sea coasts. Most brine and some deep groundwater, except those from the Pleistocene Kazusa Group, have already reached the average secular equilibrium ratio of 9.9 ± 2.7 × 10⁻¹⁵ for their mudstone and sandstone reservoirs. There was no correlation between the ³⁶Cl/Cl ratios and differences in geotectonic setting between the Pacific and the Japan Sea coast. The molar I/Br ratio suggests that the I in all of water samples was of biogenic origin. The average ¹²⁹I/¹²⁷I ratio was 290 ± 130 × 10⁻¹⁵ to 294 ± 105 × 10⁻¹⁵ in both regions, showing no relationship to the different geotectonic settings. The uncontaminated brine and groundwater samples are likely to have retained the original ¹²⁹I/¹²⁷I ratios of marine I released from the old organic matter stored in sedimentary rock.