Environmental geochemistry of an active Hg mine in Xunyang,Shaanxi Province,China

The Xunyang Hg mine (XMM) situated in Shaanxi Province is an active Hg mine in China. Gaseous elemental Hg (GEM) concentrations in ambient air were determined to evaluate its distribution pattern as a consequence of the active mining and retorting in the region. Total Hg (HgT) and methylmercury (MeHg) concentrations in riparian soil, sediment and rice grain samples (polished) as well as Hg speciation in surface water samples were measured to show local dispersion of Hg contamination. As expected, elevated concentrations of GEM were found, ranging from 7.4 to 410 ng m⁻³. High concentrations of HgT and MeHg were also obtained in riparian soils, ranged from 5.4 to 120 mg kg⁻¹ and 1.2 to 11 μg kg⁻¹, respectively. Concentrations of HgT and MeHg in sediment samples varied widely from 0.048 to 1600 mg kg⁻¹ and 1.0 to 39 μg kg⁻¹, respectively. Surface water samples showed elevated HgT concentrations, ranging from 6.2 to 23,500 ng L⁻¹, but low MeHg concentrations, ranging from 0.022 to 3.7 ng L⁻¹. Rice samples exhibited high concentrations of 50–200 μg kg⁻¹ in HgT and of 8.2–80 μg kg⁻¹ in MeHg. The spatial distribution patterns of Hg speciation in the local environmental compartments suggest that the XMM is the source of Hg contaminations in the study area.     

相对弱势群体的城市包容性感知与影响因素分析

城市化过程中包容性价值观的缺失导致城市社会走向分化,高质量的城市化是要建设人人共享的包容城市。通过明确城市包容性感知内涵的7个维度及26个评价要素,使用2020年城市体检问卷调查数据,评价老年群体、低收入群体、低学历群体和外地人4类相对弱势群体的城市包容性感知,并检验个体属性、客观城市特征以及主观感知等因素对居民包容性感知的影响。结果发现：年龄、收入、户籍差别导致的居民包容性感知差距较大,不同学历群体的包容性感知差距较小。4类相对弱势群体的包容性感知在城市之间均存在明显差别。包容性感知因个体属性特征和城市客观特征而异,中小城市居民包容性感知显著更低,常住人口占比、住房可支付能力、人均住房面积、人口密度对于包容性感知有正向促进作用。多项要素的主观感知与包容性感知显著相关,社会治安、对弱势群体友好性、邻里关系以及综合医院的满意度是影响4类相对弱势群体包容性感知的共性因素。     

Geochronology and geochemistry of the Late Triassic Longtan pluton in South China: termination of the crustal melting and Indosinian orogenesis

The Indosinian orogeny is recorded by Triassic angular unconformities in Vietnam and South China and by widely occurring granitoids in the Yunkai-Nanling and the Xuefengshan belts of South China. The Longtan pluton in the northwestern part of the Xuefengshan belt is a typical high-K, calc-alkaline, I-type granitoid, which can shed light on the relationship between the Indosinian tectonic and magmatic activity in the region. Three precise zircon U–Pb ages yielded a mean of 218 ± 0.8 Ma, which is taken as the age of crystallization. The pluton consists of both granodiorite (64.59–68.01 % SiO₂ and 3.25–4.22 % K₂O) and granite (70.49–71.80 % SiO₂ and 4.07–4.70 % K₂O). The granodiorites are characterized by relatively high Mg# (54–57), low contents of Na₂O (3.2–4.3 wt%), low abundances of incompatible elements (LILE, Nb and P), high initial ⁸⁷Sr/⁸⁶Sr (0.7175–0.7184) and negative ε_Nd(t) (?9.98 to ?9.72). REE patterns show moderate fractionation ((La/Yb)_cn = 8.07–18.80) with negative Eu anomalies (Eu/Eu* = 0.62–0.86). Compared with the granodiorite, the granite has a wider range of Mg# (49–59), lower contents of Na₂O (2.8–4.2 wt%), higher initial ⁸⁷Sr/⁸⁶Sr (0.7232–0.7243) and more negative ε_Nd(t) (?12.07 to ?11.24) values. REE patterns are relatively flat ((La/Yb)_cn = 14.73–29.37) with smaller negative Eu anomalies (Eu/Eu* = 0.48–0.63). The granodiorite has lower K₂O/Na₂O and Al₂O₃/(MgO + FeO_Tot) values than the granite. Based on major and trace element geochemistry and Sr–Nd isotopes, we interpret the Longtan granodioritic magma to have been derived by partial melting of interlayered Proterozoic metabasaltic to metatonalitic source rocks, whereas the granite was probably derived from a mixture of Proterozoic metagraywackes and metaigneous rocks. Field, petrographic and geochemical evidence indicate that partial melting and fractional crystallization were the dominant mechanism in the evolution of the pluton. The Longtan granodiorites and granites are petrologically and geochemically similar to typical Indosinian varieties and are considered to have been produced in a similar manner. The Indosinian granitoids in the region show a magmatic peak age of ~238 Ma from the Yunkai-Nanling belt in the southeast and a magmatic peak age of ~218 Ma of the Xuefengshan belt to the northwest. These early and late magmatic episodes of the Indosinian granitoids also display slight variations of regular compositions, ε_Nd(t) values and T _DM ages. Thus, we propose a syncollisional extension model that Indosinian granitoids were generated by decompressional partial melting of crustal materials triggered by two extensions during collision of the Indochina and South China blocks. The Longtan pluton in the northwesternmost part of the orogenic belt marks the termination of the Indosinian magmatism and orogenesis.     

风积沙漠地区三维地震勘探资料处理中Q补偿应用实例

在有效波组为低频、低噪且地质任务以小构造解释为目标的地区,采用Q补偿技术有利于提高有效波组的主频,达到提高纵向分辨率的目的。以鄂尔多斯某勘探区为例,采用Q值补偿技术,以克服该区沙漠地貌明显的吸收衰减滤波效应问题,提高其地震资料的中、高频成分。通过对Q补偿参数进行测试,发现Q值为50时有效波响应明显。应用结果表明,经Q补偿后,地震时间剖面有效波主频明显提高,DF7、DF8断层在补偿后的地震时间剖面上较补偿前断点更清晰、位置解释误差更少。     

全球生态地质环境遥感调查研究

全球生态地质环境是世界共同关注的一项热点问题,我国在国内已经开展了大量生态地质环境的相关研究,但是从宏观上去分析研究整个生态地质环境系统为数不多。本文从全球的角度出发,将植被、冰川、沙漠化和碳酸盐岩等4类确定为生态地质环境因子,通过卫星遥感技术,提取大量相关信息,并选择性开展生态地质环境与全球气候变化关系的研究。     

Source and commingling features of light oils from the Chepaizi uplift in the Junggar Basin,Northwest China

Geochemical composition characteristics of light oils from the Tertiary in the west of the Chepaizi uplift in the Junggar basin, northwest China, are distinct from those of biodegraded oils derived from the Permian in the study area and crude oils from some adjacent oil fields such as the Chepaizi and Xiaoguai oilfields. Oil source correlation shows that light oils in the study area have similar n-alkane and isoprenoid distribution patterns and carbon isotope compositions with the coal-derived oils from the Jurassic, and display obvious discrepancy on biomarker composition characteristics with the Cretaceous source rock extracts, inferring that they are probably the mixed oils from the Jurassic coal measures and Cretaceous source rocks. In this study, combined with the geochemical data of coal-derived oils from the Jurassic and Cretaceous source rocks or crude oils from the Cretaceous, the source and commingling features of the Tertiary crude oils of Well Pai 2 and Well Pai 8 were investigated. The proportion of the two sources in the mixed crude oils was estimated, and the hydrocarbon accumulation pattern of reservoirs in the study area was established.     

长江中下游江湖水沙调控数值模拟

以长江中下游防洪系统为对象,在大型复杂防洪系统洪水运动数值模拟基础上,成功地将面向长江中下游防洪规划论证需求的洪水演进数学模型转化为面向长江防洪系统江湖水沙调控需求的长江中下游江湖水沙调控数学模型.为适应江湖水沙调控和评估的要求,提出了基于水动力学的闸坝调度计算模式.此外,还对河网分汊泥沙分配模式进行了深入研究.通过长江中下游防洪规划及其洞庭湖区"控支强干"方案论证模拟计算,较好地解决了防洪措施蓄泄后效评估和工程优化调控模式等关键难题,为防洪规划方案的制定提供了定量依据,主要成果已应用于长江中下游防洪规划方案.     

长江中下游江湖蓄泄关系实时评估数值模拟

以长江中下游防洪系统为对象,将面向长江中下游防洪规划论证需求的水沙数学模型转化为面向长江防洪系统防汛方案评估需求的长江中下游蓄泄关系实时评估数学模型.为适应实时蓄泄评估快速、准确的要求,提出了基于水动力学的循环滚动计算模式、实时校正模式和实时防洪调度的试验机制.实现了水文学实时校正方法与水动力学数学模型的耦合,建立了基于水动力学的实时校正模式.为了满足长江中下游江湖蓄泄关系实时评价的需求,探讨了洪水模拟与分蓄洪调度模式的耦合.通过长江中下游防汛期间的试运行,较好地解决了防洪措施蓄泄关系评估和工程优化调控模式等关键难题,为防洪规划方案的制定和实时洪水调度方案优化提供了定量的依据,主要成果已应用于长江中下游防洪规划和防汛调度方案中.     

中亚造山带中新生代壳幔相互作用特征与过程——新疆北部幔源岩浆岩系对比研究

新疆北部中新生代幔源岩浆岩多位于大型走滑断裂带或者裂谷带附近,岩石系列均具有高的TiO_2含量,富碱、高度富集不相容元素和轻稀土(LREE),ε_(Nd)(t)值低正值到负值,(~(87)Sr/~(86)Sr)_i值较高,不相容元素比值La/Nb和Nb/U显示中新生代玄武岩浆在形成过程中的壳幔作用明显不同于古生代造山过程,岩浆来源于类似OIB源的富集地幔。而新疆北部地区的二叠纪幔源镁铁-超镁铁岩来源于亏损地幔,陆壳物质参与了岩浆的形成,源区可能混入了早期的弧组分或俯冲的洋壳。由于古生代多个洋盆闭合和增生造山作用致使中亚造山带的岩石圈不断增厚,于古生代晚期发生拆沉去根作用,软流圈亏损地幔上涌形成二叠纪镁铁-超镁铁岩系,而拆沉的岩石圈以及俯冲下沉的洋壳及其沉积物,在地幔环境熔融交代改造原始地幔,使中亚地区的地幔自古生代晚期以后逐渐转换为整体富碱、富含轻稀土(LREE)和不相容元素的富集地幔。被改造了的富集地幔在中新生代沿裂谷带或大型走滑断裂薄弱带上涌,形成了中新生代幔源岩浆的喷发和侵位。     

Copper complexation by fulvic acid affects copper toxicity to the larvae of the polychaete Hydroides elegans

Copper toxicity is influenced by a variety of environmental factors including dissolved organic matter (DOM). We examined the complexation of copper by fulvic acid (FA), one of the major components of DOM, by measuring the decline in labile copper by anodic stripping voltammetrically (ASV). The data were described using a one-site ligand binding model, with a ligand concentration of 0.19micromol site mg(-1) C, and a logK' of 6.2. The model was used to predict labile copper concentration in a bioassay designed to quantify the extent to which Cu-FA complexation affected copper toxicity to the larvae of marine polychaete Hydroides elegans. The toxicity data, when expressed as labile copper concentration causing abnormal development, were independent of FA concentration and could be modeled as a logistic function, with a 48-h EC(50) of 58.9microgl(-1). However, when the data were expressed as a function of total copper concentration, the toxicity was dependent on FA concentration, with a 48-h EC(50) ranging from 55.6microgl(-1) in the no-FA control to 137.4microgl(-1) in the 20mgl(-1) FA treatment. Thus, FA was protective against copper toxicity to the larvae, and such an effect was caused by the reduction in labile copper due to Cu-FA complexation. Our results demonstrate the potential of ASV as a useful tool for predicting metal toxicity to the larvae in coastal environment where DOM plays an important role in complexing metal ions.