Thermodynamic characterization of boltwoodite and uranophane: Enthalpy of formation and aqueous solubility

Boltwoodite and uranophane are uranyl silicates common in oxidized zones of uranium ore deposits. An understanding of processes that impact uranium transport in the environment, especially pertaining to the distribution of uranium between solid phases and aqueous solutions, ultimately requires determination of thermodynamic parameters for such crystalline materials. We measured formation enthalpies of synthetic boltwoodites, K(UO₂)(HSiO₄)·H₂O and Na(UO₂)(HSiO₄)·H₂O, and uranophane, Ca(UO₂)₂(HSiO₄)₂·5H₂O, by high temperature oxide melt solution calorimetry. We also studied the aqueous solubility of these phases from both saturated and undersaturated conditions at a variety of pH. The combined data permit the determination of standard enthalpies, entropies and Gibbs free energies of formation for each phase and analysis of its potential geological impact from a thermodynamic point of view.     

Acoustic Monitoring of Gas Emission Processes in the Arctic Shelf Seas

Oceanology - The emission of natural gas from the seafloor to the surface in shelf areas of the Arctic seas is of increasing interest among researchers. Recently, various types of acoustic...     

Sensitivity to stress of the estuarine bivalve Macoma balthica from areas between the Netherlands and its southern limits (Gironde)

Variation in the sensitivity to stress of Macoma balthica was measured in several French and Dutch estuaries. For adult and juvenile Macoma balthica exposed to copper under conditions of starvation, differences in mortality rate, condition, glycogen, burrowing rate and copper content were assessed. No significant differences were observed between adults and juveniles; the influence of treatment and origin was always evident. Animals from the most southern estuaries, Loire and Gironde, near to the species's southern limit of distribution, showed, in the field, the strongest deviations for the ecophysiological traits measured, and were in the experiments the most sensitive to stress.     

Spatial variation in low-level <Superscript>134</Superscript>Cs in the coastal sediments off central Honshu in the Sea of Japan: implications for delivery,migration, and redistribution patterns

In 2014 and 2015, we examined the spatial distribution of cesium-134 (half-life: 2.06 years) from the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) in marine sediments within coastal–basin areas (water depths of 40–520 m) off central Honshu Island (the main island of Japan) in the Sea of Japan. The ¹³⁴Cs concentrations in both the surface sediment (0–1 cm depth) and whole-core inventory exhibited wide variations, and were highest at the site closest to the Agano River Estuary area (6.7 Bq/kg-dry and 886 Bq/m², respectively). This indicates that ¹³⁴Cs in coastal areas was delivered by riverine suspended solids (SS). Given the spatial variation in ¹³⁴Cs concentrations, we believe that ¹³⁴Cs partially migrated northeastward within ~50 km along Honshu Island (at water depths shallower than ~140 m), and southwestward, including the Sado Basin area. This is predominantly attributable to the transport of SS by bottom currents and unsteady downward delivery onto the steep slopes of the basin. The total amount of ¹³⁴Cs in the study area in 2014 was estimated at approximately 0.6 TBq (decay-corrected to March 11, 2011, date of FDNPP accident).     

TOPEX Constrained Solution of Mean Sea Surface by Joint Processing of TOPEX,ERS-1 and GEOSAT Altimetric Measurements

We present an improved crossover adjustment procedure to determine mean sea surface height using TOPEX, 35-day repeat phase ERS-1, Geosat, and 168-day repeat phase ERS-1 satellite altimeter data. The mean sea surface frame defined by the TOPEX data is imposed as certain constraints in our crossover adjustment procedure rather than held fixed as in some other procedures. The new procedure is discussed in detail. Equations are developed to incorporate the a priori information of Topex data as well as other satellite altimeter data. The numerical computation result shows that the rms crossover discrepancies are reduced by an order of 1 cm when the Topex data is not fixed. Furthermore, the computed mean sea surface is less noisy and more realistic than that computed by the traditional procedure.     

Role of Vertical Resolution in Numerical Models Towards the Intensification,Structure and Track of Tropical Cyclones

The impact of vertical resolution on the evolution and movement of tropical cyclones was studied using NCAR MM5 model with a horizontal resolution of 9 km. Four numerical experiments were performed with different vertical resolutions, that is, with 23 vertical levels as control experiment, and 36 vertical levels with high resolution in the lower troposphere, 33 vertical levels with high resolution in the upper troposphere and 46 vertical levels with increased vertical resolution throughout the troposphere as relative to base experiment. The results indicate that increased vertical resolution in the lower troposphere produces efficient intensification and better structure in terms of eye and eyewall. Increased vertical resolution at lower levels improves the prediction of vertical shear of horizontal wind. Experiments with high resolution in the lower troposphere and high resolution throughout the troposphere simulate better track up to 72 hours.     

Mineral associations of the Lost Village and Lost City hydrothethermal fields in the North Atlantic

During the 50th cruise of R/V Akademik Mstislav Keldysh, on the south slope of the Atlantis massif (30°07′N; the Middle Atlantic Ridge), an inactive hydrothermal field named the Lost Village was discovered. This new field was formed of light carbonate rock and was located near the active Lost City hydrothermal field. The mineralogical associations of these fields were studied. A conclusion about the participation the ocean water in the changing of the carbonate composition of the inactive hydrothermal field was reached.     

Use of late ovarian atresia in describing spawning history of sardine, Sardina pilchardus

We investigated and compared the pattern of accumulation of recent and late atretic follicles in the ovaries of Iberian sardine, Sardina pilchardus, in relation to body size with the aim to examine whether late atresia can be used in back-calculations of individual spawning history. Oppositely to earlier stages, late atresia in sardine was shown to accumulate even at peak spawning periods in fish of larger size/age indicating a relationship between atretic intensity and the distant reproductive performance of the individuals. Despite the fact that intensity of late atresia was very high in some occasions, its accumulation was not shown to impede imminent spawning activity. Lack of dependence between imminent spawning activity and the intensity of late atresia was related to the differential pattern with which postovulatory and atretic follicles are associated to the lamellar epithelium of the ovary. Finally, the effect of the ‘reference trap’ which is a major source of bias when quantifying structures in stereological measurements, could be mediated or even completely removed by using a measure of ovarian growth, such as gonosomatic index in the present study, as a covariate when modeling variability in the intensity of atresia.