Risk of water pollution due to ash–sludge mixtures: column trials

The purpose of this work was to study the risks of water pollution due to the use of mixtures containing wood ash and sewage sludge. Mixtures including sludge and ash may be recycled as fertilizers, and they are economical as they do not integrate commercial limes, but Escherichia coli counts may keep significantly high in such mixtures, because their pH is not alkaline enough. In view of that, it seems interesting to study the E. coli survival in lixiviate from ash?Csludge mixtures including limes rather than from ash?Csludge mixtures alone. Two kinds of experiments were performed using laboratory column trials under saturated flow conditions. The first experiment investigated the chemical leaching behaviour of a mixture of 70% timber-industry wood ashes and 30% urban sewage sludge (% dry weight) at doses equivalent to 10 and 30?Mg/ha. The second experiment studied the survival of E. coli in lixiviates generated from 30?Mg/ha of a mixture consisting in 75% wood ash, 20% sewage sludge and 5% quicklime (% dry weight). In the first experiment, admixture of the ash and sludge achieved a stabilization of elements such as aluminium, iron, magnesium, nickle, carbon monoxide, cadmium, chromium and molybdenum that reduced their solubility compared with that in the ash or sludge alone. Significant solubilisation of heavy metals was not observed, with overall minor risk of chemical water pollution. In the second experiment, although including quicklime E. coli counts were still detected in the lixiviate, indicating risk of water contamination.     

Ultrahigh-pressure metamorphism in the forbidden zone: the Xugou garnet peridotite, Sulu terrane, eastern China

The Xugou garnet peridotite body of the southern Sulu ultrahigh‐pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo₉₁), enstatite (En_92?93), garnet (Alm_20?23Prp_53?58Knr_6?9Grs_12?18), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high‐Mg number, very low CaO, Al₂O₃ and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp_44?58) clinopyroxenites are foliated. Except for rare kyanite‐bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm_29?34Prp_32?50Grs_15?39) + omphacite (Jd_24?36) + minor rutile. Clinopyroxenite and eclogite exhibit LREE‐depleted and LREE‐enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high‐pressure crystal accumulation (+ variable trapped melt) from melts resulting from two‐stage partial melting of a mantle source. Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (< 5 °C km^?1), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K‐feldspar indicate low‐temperature metasomatism.     

Biofilms, microbial mats and microbe-particle interactions: electron microscope observations from diatomaceous sediments

Sediments and diatoms from the mudflats of the Bay of Bourgneuf in western France were examined in an electron microscope study of biofilms and microbial mats. The sediments were kept in an aquarium for study and a diatom culture was made of the benthic diatoms. The sediment biofilm was composed of exopolymeric substances (EPS), incorporated clay particles and, rarely, bacteria. This film coated all particles at the sediment-water interface. Its surface morphology reflected its composition and internal structure. Thin films were smooth, whilst a lumpy structure or incorporated fibrils produced either a mammillated or ropy surface, and clays in the structure gave rise to a flaky morphology. At shallow depths in the sediment column (0.5 cm) the biofilm was already degraded. The biofilm coating degraded diatom frustules in the benthic diatom culture consisted of EPS and bacteria and presented a ragged appearance. Microbial mats occurred on the surface of the fresh littoral sediments as well as those in the aquarium, and on the wall of the aquarium. The mat on the surface of the aquarium sediments had an open structure with webs of fibrils and bacteria in the pore space. It formed in a relatively quiet environment. Pore space was more limited in the mat from the surface of the fresh littoral sediments, in which direct contact between biofilm coated particles was common. In the exposed environment of the aquarium wall there was a thick, resistant coating of EPS. In addition to binding particles together, the presence of mats and biofilms in sediments affects sediment physical properties such as porosity and permeability, the flux of dissolved substances in pore waters and the dissolution of particles and can, therefore, influence early diagenesis. Mats and biofilms seem to be more readily preserved in the geological record than the micro-organisms, such as bacteria, which produce them. Their identification in the sedimentary record would greatly aid interpretation of sediment genesis and evaluation of the microbial role in sediment formation.     

Correlation of spectroscopic properties and substitutional sites of Cr3+ in aluminosilicates: II. Andalusite and sillimanite

This paper is an extension of the earlier one dealing with kyanite in which the best fitting value of the oxygen ligand distance for Cr³⁺ is adopted to study the spectroscopic properties of Cr³⁺ ions doped at the two possible Al sites in the other two polymorphs of the aluminosilicate group (Al₂O₃ · SiO₂), namely, andalusite and sillimanite. The superposition model and the crystal field analysis package recently developed for 3d ions doped at arbitrary low symmetry sites in crystals are used to predict energy levels and statevectors within the whole 3d ³ configuration. Then the values of the ground state zerofield splitting for Cr³⁺ ions at each Al sites in the two crystals are obtained. The splittings of the lower excited states ² E and ⁴ T ₂ as well as the admixture of ⁴ T ₂ into ² E have also been predicted. Comparison of our results with the available experimental data enable us to correlate the optical and EPR Spectroscopic properties with the substitutional Cr³⁺ sites. The conclusion is that in andalusite and sillimanite only the Al sites with nearly-octahedral six-fold coordination seem to be occupied by Cr³⁺ ions.     

Catastrophic landslip activity in two hard rock terrains of peninsular India

This paper presents the case histories of two catastrophic landslips in hard rock terrains with varied climatic and geological environments. The first slip is associated with a power project in very close proximity (200 m) of the Porthimund Dam (11°22N, 76°3430E), in a charnockitic terrain in the Nilgiri hills (Tamil Nadu), and the second is associated with a railroad structure (19°525N, 78°1720E), in Adilabad district (Andhra Pradesh), in a basaltic terrain.The landslip in the charnockites is attributable to: (1) a high degree of saprolitization in the charnockites, with maximum intensity in the crest portion; (2) the coincidence of a major joint pattern in a NE-SW direction, with the strike of the foliation; and (3) the poor-to-fair physical rock quality in the crest and scarp portions.The slips in the basaltic terrain are due to: (1) the partially altered, highly jointed nature of the regional trap rocks with boulder sizes varying from 20 cm to 250 cm in diameter and the debris accumulating in a precarious condition on the northeast side of the rail track, with unfavorable alignment direction; and (2) the instability created in the weak rock mass by the vibrational forces of heavily loaded running trains.The weathered state of the rock masses in both the cases, showing good agreement with their physical state, accounts for the landslips. The remedial measures suggested are also discussed.     

Soft‐sediment deformation structures in a Pleistocene glaciolacustrine delta and their implications for the recognition of subenvironments in delta deposits

The development of soft‐sediment deformation structures in clastic sediments is now reasonably well‐understood but their development in various deltaic subenvironments is not. A sedimentological analysis of a Pleistocene (ca 13·1 to 15 ¹⁰Be ka) Gilbert‐type glaciolacustine delta with gravity‐induced slides and slumps in the Mosty‐Danowo tunnel valley (north‐western Poland) provides more insight, because the various soft‐sediment deformation structures in these deposits were considered in the context of their specific deltaic subenvironment. The sediments show three main groups of soft‐sediment deformation structures in layers between undeformed sediments. The first group consists of deformed cross‐bedding (inclined, overturned, recumbent, complex and sheath folds), large‐scale folds (recumbent and sheath folds) and pillows forming plastic deformations. The second group comprises pillar structures (isolated and stress), clastic dykes with sand volcanoes and clastic megadykes as examples of water‐escape structures. The third group consists of faults (normal and reverse) and extensional fissures (small fissures and neptunian dykes). Some of the deformations developed shortly after deposition of the deformed sediment, other structures developed later. This development must be ascribed to hydroplastic movement in a quasi‐solid state, and due to fluidization and liquefaction of the rapidly deposited, water‐saturated deltaic sediments. The various types of deformations were triggered by: (i) a high sedimentation rate; (ii) erosion (by wave action or meltwater currents); and (iii) ice‐sheet loading and seasonal changes in the ablation rate. Analysis of these triggers, in combination with the deformational mechanisms, have resulted – on the basis of the spatial distribution of the various types of soft‐sediment deformation structures in the delta under study – in a model for the development of soft‐sediment deformation structures in the topsets, foresets and bottomsets of deltas. This analysis not only increases the understanding of the deformation processes in both modern and ancient deltaic settings but also helps to distinguish between the various subenvironments in ancient deltaic deposits.     

Mapping of seawater inundation along Nagapattinam based on field observations

Nagapattinam, in the east coast of India, was severely affected during the deadliest Indian Ocean tsunami of December 26, 2004. The tsunami caused heavy damage to life and property, and the death toll was about 3,378 in Nagapattinam taluk. Certain villages along the coast witnessed large inundation while adjacent villages were protected from the fury of the tsunami waves. This study was carried out to examine the underlying causes for the vulnerability along Nagapattinam coast with the help of field observations, remote sensing, and geographical information system as tools. Coastal areas with high sand dunes have been protected from tsunami, and areas adjacent to backwaters were inundated. Realtime Kinematic Global Positioning System and high-resolution satellite data were used to map the topographic information and maximum extent of inundation. Thematic maps on land use, land cover, and coastal geomorphology were generated using remote sensing and field data. Using field data as the primary source of information, tsunami hazard maps have been generated for Nagapattinam.     

Geochemistry and health aspects of F-rich mountainous streams and groundwaters from sierras Pampeanas de Cordoba,Argentina

Symptoms of dental fluorosis have been observed in rural communities located in the Sierras Pampeanas de Córdoba, a mountainous area in Central Argentina. The clinical assessment was performed in the Charbonier Department, where the fluoride (F⁻) intake was determined to be 3.90 ± 0.20 mg day⁻¹ (n = 16). In this community, mild and severe fluorosis reach an incidence of 86.7% (total teeth surface = 636 teeth) among the children population. To determine the origin and distribution of fluorine in natural waters from the Charbonier Department and nearby regions, sampling was performed in the area covering the San Marcos River basin. The obtained results show that F⁻ concentrations vary between ~1 to ~2.5 mg l⁻¹, with an outlier value of 8 mg l⁻¹. The spatial distribution of F⁻ shows that the lowest concentrations are found at the basin’s catchments. Maximum values are located in two sectors of the basin: the Charbonier depression in the eastern part and at the San Marcos village, downstream the main collector, in the western part of the basin. In these two regions, the F⁻ contents in ground- and surface waters are >2.0 mg l⁻¹ and nearly constant. Dissolved F⁻ in natural waters from the study area has its origin in the weathering of F-bearing minerals present in the region’s dominant lithology. The extent of mineral weathering is mostly determined by the residence time of water within the aquatic reservoir. Longer residence times and a major solid–water interaction lead to enhanced release of F⁻. This explains the higher F⁻ concentrations found in basin areas with lower run off. The removal of F⁻ from water appears to occur by neither fluorite precipitation, nor by adsorption. Hence, variations in F⁻ concentrations seem to be more related to regional hydrological conditions.     

Sinian-Cambrian Tectonic Framework in the Tarim Basin and its Influences on the Paleogeography of the Early CambrianEI北大核心CSCD

Due to strong remodification and sparse trace remnants, tectonic restoration is critical for the reconstructing of the paleography and basin-prototype in the multiple-cycles superimposed basin, which is also fundamental for the hydrocarbon exploration of the deep marine carbonate in the Tarim Basin. This study presents the tectonic framework of the transition phase from the Sinian to the Cambrian Period and its constrains on the paleography of the Cambrian in the Tarim Basin based on comprehensive analysis of new geochronology data, seismic data and regional tectonic data. The results showed that (1) there is a large regional unconformity between the Cambrian and Precambrian, suggesting a discontinuous deposition from the Sinian to the Cambrian that is contrary to the major view; (2) a broad flattened paleotopography formed before Cambrian Period, which is favorable for the wide epicontinental sea environment and a gentle homoclinal ramp platform development in the early Cambrian, and the residual basement low relief uplifts that influence the microfacies differentiation in the carbonate platform; (3) the Cambrian carbonate platform has been involved much into the marginal orogenic belts, and the proto-platform is probably of 200 km out of the present basin in S-N direction; (4) there is a weak extensional setting in the Cambrian-Early Ordovician rather than a strong rifting setting with a large aulacogen into the platform, in which a inter-platform shallow depression and stable ramp platform developed in the Cambrian; (5) there is not troughs, but rather low relief uplifts developed in the Early Cambrian in the southwestern Tarim Basin, and lack of large uplifts along the carbonate platform margins; (6) it is showed a broad architecture of platform-wide slope-ocean basin from the inner Tarim plate to its margin in the Cambrian Period. Considering the basin prototype, the restoration of the tectono-paleography in the early Cambrian in the Tarim Basin is distinct from those of the previously proposed. We propose that a gentle pattern with “two platforms and one inter-depression” in E-W striking other than multiple small platform constrained in the basin, and further subdivision of the western platform with inner platform low uplift and sag in N-S striking, which is possibly inherited from the basement architecture. On the outer of the united platform, there is probably broad gentle slope for transition to ocean basin. We therefore argue that tectonic restoration is crucial for reconstruction of the paleogeography and basin prototype, especially for basins experienced multiphase of tectonic cycles. © 2018, Science Press. All right reserved.