Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.     

Spatial assessment and redesign of a groundwater quality monitoring network using entropy theory, Gaza Strip, Palestine

Using entropy theory, a methodology was developed for the evaluation and redesign of groundwater quality monitoring wells in the Gaza Strip in Palestine. Essential to the methodology is the development of a Transinformation Model (TM) which yields the amount of information transfer and the dependency between the wells as a function of distance. The TM parameters, such as the minimum transinformation and the range, were employed for evaluating the network which revealed that most of the distances between wells were less than the range. It also indicated that a high percentage of redundant information existed in the network. Therefore, the network was reduced by superimposing a square pattern over the monitored area and selecting one well per square block in a stratified pattern. The methodology was tested using the chloride data collected from 1972–2000 from 417 groundwater quality monitoring wells in the Gaza Strip. The number of the groundwater quality monitoring wells in the Gaza Strip was reduced by 53%, while there was 26% redundant information based on the minimum existing distance between wells. This methodology is meant to help monitor the groundwater quality (salinity) in the Gaza Strip.     

Ammonium regeneration in intertidal sediments of the Yangtze estuary during air-exposure

The influences of exposure to the atmosphere on ammonium cycle in the intertidal surface sediments were in situ studied with a geochemical approach at a typical station in the Yangtze Estuary during three tidal cycles in September 2003. During an about 8-h emersion period of each diurnal tide, six high-resolution vertical profiles of adsorbed and dissolved ammonium were measured. It was observed that both adsorbed and dissolved ammonium generally had an increasing trend in sediment cores during the exposure. The rate of ammonium regeneration in sediments was estimated using the accumulation amount of ammonium including adsorbed and soluble fractions during the daytime emersion. The calculation result showed that there was relatively high ammonification rate (˜500 nmol N cm⁻³ day⁻¹), which reflected that organic nitrogen in sediments was quickly decomposed with a residence time of ˜52.7 days. Due to the dramatic temperature difference observed in sediment profiles, free convection was considered an important mechanism of regulating the efflux of produced ammonium into overlying waters. The total estimated amount of regenerated ammonium was ˜1.35×10⁵ t N year⁻¹ in the intertidal flat of the Yangtze Estuary, which occupied 7.6% of the total inorganic nitrogen annually transported to the estuarine ecosystem.     

Check dam positioning by prioritization of micro-watersheds using SYI model and morphometric analysis — Remote sensing and GIS perspective

Sediment Yield Index (SYI) model and results of morphometric analysis have been used to prioritize watersheds and to locate sites for checkdam positioning in Tarafeni watershed in Midnapur district. West Bengal. Various thematic maps such as land use/land cover, slope, drainage, soil etc. were prepared from 1RS ID LISS III digital data, SOI toposheets of 1:50,000 scale and other reference maps. Morphometric parameters such as bifurcation ratio (R_b). drainage density (D_d), texture ratio (T), length of overland flow (L_o), stream frequency (F_u), compactness coefficient (C_c), circularity ratio (R_c), elongation ratio (E_r), shape factor (B_s) and form factor (R_f) were computed. Automated demarcation of prioritization of micro-watersheds was done by using GIS overlaying technique by assigning weight factors to all the identified features in each thematic map and ranks were assigned to the morphometric parameters. Five categories of priority viz., very high, high, medium, low and very low, were given to all the watersheds in both the methods. Sixty-two micro-watersheds using SYI method and twenty-three micro-watersheds using morphometric have been prioritized as very high priority. Final priority map was prepared by considering the commonly occurred very high-prioritized micro-watersheds in both SYI model and morphometric analysis. Twenty-four suitable sites were identified for check dam construction in 21 highly prioritized watersheds. It is proved that integrated study of SYI model and morphometric analysis yield good result in prioritization of watersheds.     

An algorithm for determination of aerosol opticalthickness from AVHRR imagery over oceans

Summary The uncertainty in aerosol size distributions is a main source of errors in aerosol optical thickness determined from satellite measurements. To reduce the errors resulting from the uncertainty in aerosol size distributions, we have performed sensitivity analyses. It is found the errors resulting from the uncertainty in aerosol size distribution can be considerably reduced by using the Junge power law to approximate the aerosol size distribution in an actual atmosphere, if the exponent value is determined at the same time. An iterative algorithm is then developed for the simultaneous determination of aerosol optical thickness and the exponent of the Junge power law over ocean areas from the upwelling radiances measured in AVHRR visible and near infrared channels. A number of numerical experiments are carried out to investigate the validity of the Junge power law approximation by assuming the aerosol size distributions in an actual atmosphere are bimodal with different mode parameters, and by using the actual aerosol size distributions determined at several places by Kaufman et al. (1994). The results show that the errors in determined aerosol optical thickness resulting from the Junge power law approach are significantly reduced. The iterative algorithm is investigated further by comparing the aerosol optical thickness deduced from satellite measurement with that observed by a sun photometer. Received October 10, 2001 Revised December 28, 2001     

Selective controlled base isolation system with magnetorheological dampers

A base isolation system composed of low‐damping isolation bearings and magnetorheological (MR) fluid dampers is described. The MR fluid changes its properties under the influence of a magnetic field resulting in a damper with characteristics that may be modified in real time. This feature enables optimal control under changing excitations in a stable and cost‐effective manner. The voltage is applied according to a selective control strategy. According to the proposed approach the dampers are activated only within a given range of the base displacements. The selective control improves the efficiency of the system and significantly reduces the control forces required for an optimal structural behaviour. Models of five‐ and eight‐storey buildings are used to study the efficiency of the proposed system. Copyright © 2002 John Wiley & Sons, Ltd.