基于电化学法的铬盐清洁生产工艺研究

现有铬盐生产技术阻碍了铬盐行业的清洁化发展,研发新型铬盐生产技术实属必要。中国科学院青海盐湖研究所自行研发出一套以电化学法为基础的铬盐清洁生产工艺,涵盖三条大工艺和四种母系铬盐产品。包括氢氧化钠溶液中电化学氧化铬铁制备铬酸钠联产三氧化二铬和三氧化二铁工艺,离子膜电解法从铬酸钠合成重铬酸钠工艺,以及离子膜电解法从重铬酸钠合成铬酸酐工艺。相比现有铬盐生产技术,该技术的优势主要体现在以下五点:温和化、去渣化、高值化、自动化和高效化。目前相关研发工作业已走出实验室,走过产业化中间试验,正向产业化示范线迈进。     

A method for the extraction of partition lines from long and narrow patches that account for structural features

The extraction of partition lines for long and narrow patches (LN patches) is an important yet difficult problem in the generalization of thematic data. When current methods are used to process polygons with irregular shapes or complex branch convergence zones, the extracted line structural features tend to be inaccurate and topologically erroneous. In this article, we propose an improved partition lines extraction algorithm of constrained Delaunay triangulation to counter these issues. The proposed method aims to maintain consistency between the extracted line structure characteristics and the actual object structure, especially for complex branch convergence zones. First, we describe three types of aggregation patterns (Type A, B, and C aggregation zones) that occur in partition line extractions for LN patches of complex branch convergence zones using Delaunay triangulation. Then, a partition line extraction algorithm that accounts for the direction between the edges of triangles and the distance of nodes in aggregation zones is proposed. Finally, we test our method for a dataset relating to Guizhou Province, China. Compared with the current method that uses quantitative indicators and visualization, the results indicate that our method not only has applicability for simple situations but also is superior for preserving structural features of complex branch convergence zones.     

浅论县（市）级土地利用数据库系统建设

随着经济的迅猛发展,各地土地利用情况多种多样,采用手工管理土地资料更新周期长,综合利用率低,各种查询统计要耗费大量的人力物力,而且统计计算的数据结果精度不高。因此仅仅依靠传统的手工管理模式已经远远不能满足土地管理工作的需要,为保质保量按时完成全国土地利用现状更新调查,加强地籍规范化管理,利用成熟的计算机技术辅助进行土地调查已势在必行。     

EGM96和EGM2008地球重力场模型计算弹道扰动引力的比较

给出了利用地球重力场模型计算扰动引力以及重力场模型截断误差的公式,计算了36阶、360阶、2 160阶地球重力场模型在径向和水平方向的截断误差,并对36阶、360阶的EGM96和EGM2008重力场模型计算的弹道扰动引力矢量进行了分析和比较.结果表明,采用重力场模型计算扰动引力时,模型阶数和弹道点的高度越低,模型截断误差越大;EGM96和EGM2008模型的一致性随着模型阶数的升高而逐渐降低.总体来看,EGM2008模型的精度要好于EGM96模型.     

胶州湾菲律宾蛤仔死壳分布与生态环境关系的研究

胶州湾菲律宾蛤仔栖息地带由于近年受拖耙捕生产，底质遭到频繁骚动。同时沿岸带局部水域环境污染严重，以及河口盐度突发性骤降等因素，直接影响了蛤仔的存活率。因而蛤仔死壳逐年增多。据１９９０年调查，９月份幼蛤和成蛤死壳平均密度比同年４月分别增加３．５倍和１．８倍，蛤仔资源量亦受一定损失。     

Environmental impact of fluidized solidified silt casting on surrounding water bodies

Abstract

With the growing demand for underwater refill engineering, the construction technology of implementing fluidized solidification in underwater pouring has recently received increased attention. However, the environmental impact of underwater casting on surrounding water bodies, especially when the silt is polluted, is still unclear. In this study, a simulated underwater pouring test and a static immersion release test were conducted separately to study the quality of the surrounding water during and after pouring. The results showed that fluidized-solidified silt casting could increase the pH of the surrounding water, even after the pouring had stopped, by approximately 1.0 and the turbidity could reach 200 NTU. No diffusion of Zn and Cu into the surrounding water was observed and while Ni and Cr exhibited slight diffusion, this was at a level well below international water quality standard. During construction, reducing the distance from the seafloor to the bottom of the pouring catheter could reduce the level of pollution. After construction, the use of neutral solidified materials can effectively reduce the pH of the surrounding water and the potential risk of heavy metal dissolution.     

Binary Star Fractions from the LAMOST DR4

Stellar systems composed of single, double, triple or higher-order systems are rightfully regarded as the fundamental building blocks of the Milky Way. Binary stars play an important role in formation and evolution of the Galaxy. Through comparing the radial velocity variations from multiepoch observations, we analyze the binary fraction of dwarf stars observed with LAMOST. Effects of different model assumptions, such as orbital period distributions on the estimate of binary fractions,are investigated. The results based on log-normal distribution of orbital periods reproduce the previous complete analyses better than the power-law distribution. We find that the binary fraction increases with Teff and decreases with [Fe/H]. We first investigate the relation between α-elements and binary fraction in such a large sample as provided by LAMOST. The old stars with high [α/Fe] dominate with a higher binary fraction than young stars with low [α/Fe]. At the same mass, earlier forming stars possess a higher binary fraction than newly forming ones, which may be related with evolution of the Galaxy.     

Extreme Flood Events over the Past 300 Years Inferred from Lake Sedimentary Grain Sizes in the Altay Mountains,Northwestern China

Understanding the temporal variations of extreme floods that occur in response to climate change is essential to anticipate the trends in flood magnitude and frequency in the context of global warming. However, long-term records of paleofloods in arid regions are scarce, thus preventing a thorough understanding of such events. In this study, a reconstruction of paleofloods over the past 300 years was conducted through an analysis of grain sizes from the sediments of Kanas Lake in the Altay Mountains of northwestern China. Results showed that grain parameters and frequency distributions can be used to infer possible abrupt environmental events within the lake sedimentary sequence, and two extreme flood events corresponding to ca. 1736–1765 AD and ca. 1890 AD were further identified based on canonical discriminant analysis(CDA) and coarse percentile versus median grain size(C-M) pattern analysis, both of which occurred during warmer and wetter climate conditions by referring to tree-ring records. These two flood events are also evidenced by lake sedimentary records in the Altay and Tianshan mountains. Furthermore, through a comparison with other records, the flood event from ca. 1736–1765 AD in the study region seems to have occurred in both the arid central Asia and the Alps in Europe, and thus may have been associated with changes in the North Atlantic Oscillation(NAO) index.     

Structural, curvature and electronic properties of Rh adsorption on armchair single-walled carbon nanotube

This paper systematically studies the rolling effects of the (n, n) single-wall carbon nanotubes (SWCNT) with different curvatures on Rh adsorption behaviours by using density functional theory. The outside charge densities of SWCNTs are found to be higher than those inside, and the differences decrease with the increase of the tube radius. This electronic property led to the discovery that the outside adsorption energies are higher than the inside ones, and that the differences are reduced with the increase of the tube radius. Partial density of states and charge density difference indicate that these strong interactions induce electron transfer between Rh atoms and SWCNTs.     

大陆解体与被动陆缘的演化

火山型被动陆缘是大陆解体过程中形成的一类陆缘类型,其演化过程与活动陆缘一样复杂多变。随着近年来对大陆解体过程与被动陆缘演化的深入研究,对其沉积过程、岩浆活动以及变质作用研究都有了很大的进展。陆壳减薄解体的过程有许多不同的模式,不对称的简单剪切模式可能是火山型被动陆缘的成因,其机制是软流圈隆起的最大位置从剖面上看与地壳减薄最大位置不在一条垂线上,造成软流圈上升的岩浆在解体的大陆一侧形成火山型被动陆缘。被动陆缘的沉积建造由两套沉积物组成,一套是大陆解体的裂谷阶段所形成的陆相沉积物和双模式火山岩组合,另一套是稳定陆缘的复理石组合;岩浆作用中基性岩类反应了物质直接源于上地幔的主要特点,并有部分受到地壳混染的特征;变质作用中高温低压环境主要发生在裂谷作用阶段,其特点反映了大陆解体过程中随着时间的增温和减压过程,而拆离伸展阶段则被脆性变形所代替。