A Study on Organic Inclusions in Clastic Reservoir Rocks and Their Application to the Assessment of Oil and Gas Accumulations

Terrigenous clastic reservoir rocks are widespread in China,and nearly all the industrial oil and gas accumulations in eastern China occur in the clastic rocks.The study shows that organic inclusions are mostly distributed in the secondary fissures and pores which were ormed in the process of oil-rock interaction,rather than in the cements or secondary enlargements. The organic inclusions are dominantly organic gas-rich or are composed of pure hydrocarbons.Homogenization temperatures range mainly from 120℃ to 130℃，which shows a relatively high maturity of organic matter.Vertical and horizontal temperature changes provide the grounds for the investigation of basin evolution and thermal fluid-kinetics-model.Fluorescence spectral characteristics o the organic inclusions indicate that oils and gases in the area studied probably have experienced two-stage or two-time migration.Micro-fluorescence rescearch is one of the effective approaches to oil/source correlation and oil migration-stage determination.The abundance and occurrence of organic inclusions is one of the indicators of oil and gas abundance and accumulation in rock layers.With the help of other informatio,organic inclusions can provide the basis for the prospective assessment of oil and gas in clastic reservoir rocks.     

深海二叠——三叠系界线研究现状

综述了深海二叠（Ｐ）－－三叠系（Ｔ）界线研究现状，介绍了深海Ｐ－Ｔ界线附近岩石地层，生物地层、缺氧事件及生物绝灭和复苏的研究进展，指出了深海Ｐ－Ｔ界线，缺氧事件和生物绝灭研究的分歧、不足及其症结。     

福建晋江市前港湖、龙湖、虺湖等的地震堵塞成因研究

在国外前苏联学者尼可拉也夫曾提及地震后有的河流形成地震坝,其后再超覆沉积细粒物质,并称为"地震沉积相",显然这是指的地震堵塞湖形成后的沉积.国内最著名的地震堰塞湖是1933年四川省茂汶北的迭溪7.5级地震,这次强震不仅使迭溪全城及周围60余城镇、村寨全部毁灭,并且四山普遍崩溃,迭溪台地大规模崩塌、堵塞岷江,形成四个地震堵塞湖.大震后45天湖水溃决,造成下游水灾.类似这种地震堵塞湖是地震导致山地,丘陵或台地崩塌堵塞溪流,是地震导致的重力作用堵塞,应为地震重力堰塞湖.本文论及的地震堰塞湖即前港湖、龙湖、虺湖、丙州西侧小湖位于福建省晋江市龙湖镇西南侧,处晋江半岛中部,4个湖沿着控制深沪湾地堑北西边缘的衙口-丙洲断裂呈NE60°线状展布.该断裂与其东侧的深沪-金井断裂共同构成了全新世深沪湾地堑,卫星照片中有清晰的显示.这两条断裂及其所夹的活动地堑同属于区域性的常乐-诏安断裂带中段部份.     

发射光谱载体蒸馏法测定地质样品中微量硼铍锡银

选择了适合的缓冲剂,利用载体蒸馏法将被测元素与基体元素分离,使Be转变为易挥发的氟化物与B、Sn、Ag同时蒸发;降低了谱线背景及元素检出限;加入内标元素Au、Bi,提高了方法的准确度和精密度;采用普通 3mm×3mm×0.7mm杯型电极,装样量少,操作简单。方法检出限(wB/10-6)分别可达B1.5、Be0.3、Sn0.8、Ag0.02;准确度(Δlog C)基本在-0.05～0.05,精密度(RSD,n=8)为2.9%～17%。     

电法软件设计中交互与可视化技术应用

电法软件中的可视化技术包括电法数据交互编辑修改、样点曲线和一维地电模型的可视化和人机交互、断面图等值线与颜色填充、二维地电模型人机交互建模、三维异常体交互建模.这些技术为实现一个实用、快速、操作方便的电法软件系统提供了可靠的保证.     

A study on the focal parameters of Shidian M =5.9 earthquake sequences in 2001

On the basis of about 300 earthquake wave forms observed in the Shidian M _S=5.9 sequences on April 12, 2001 recorded in Kunming Digital Seismic Network, the spectra of shear wave have been used to estimate the focal parameters of these earthquake sequences. The results show that within the magnitude range of 1.5–5.3, the seismic moments are 10¹⁰–10¹⁶ N·m, the corner frequencies are 0.2–0.8 Hz, radii of the focal rupture are 200–2 500 m and the stress drops are 0.1×10⁵–20×10⁵Pa. Through the statistical analyses of variation of corner frequency f _c and stress drop Δσ with time, it is discovered that the average corner frequency of the foreshock sequences is obviously lower than that of the aftershock sequences. Contrarily, the average stress drops Δσ of the foreshock sequences are clearly higher than that of the aftershocks. It is considered that these variation characteristics of average corner frequency and stress drops before and after the main shock have index significance to the precursory information before a strong earthquake. The higher stress drops for the foreshock sequences show that the higher shear stresses have been stored in the area of main shock. After the main shock, most of the stresses have been released, so the aftershock sequences show a rupture process of lower stresses. Foundation item: Scientific and Technological Key Project of Yunnan Province (2001NG46)     

Migrating pingos in the permafrost region of the Tibetan Plateau, China and their hazard along the Golmud–Lhasa railway

Most pingos in the permafrost region of the high northern Tibetan Plateau form along active fault zones and many change position annually along the zones and thus appear to migrate. The fault zones conduct geothermal heat, which thins permafrost, and control cool to hot springs in the region. They maintain ground-water circulation through broken rock in an open system to supply water for pingo growth during the winter in overlying fluvial and lacustrian deposits. Springs remain after the pingos thaw in the summer. Fault movement, earthquakes and man's activities cause the water pathways supplying pingos to shift and consequently the pingos migrate.

The hazard posed to the new Golmud–Lhasa railway across the plateau by migrating pingos is restricted to active fault zones, but is serious, as these zones are common and generate large earthquakes. Pingos have damaged the highway and the oil pipeline adjacent to the railway since 2001. One caused tilting and breaking of a bridge pier and destroyed a highway bridge across the Chumaerhe fault. Another has already caused minor damage to a new railway bridge. Furthermore, the construction of a bridge pier in the North Wuli fault zone in July–August 2003 created a conduit for a new spring, which created a pingo during the following winter. Measures taken to drain the ground-water via a tunnel worked well and prevented damage before the railway tracks were laid. However, pier vibrations from subsequent train motion disrupted the drain and led to new springs, which may induce further pingo growth beneath the bridge.

The migrating pingos result from active fault movement promoting artesian ground-water circulation and changing water pathways under the seasonal temperature variations in the permafrost region. They pose a serious hazard to railway construction, which, in turn can further disturb the ground-water conduits and affect pingo migration.     

Pristine and reacted surfaces of pyrrhotite and arsenopyrite as studied by X-ray absorption near-edge structure spectroscopy

Fe L-, S L-, and O K-edge X-ray absorption spectra of natural monoclinic and hexagonal pyrrhotites, Fe_1-xS, and arsenopyrite, FeAsS, have been measured and compared with the spectra of minerals oxidized in air and treated in aqueous acidic solutions, as well as with the previous XPS studies. The Fe L-edge X-ray absorption near-edge structure (XANES) of vacuum-cleaved pyrrhotites showed the presence of, aside from high-spin Fe²⁺, small quantity of Fe³⁺, which was higher for a monoclinic mineral. The spectra of the essentially metal-depleted surfaces produced by the non-oxidative and oxidative acidic leaching of pyrrhotites exhibit substantially enhanced contributions of Fe³⁺ and a form of high-spin Fe²⁺ with the energy of the 3d orbitals increased by 0.3–0.8 eV; low-spin Fe²⁺ was not confidently distinguished, owing probably to its rapid oxidation. The changes in the S L-edge spectra reflect the emergence of Fe³⁺ and reduced density of S s–Fe 4s antibonding states. The Fe L-edge XANES of arsenopyrite shows almost unsplit e_g band of singlet Fe²⁺ along with minor contributions attributable to high-spin Fe²⁺ and Fe³⁺. Iron retains the low-spin state in the sulphur-excessive layer formed by the oxidative leaching in 0.4 M ferric chloride and ferric sulphate acidic solutions. The S L-edge XANES of arsenopyrite leached in the ferric chloride, but not ferric sulphate, solution has considerably decreased pre-edge maxima, indicating the lesser admixture of S s states to Fe 3d orbitals in the reacted surface layer. The ferric nitrate treatment produces Fe³⁺ species and sulphur in oxidation state between +2 and +4.     

地质岩芯科技资源科普化工作探索与实践——以自然资源实物地质资料中心为例

岩芯科技资源科普化是打通地质科研—科普链条的重要途径,本文通过梳理我国岩芯科技资源现状,分析了岩芯科技资源科普化的现实意义,重点阐述了岩芯科技资源在向地质科普转化5个方面的探索与实践,提出了今后岩芯科技资源科普化工作应建立良好政策机制制度、转变科研人员观念、科技知识向科普转化水平、新技术新手段的应用以及做好科普活动的实施总结等5项工作建议。     

太湖表层沉积物多环芳烃的空间分布、来源及其风险

随着太湖流域社会与经济的发展,多环芳烃(PAHs)在各种环境介质中逐渐累积,污染日益严重,可能对太湖生态环境及周边人体健康构成威胁。为探究太湖沉积物PAHs的来源及生态风险,于2021年12月在太湖采集30个表层沉积物样品,利用气相色谱-质谱联用仪(GC-MS)检测样品中16种PAHs含量;利用受体模型和苯并[a]芘(BaP)毒性当量法进行来源解析及生态风险评估,并将各来源贡献与毒性当量浓度相结合,量化源风险。结果表明,太湖表层沉积物中16种PAHs总含量介于124~592 ng/g之间,平均值为294 ng/g,中值为279 ng/g;高环多环芳烃(HMW PAHs)为主要组分,占∑PAHs的67%。高含量区域位于竺山湾、梅梁湾、贡湖湾和西太湖,与国内外其他湖泊沉积物相比,太湖沉积物PAHs含量处于较低水平。源解析的结果表明,太湖表层沉积物中PAHs交通排放源贡献率为29.1%、煤炭燃烧源贡献率为26.7%、生物质燃烧源贡献率为28.7%、石油源贡献率为15.6%。生态风险评价结果表明,交通排放源、生物质燃烧源、煤炭燃烧源和石油源的BaP毒性当量含量(TEQ_BaP)均值分别为19.34、17.81、16.33和9.1 ng/g,均小于70 ng/g,几乎处于无风险水平。西太湖、贡湖湾和梅梁湾的部分区域ΣTEQ_BaP大于70 ng/g属于潜在风险区,具有一定潜在毒性。在后续的污染治理中应重点关注太湖西北部地区污染物的排放。本研究可为沉积物中PAHs污染的研究提供数据支撑,为地方政府精准、高效地管控PAHs污染提供理论依据。