海水中微量元素无机离子交换动力学研究——液膜递进模型理论 Ⅰ.天然海水条件下

最近十几年来,海水物理化学中关于海水的化学热力学研究已较广泛地开展,并已有一些重要的研究结果报导。但是,关于海水中化学动力学的研究,至今却基本上仍属空白。然而这正是海洋中许多化学过程(特别像海水化学资源开发、海洋污染和防治等实践性比较强的领域中)要解决的关键问题。本文是我们从事这一方面研究工作的第一篇报导,讨论的内容是海洋中最重要的过程之一——无机离子交换过程。     

Occurrence and characteristics of sporadic sodium layer observed by lidar at a mid-latitude location

Na lidar observations of SSL during the past 5 years at a mid-latitude location (Wuhan, China, 31°N, 114°E) are reported in this paper. From 26 SSL events detected in about 230 h of observation, an SSL occurrence rate of 1 event/9 h at our location was obtained. This result, combined with that reported by Nagasawa and Abo (Geophys. Res. Lett. 22 (1995) 263) at Tokyo, Japan, reveals that the SSL occurrence can be relatively frequent at some mid-latitude locations. The statistical analyses of main parameters for the 26 SSL events were made, and the results were compared with those previously reported. By examining the corresponding data from a nearby ionosonde, it was found that there was a fairly good correlation between SSL and Es. Of the 18 pairs of SSL and Es events checked, 15 of SSL were accompanied by Es, and 8 pairs of them were correlated within 1 h in time and within 5 km in altitude. From the analyses of observed perturbations during SSL development, the role of dynamic processes of atmosphere in the SSL formations were emphasized.     

海洋动物体石油烃污染评价标准参考值的探讨

目前,国内外尚无颁布任何海洋生物石油污染评价标准,为了满足海洋生物石油污染评价的需要,本文采用综合分析与毒理学分析相结合的方法,探讨和提出了海洋动物石油污染评价标准参考值,海洋鱼类、贝类和甲壳类的石油污染评价标准参考值（干重）分别为１５、７０ 和２５ ｍ ｇ／ｋｇ。     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

鄂尔多斯西南缘前陆盆地沉降和沉积过程模拟

本文将东祁东逆冲带与鄂尔多斯西南缘晚三叠世前陆盆地相结合，研究了逆冲带内部变形特征，前陆盆地中层序地层格架特征及其反映的盆缘构造性质和幕式逆作作用。     

CCD Photometry and Long-Term Optical Variability of 3C 345

This paper presents evidence for long-term optical variability and colour behaviour of the blazar 3C 345 (1641+399, z=0.595). Our results show that the amplitude of the optical variations of 3C 345 has been only about 3 magnitudes from its photometric history; existent significant correlation between brightness and colours is found for 3C 345. Our recent CCD photometry of 3C 345 in May 1996 and May 1997 showed that they are in good agreement with our prediction of the optical variability period of about 10 years (see Zhang et al., 1998; Webb et al., 1988). This revised version was published online in July 2006 with corrections to the Cover Date.     

煤层冲刷带预测方法评述

介绍了沉积分析法、矿井物探法以及地质统计法三种煤层冲刷带预测方法.实例证明,根据煤矿生产的具体情况,选择一种或综合运用几种方法,能较好地预测冲刷带的位置和范围.     

Exploring the hydrologic response to the urban building coverage ratio by model simulation

Theoretical and Applied Climatology - The increasing building coverage ratio accompanied by the increase in impervious surfaces during the urbanization process may change the flow concentration...     

江苏沿海高速公路低能见度浓雾的气候特征和影响因子研究

文章对2012年6月至2014年6月期间发生于江苏省沿海高速公路的浓雾过程(能见度0.5 km)进行统计分析,探讨了低能见度浓雾的气候特征、气象要素变化以及主要环流形势背景。研究结果表明:(1)低能见度浓雾月分布次数有显著差异,3-6月、12月至次年2月雾发生次数最高,春、冬季高于夏、秋季;03:00-05:00为低能见度生成的高峰时段,08:00左右为消散峰值时段。(2)能见度低于0.5 km后,如果相对湿度继续增大到97%左右、温度处于0~4℃、风速在0~2 m·s~(-1)、风向在ENE-SSE,能见度可能继续下降到0.2 km以下。(3)对150366个样本的环流背景统计分析表明,中北部路段的低能见度天气大多数是由锋前雾引起的,主要出现在中低层暖区域内,地面为冷锋前部弱气压场的环流条件下。全路段大面积低能见度天气由辐射雾和平流雾造成,辐射雾天气形势主要是高层为下沉气流,配合地面受弱高压或高压南下;平流雾出现在中低层暖性系统,地面位于入海高压后部或低压倒槽东侧,低层盛行偏东风或东南风。(4)"象鼻型"先期振荡现象适用于沿海高速公路低能见度预报过程,尤其对能见度稳定维持0.2 km以下的浓雾过程有很好的预警和监测作用。     

商丹断裂带东段基性岩、超基性岩中的铁铬镍资源潜力预测

对商丹断裂带东段基性-超基性岩带（体）及其中的铁、铬等矿化特征作了概述,在岩带中圈出了A、B、C、D四个基性-超基性岩体集中区,对该带中铁铬镍等矿产资源潜力作了地质预测,认为该基性-超基性岩带是岩浆型铁、铬、镍等矿产的良好找矿远景区,提出了下步找矿工作思路、方法手段的建议.