Effects of key components of <Emphasis Type="Italic">S. triqueter</Emphasis> root exudates on fractions and bioavailability of pyrene–lead co-contaminated soils

The key components of S. triqueter root exudates involved 4-oxo-pentanoic acid, succinic acid, glutaric acid, phthalate acid, citric acid, vanillic acid, myristic acid, pentadecanoic acid, decanoic acid, 14-methyl-pentadecanoic acid, hexadecanoic acid, octadecanoic acid and oleic acid, and the content of the water-soluble organic acids (citric acid, succinic acid and glutaric acid) significantly increased in pyrene and lead co-contaminated rhizosphere soil. These three water-soluble organic acids including citric acid, succinic acid and glutaric acid were detected as the specific root exudates of S. triqueter under stress of pollutants for pyrene and lead, so they were chosen as the research objects, and they were added into the bioremediation systems of pyrene and lead co-contaminated wetland soils. Compared with the control, the treatments added the three organic acids always improved the quantity of the bioavailable fraction of pyrene and lead in wetland soils and greatly influenced other chemical states of pyrene and lead fractions in the test concentration range. Under the 50 g kg^?1 of organic acids concentration, the amount of the bioavailable fraction of pyrene and lead increased 41.0 and 872.7 % by citric acid, respectively. The enhancement of bioavailability of pyrene and lead in the wetland soil by adding organic acids generally decreased in the following order: citric acid > succinic acid > glutaric acid. Enhancing effects of organic acids on the bioavailability improvement of pyrene and lead is remarkable.     

Experimental and modeling study on Cr(VI) transfer from soil into surface runoff

With the development of modern agriculture, large amount of fertilizer and pesticide outflow from farming land causes great waste and serious pollution to surface water and groundwater, and threatens ecological environment and even human life. In this paper, laboratory experiments are conducted to simulate adsorbed Cr(VI) transfer from soil into runoff. A two-layer in-mixing analytical model is applied to analyze laboratory experimental results. A data assimilation (DA) method via the ensemble Kalman filter (EnKF) is used to update parameters and improve modeling results. In comparison with the experimental data, DA updated modeling results are much better than those without the updating. To make predictions better, the inflation method with a constant inflation factor via DA method was used to compensate the fast decrease of ensemble spread partially related to filter inbreeding. Based on the used rainfall and relevant physical principles, the updated value of the incomplete mixing coefficient γ is about 14.0 times of the value of the incomplete mixing coefficient α in experiment 1 and about 7.4 times in experiment 2, while the difference between the flow rate of runoff and infiltration is not so large even after reaching stable infiltration condition. The results indicate the loss of Cr(VI) in soil solute is mainly due to infiltration, rather than surface runoff. With the increase of mixing layer depth, soil adsorption capacity will increase and the loss of soil solute will decrease. The study results provide information for reducing and even preventing the agricultural nonpoint source pollution.     

Simulation of interactions among multiple debris flows

Adjacent debris flows may interact in many ways: two or more concurrent debris flows may merge; one debris flow can run out over an existing debris flow fan. Such interactions may cause debris flow properties to change in the mixing process as well as more severe adverse effects than those caused by a single debris flow. This paper aims to investigate the interactions among channelized debris flows originated from adjacent catchments. Both concurrent and successive debris flows are considered. If several debris flows originate from different locations concurrently and merge, the volumetric sediment concentration (i.e., the ratio of the volume of solid material to the total volume of debris flow), C _v, is a good index to capture the mixing process of these debris flows. The change in C _v reflects where mixing occurs and the mixing degree. The debris flow properties (e.g., yield stress and dynamic viscosity) evolve in the mixing process and can be captured by the change in C _v. The debris flow with a larger volume dominates the mixing process, and the properties of the mixed debris flow are more similar to those of the larger debris flow. The inundated areas and runout distances of successive debris flows are smaller than those of concurrent debris flows of the same total volume due to the smaller scales of the individual events and blockage by the earlier debris flows. However, the deposit depth in the interacting part of the debris flow fans of successive debris flows can be much larger than that of concurrent debris flows, leading to more destructive cascading hazards (e.g., the formation of debris barrier lakes). The sequence of successive debris flows not only significantly influences the runout characteristics of the debris flows but also substantially affects the cascading hazards.     

Soil moisture potential and water content in the unsaturated zone within the arid Ejina Oasis in Northwest China

Three soil profiles were selected in the Ejina Oasis, northwest China, to determine water content profiles and evolution of soil moisture potentials in the unsaturated zone within the arid area. The total soil moisture potentials have been monitored for about 3 months in 2001 at different depths in the soil profiles. The occurrence and movement of water in the unsaturated zone was analyzed using the zero flux plane (ZFP) method. It is shown that convergent ZFPs and divergent ZFPs may occur at depths between 0.5 and 3.0 m, and that the depth of the ZFPs was controlled by the root zone of plants growing on the land surface. Profiles of the total soil moisture potentials were observed to be coincident with those of the water contents at the three experimental sites. The total soil moisture potential showed a slight increasing trend and the ZFPs tend to vanish from summer to winter as the water extraction by roots decreased. Evapotranspiration through vegetation has an important bearing on the water content and the total potential in the unsaturated zone.