Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

Biostratigraphy,sedimentology and sequence stratigraphy of the Tournaisian–Viséan transitional strata in South China (Guangxi)

The biostratigraphy and sedimentological evolution of the Tournaisian–Viséan (T–V) transitional strata in South China (Guangxi) have been investigated. The sediments were deposited on a carbonate platform and in slope and basinal environments. In the T–V transitional strata, six foraminiferal associations have been distinguished which allow correlation between the shallow and deep water deposits. A careful examination of the evolutionary stages of the foraminifer Eoparastaffella provides a more accurate criterion for the definition of the T–V boundary, but does not significantly modify the historical one. The distinction of two morphotypes is based on the elevation of the last whorl and the peripheral outline. Tournaisian specimens of Eoparastaffella have a well rounded periphery (morphotype 1) contrasting with the subangular periphery of younger Viséan specimens (morphotype 2). A coefficient can be deduced from simple biometric measurements for more precisely defining the T–V boundary. The sequence stratigraphy of the T–V strata in South China has been reconstructed by combining biostratigraphical and sedimentological data. It allowed the correlation of the T–V transitional strata between the platform area and the slope and basinal locations. Late Tournaisian strata were deposited during a highstand systems tract. Near the end of the Tournaisian, a major drop in relative sea-level led to the development of an unconformity in the platform area. Lowstand deposits formed during latest Tournaisian time in the basin where a detailed biostratigraphic framework has been devised. Sediments deposited during the ensuing transgressive systems tract overlie the late Tournaisian highstand sediments in the platform area and the latest Tournaisian lowstand deposits in the basin. A major drop in relative sea-level near the end of the Tournaisian has been recognized worldwide. Therefore, the possibility of using the sequence stratigraphy of the T–V strata in South China for worldwide correlations should be investigated. © 1997 John Wiley & Sons, Ltd.     

Atmospheric Water Vapor Pressure over Land Surfaces: A Generic Algorithm with Data Input Limited to Air Temperature, Precipitation and Geographic Location

Summary A lack of information for surface water vapor pressure (WVP) represents a major impediment to model-assisted ecosystem analysis for understanding plant-environment interactions or for projecting biospheric responses to global climate change. This paper reports on a generic algorithm that captures global variation in monthly WVP. The algorithm solves WVP in terms of reduction from saturation WVP as a negative exponential function of potential evapotranspiration; the reduction rate per unit potential evapotranspiration in turn varies with monthly precipitation and a series of variables that distinguish local climate regimes. Data input to the algorithm is limited to monthly air temperature and precipitation, plus latitude, longitude and elevation. The algorithm is specified through regression fitting to monthly climate normal data from 852 stations around the world. It accounts for 96% of the variance in the WVP data, with a root mean square error of 0.17 kPa, or 12% of the data mean. The algorithm closely reproduces five-year sequential monthly WVP data for each of five selected United States locations representitative of diverse climate regimes: the average error generally falls within ±12% of the data mean, and the absolute error within ±0.2 kPa. Its projections also compare favorably against the WVP output from the General Circulation Models for temperature and precipitation conditions under the scenario of a doubled atmospheric carbon-dioxide concentration: the two fall within ±10% of each other for 75% of a total 264 data cases, or within ±20% for 94% of the cases. These statistics suggest that the spatially-based algorithm is useful for projecting temporal variation in WVP, and for extrapolative applications beyond the fluctuation range of present climate. Received March 4, 1999     

MODAL ANALYSIS OF SOFT-SOIL SITES INCLUDING RADIATION DAMPING

For the one-dimensional analysis of soft-soil layers on an elastic half-space, a general form of analytical solution is developed for converting radiation damping due to energy leaking back to the half-space into equivalent modal damping, allowing the modal analysis technique to be extended to a site where radiation damping has to be accounted for. Closed-form solutions for equivalent modal damping ratios and effective modal participation factors are developed for a single layer with a shear wave velocity distribution varying from constant to linearly increasing with depth. Compact and recursive forms of solutions for equivalent modal damping ratios are developed for a system with an arbitrary number of homogeneous layers on an elastic half-space. Comparisons with numerical solutions show that the modal solutions are accurate. The nominal frequency of a site, i.e. the inverse of four times the total shear wave travel time through the layers, is an important parameter for estimating the high mode frequencies. A parameter study shows that for the same impedance ratio of the bottom layer to the elastic half-space, a system of soil layers with an increasing soil rigidity with depth has, in general, larger peak modal amplifications at the ground surface than does a single homogeneous layer on an elastic half-space, while a system with a decreasing soil rigidity with depth has smaller modal peak amplifications. © 1997 by John Wiley & Sons, Ltd.     

On the relationship between historical land‐use change and water availability: the case of the lower Tarim River region in northwestern China

Natural ecosystems in the region of the lower Tarim River in northwestern China strongly deteriorated since the 1950s due to an expanding desertification. As a result, the downstream Tarim River reaches became permanently dry land. This historical evolution in land‐use change is typically the result of the anthropogenic impact on natural ecosystems. On the basis of a spatially distributed hydrological catchment model bidirectionally linked with a fully hydrodynamic MIKE11 river model, land‐use changes characterized by historical changes in leaf area index (LAI) of vegetation, as well as the evolution of irrigated surface areas, can be causally related to changes in water resources (groundwater storage and surface water resources). An increased surface area of irrigated (agricultural) land, together with a majority of inefficient irrigation methods, did lead to a strong increase of water resources consumption of the farmlands located in the upper Tarim River area. Evidently, this evolution influenced available water resources downstream in the Tarim basin. As a result, farmland has been gradually relocated to the upstream regions. This has led to reduced flows from the upper Tarim stream, which subsequently accelerated the dropping of the groundwater level downstream in the basin. This study moreover demonstrates that land surface biomass changes (cumulative LAI) along the lower Tarim River are strongly related to the changes in groundwater storage. Copyright © 2012 John Wiley & Sons, Ltd.     

Lateral migration,thermoluminescence chronology and colour variation of longitudinal dunes near Birdsville in the Simpson Desert,central Australia

The longitudinal dunes of the Simpson Desert, in the vicinity of Birdsville, have been reworked largely during the Holocene from dunes deposited up to 80000 years ago or earlier. The widespread asymmetry of these roughly northward-trending dunes, with steeper eastern faces and more gentle western faces, supports wind-rose data showing sand-transporting winds from the southwest obliquely intersecting the dunes. While this suggests a change in the wind pattern since the dune field was oriented, it does not indicate that the dunes are necessarily shifting leeward (eastward) as a consequence. It is hypothesized that the direction of migration is controlled by the extent to which the dunes are vegetated. Relatively well-vegetated dunes can accrete sand on their gentle stoss slopes and erode on their lee slopes causing them to shift westward and hence obliquely into the wind, a condition that probably prevails in wetter regions and during episodes of relatively humid climate. In contrast, in very dry areas or during arid phases, sand can move unimpeded up a sparsely vegetated stoss face and over the crest to form an avalanche or slip face on the lee side, thereby causing the dunes to shift eastward. Despite evidence that longitudinal dune crests can shift laterally to some extent, the dunes in the western part of the Simpson Desert have not migrated, either westward or eastward, more than 100m or so from their Pleistocene cores. Aeolian transport and partial or complete removal of iron cutans from around quartz grains results in dunes of widely varying colour yet of similar age.     

Atmospheric Artifact Compensation in Ground-Based DInSAR Applications

In this letter, a coherence-based technique for atmospheric artifact removal in ground-based (GB) zero-baseline synthetic aperture radar (SAR) acquisitions is proposed. For this purpose, polarimetric measurements acquired using the GB-SAR sensor developed at the Universitat Politecnica de Catalunya are employed. The heterogeneous environment of Collserola Park in the outskirts of Barcelona, Spain, was selected as the test area. Data sets were acquired at X-band during one week in June 2005. The effects of the atmosphere variations between successive zero-baseline SAR polarimetric acquisitions are treated here in detail. The need to compensate for the resulting phase-difference errors when retrieving interferometric information is put forward. A compensation technique is then proposed and evaluated using the control points placed inside the observed scene.     

Using Sequential Self-Calibration Method to Identify Conductivity Distribution: Conditioning on Tracer Test data

An iterative inverse method, the sequential self-calibration method, is developed for mapping spatial distribution of a hydraulic conductivity field by conditioning on nonreactive tracer breakthrough curves. A streamline-based, semi-analytical simulator is adopted to simulate solute transport in a heterogeneous aquifer. The simulation is used as the forward modeling step. In this study, the hydraulic conductivity is assumed to be a deterministic or random variable. Within the framework of the streamline-based simulator, the efficient semi-analytical method is used to calculate sensitivity coefficients of the solute concentration with respect to the hydraulic conductivity variation. The calculated sensitivities account for spatial correlations between the solute concentration and parameters. The performance of the inverse method is assessed by two synthetic tracer tests conducted in an aquifer with a distinct spatial pattern of heterogeneity. The study results indicate that the developed iterative inverse method is able to identify and reproduce the large-scale heterogeneity pattern of the aquifer given appropriate observation wells in these synthetic cases.     

Rocky desertification and its causes in karst areas: a case study in Yongshun County,Hunan Province,China

Rocky desertification, a process of land degradation characterized by soil erosion and bedrock exposure, is one of the most serious land degradation problems in karst areas, and is regarded as an obstacle to local sustainable development. It is well known that human activities can accelerate rocky desertification; however, the effects of climate change on rocky desertification in karst areas are still unclear. This study focused on the effects of temperature and precipitation changes and human activities on rocky desertification in karst areas to determine the impacts of climate change and human disturbances on rocky desertification. Areas of different level of rocky desertification were obtained from Landsat TM (1987) and Landsat ETM+ (2000) images. The results show that, although the total desertification area increased by only 1.27% between 1987 and 2000, 17.73% of the slightly desertified land had degraded to a moderate or intense level, 2.01 and 15.71%, respectively. Meanwhile, between 1987 and 2000, the air temperature increased by 0.7°C, and precipitation increased by 170 mm. Statistical results indicate that the increase in precipitation was caused by heavy rainfall. In addition, under the interactive influences of heavy rainfall and temperature, the average karst dissolution rate was about 87 m³ km⁻² a⁻¹ during the 14 years in the study area. Further analysis indicated that rocky desertification was positively related with the increase in temperature and precipitation and especially with the heavy rainfall events. Climate change accelerated rocky desertification in the karst areas. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Maximum-likelihood ambiguity resolution based on Bayesian principle

 Based on the Bayesian principle and the fact that GPS carrier-phase ambiguities are integers, the posterior distribution of the ambiguities and the position parameters is derived. This is then used to derive the maximum posterior likelihood solution of the ambiguities. The accuracy of the integer ambiguity solution and the position parameters is also studied according to the posterior distribution. It is found that the accuracy of the integer solution depends not only on the variance of the corresponding float ambiguity solution but also on its values. Received: 27 July 1999 / Accepted: 22 November 2000