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171.
The Tons Valley, situated in the central-easternmost part of the Himachal Lesser Himalaya, adjoining the Garhwal Himalaya, shows geological features suggestive of a strong pre-Tertiary deformational episode. The Paleoproterozoic Dharagad Group, overlain by the Mesoproterozoic Deoban and Neoproterozoic Simla groups rest as a thrust sheet over the Middle Cambrian Chilar Formation, which occurs as windows and also as tectonic slivers within the thrust sheet designated as the Dharagad Thrust Sheet (DTS). The mineral lineation, inclination of tectonic slivers and overturned beds suggest that the DTS was translated from the NE. The westernmost and southwesternmost leading edges of the DTS are exposed at Subathu and Morni WNW and WSW respectively of the Tons Valley. The position of the leading edges of the DTS vis-à-vis the windows in the Tons Valley suggest a minimum translation of about 50 km for the DTS. The Simla Group at Subathu and the Deoban at Morni, forming parts of the DTS, constitute basement for the Thanetian–Lutetian Subathu Formation of the Himalayan Foreland Basin (HFB). This stratigraphic relationship unambiguously demonstrates that the Simla and the Deoban Groups, forming leading edges of the allochthonous DTS, were already translated and emplaced at Subathu and Morni before the creation of the HFB in which the deposition commenced with the Subathu Formation in Thanetian. It implies that the DTS was translated from the NE to the present position at Subathu and Morni in pre-Thanetian time. There is no direct evidence to constrain the age of the thrusting.In view of regional regression in Late Cambrian, a distinct angular unconformity between the Cambrian and the overlying Ordovician, Early Paleozoic metamorphism and extensive development of Early Paleozoic granites and their rapid exhumation, a Late Cambrian age is suggested for the DTS thrusting. Not only the direction of movement of the DTS is same as that of the Tertiary thrust sheets but also Cambrian folds are co-axial with the Tertiary folds. This strange coincidence shows that similar kinematic field existed during two tectonic events. A ridge, like the present Central Crystalline Axis, was elevated between the Tethyan and Lesser Himalayan basins, which contributed zircons of the Early Cambrian age to both basins. 相似文献
172.
Samuel Giersch Eberhard Frey Wolfgang Stinnesbeck Christina Ifrim José Manuel Padilla Gutierrez 《Swiss Journal of Geoscience》2011,104(1):73-84
A new species of the clupeid genus Scombroclupea is described from the Upper Cretaceous (Cenomanian) Plattenkalk locality “Loma la Mula” in Coahuila, northeastern Mexico. The material provides new osteological data for the genus, which clarify its systematic position. The Mexican Scombroclupea points to an occurrence of the genus in the western Tethys and indicates a vicariant event between S. macrophthalma from Lebanon and Croatia and the new species described herein. The analysis of the functional morphology of Scombroclupea supports the reconstruction of an oscillatory locomotion mode in this genus. 相似文献
173.
In this work, investigations dealing with the determination of hydrocarbons in contaminated soil water are presented. The hydrocarbons under investigation range from low to high volatility compounds. A GC‐FID method was developed that due to its efficiency, routine suitability, relative rapidity, and low cost is suitable for the analysis of complex chemical mixtures of highly volatile hydrocarbons (with boiling points between 69 and 190°C). The standard used was a gasoline mixture with boiling points ranging from 100 to 190°C. For this standard, no supplementary preparation is needed and it is suitable for the whole range of hydrocarbons under investigation. The determination of the hydrocarbon content of the samples was performed applying univariate and multivariate statistical analysis to the experimental data. In the characterization of a contamination with highly volatile hydrocarbons of soil water originating from different depth layers from the chemistry location Leuna (Sachsen‐Anhalt, Germany), the advantages of a multivariate method are demonstrated in exemplary manner. 相似文献
174.
The ecological tidal model simulates the cycling of carbon, nitrogen, phosphate, and silicate and describes the tidal, diurnal,
and annual dynamics of the back barrier area of the island Spiekeroog in the German Bight. The region is characterized by
strong tidal currents and extensive tidal flats. It is strongly influenced by the conditions in the southern part of the German
Bight. This model study investigates the dependence of the model behavior on the boundary conditions and the forcing. The
effect of short- and long-term sea level rise on nutrient and plankton dynamics is analyzed. As the model is set up as semi-Lagrangian
with only a coarse approximation of the hydrodynamics, the seasonal and intratidal variability in the biogeochemical cycling
can only be reproduced qualitatively. By varying the boundary conditions, the intrinsic dynamics of the back barrier area
can be separated from boundary condition effects. This study shows that any agreement between model results and field data
cannot be expected without correct boundary conditions. The seasonal variability is of major importance, while higher-frequency
variability only plays a minor role. 相似文献
175.
Unusual exsolution phenomena in omphacite and partial replacement of phengite by phlogopite + kyanite in an eclogite from the Erzgebirge 总被引:4,自引:0,他引:4
Esther Schmädicke Wolfgang Friedrich Müller 《Contributions to Mineralogy and Petrology》2000,139(6):629-642
In the Erzgebirge Crystalline Complex, eclogites occur in three different high pressure (HP) units (1, 2 and 3) recording
contrasting pressure (P)–temperature (T) conditions. Eclogites from HP-unit 1 experienced peak metamorphic conditions in the
coesite stability field at about 33 kbar/850 °C. Commonly, these eclogites from HP-unit 1 are all very similar, with an eclogitic
peak assemblage of omphacite–garnet–coesite–K-feldspar, rarely accompanied by kyanite, and omphacites systematically deviating
from a stoichiometric composition. In contrast, an eclogite recently found near Blumenau, is mineralogically and geochemically
different from the typical eclogites of HP-unit 1. This unusual eclogite reveals the eclogitic equilibrium assemblage omphacite–garnet–coesite–phengite–phlogopite–kyanite,
and yields metamorphic peak conditions of 870 °C and >29 kbar. There is clear textural evidence of the formation of phlogopite
and kyanite under partial consumption of phengite and garnet. Moreover, the omphacite is stoichiometric and contains abundant
exsolution lamellae, the thickest of which were identified as quartz by the electron microprobe. The finer lamellae were studied
by transmission electron microscopy (TEM). Oligoclase was identified as an exsolution phase. Other lamellae proved to consist
of K-white mica, also interpreted as exsolution. Prior to exsolution, the omphacite composition must have been cation-deficient,
as that of the other, common HP-unit 1 eclogites. These non-stoichiometric compositions are ascribed to partial substitution
by the Ca-Eskola pyroxene component, which calculates to an average of 8 mol% for omphacite in HP-unit 1 eclogites. According
to experiments, this substitution becomes significant at P > 30 kbar. Exsolution of K-white mica may indicate hydroxyl defects
in the original omphacite, also favoured by high pressure. Oligoclase and K-white mica exsolution from Ca-Eskola-rich clinopyroxene
has not previously been reported. The omphacite has a disordered C2/c structure; and in just one case very small (a few tens
of nanometres) antiphase domains, resulting from the C2/c to P2/n transformation, are present. These features may indicate
a brief thermal history and rapid tectonic processes.
Received: 4 January 1999 / Accepted: 20 April 2000 相似文献
176.
Identifying causes of ground-penetrating radar reflections using time-domain reflectometry and sedimentological analyses 总被引:5,自引:0,他引:5
Ground-penetrating radar (GPR) is a geophysical technique widely used to study the shallow subsurface and identify various sediment features that reflect electromagnetic waves. However, little is known about the exact cause of GPR reflections because few studies have coupled wave theory to petrophysical data. In this study, a 100- and 200-MHz GPR survey was conducted on aeolian deposits in a quarry. Time-domain reflectometry (TDR) was used to obtain detailed information on the product of relative permittivity (ɛr ) and relative magnetic permeability (μr ), which mainly controls the GPR contrast parameter in the subsurface. Combining TDR data and lacquer peels from the quarry wall allowed the identification of various relationships between sediment characteristics and ɛr μr . Synthetic radar traces, constructed using the TDR logs and sedimentological data from the lacquer peels, were compared with the actual GPR sections. Numerous peaks in ɛr μr , which are superimposed on a baseline value of 4 for dry sand, are caused by potential GPR reflectors. These increases in ɛr μr coincide with the presence of either organic material, having a higher water content and relative permittivity than the surrounding sediment, or iron oxide bands, enhancing relative magnetic permeability and causing water to stagnate on top of them. Sedimentary structures, as reflected in textural change, only result in possible GPR reflections when the volumetric water content exceeds 0·055. The synthetic radar traces provide an improved insight into the behaviour of radar waves and show that GPR results may be ambiguous because of multiples and interference. 相似文献
177.
Since 1980 when F. Lippmann's seminal paper appeared, ourunderstanding of solubility equilibria involving ionic solidsolutions has been advanced by theoretical considerations as wellas careful experimental studies designed to determine excess Gibbsfunctions. A unified theory of solid-solution aqueous-solutionequilibria as well as the thermodynamic background of thephenomenon of ``stoichiometric saturation' are reviewed.It is shown that Lippmann diagrams effectively summarize thethermodynamic basis of solid-solute aqueous-solution equilibria ofsparingly soluble metal carbonate systems. Clearly, the predictivepower of these diagrams may be limited due to kineticrestrictions. Only when dissolution and precipitation areessentially reversible, favourable conditions to synthesizehomogeneous solid phases can be derived from studies of equilibria. 相似文献
178.
179.
Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis 下载免费PDF全文
Lutz Nasdala Fernando Corfu John W. Valley Michael J. Spicuzza Fu‐Yuan Wu Qiu‐Li Li Yue‐Heng Yang Chris Fisher Carsten Münker Allen K. Kennedy Peter W. Reiners Andreas Kronz Michael Wiedenbeck Richard Wirth Chutimun Chanmuang Manuela Zeug Tamás Váczi Nicholas Norberg Tobias Häger Alfred Kröner Wolfgang Hofmeister 《Geostandards and Geoanalytical Research》2016,40(4):457-475
In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for 206Pb/238U and 0.67676 ± 0.00023 for 207Pb/235U (weighted means, 2s uncertainties). Its 206Pb/238U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ18O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean 176Hf/177Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ7Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g?1 Li (2s). Zircon M127 contains ~ 923 μg g?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 1018 alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination. 相似文献
180.
Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite 下载免费PDF全文
Ann‐Christine Ritter Vasileios Mavromatis Martin Dietzel Ola Kwiecien Felix Wiethoff Erika Griesshaber Laura A. Casella Wolfgang W. Schmahl Jennifer Koelen Rolf D. Neuser Albrecht Leis Dieter Buhl Andrea Niedermayr Sebastian F. M. Breitenbach Stefano M. Bernasconi Adrian Immenhauser 《Sedimentology》2017,64(5):1354-1380
For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different 18O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ47 which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ18O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ18O and Δ47 signatures reveal exchange with the aqueous fluid, whereas δ13C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments. 相似文献