Cladocerans and chironomids as indicators of lake level changes in north temperate lakes

Water level fluctuations affect the size of the pelagic zone relative to the size of littoral habitats, and thus may influence the relative abundance of remains from planktonic and littoral cladocerans in sediment. The application of this planktonic/littoral ratio for the reconstruction of past water level changes is discussed using examples of: (1) surficial profundal sediments from lakes of different water depths; (2) Holocene variation in a profundal sediment core; (3) horizontal variation in surficial sediments within a lake; and (4) long term variation in an inshore sediment core. The latter seemed to be the most promising application of this ratio. Maximum effects of water depth changes on the lake fauna are expected in the littoral zone. It is, however, difficult to read this effect directly from subfossil cladoceran and chironomid assemblages from inshore sediments as shown by a sediment profile from a site exposed to a long term decrease of water depth.     

On the transfer of stratospheric ozone into the troposphere near the north pole

A series of nearly daily ozone vertical profiles obtained at station T-3 on Fletcher's Ice Island (85°N, 90°W) during the period January-March 1971 shows several significant ozone intrusions into the troposphere. These intrusions are not only associated with enhanced ozone amounts in the stratosphere but also require tropopause folding events to transport ozone into the troposphere. These folds in the Arctic tropopause appear to be capable of contributing significantly to the ozone budget of the Arctic troposphere during the late winter and spring seasons. The importance of tropopause folding for bringing ozone into the troposphere seen in the daily ozone profiles confirms the results found in the Arctic Gas and Aerosol Sampling Program aircraft flights.     

Estimates of gross and net fluxes of carbon between the biosphere and the atmosphere from biomass burning

In order to estimate the production of charcoal and the atmospheric emissions of trace gases volatilized by burning we have estimated the global amounts of biomass which are affected by fires. We have roughly calculated annual gross burning rates ranging between about 5 Pg and 9 Pg (1 Pg = 10¹⁵ g) of dry matter (2–4 Pg C). In comparison, about 9–17 Pg of above-ground dry matter (4–8 Pg C) is exposed to fires, indicating a worldwide average burning efficiency of about 50%. The production of dead below-ground dry matter varies between 6–9 Pg per year. We have tentatively indicated the possibility of a large production of elemental carbon (0.5–1.7 Pg C/yr) due to the incomplete combustion of biomass to charcoal. This provides a sink for atmospheric CO₂, which would have been particularly important during the past centuries. From meager statistical information and often ill-documented statements in the literature, it is extremely difficult to calculate the net carbon release rates to the atmosphere from the biomass changes which take place, especially in the tropics. All together, we calculate an overall effect lof the biosphere on the atmospheric carbon dioxide budget which may range between the possibilities of a net uptake or a net release of about 2 Pg C/yr. The release of CO₂ to the atmosphere by deforestation projects may well be balanced by reforestation and by the production of charcoal. Better information is needed, however, to make these estimates more reliable.Now at the Max-Planck-Institute for Chemistry, Mainz, FRG.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

A Three-year Study of Nonmethane Hydrocarbons in Surface Air over Saxony (Germany)

Measurements of the nonmethane hydrocarbon (NMHC) mixing ratio over a period of 42 months were carried out for the first time in the air of a research station situated in the former East Germany during the SANA project. Apart from four species, all other species analysed showed a statistically significant downward trend at the 95% significance level. The decrease of the hydrocarbon concentrations was superimposed by seasonal variations. A drop of about 40% of the annual mean values from 1993 to 1995 was observed. This development reflects the dramatic changes in traffic, industry, power economy, and agriculture in Saxony after the reunification of Germany. The remove of two-stroke engined cars is reflected in NMHC mixing ratio changes, as is the removal of obsolete chemical plants. Generally it was not possible to relate causes and effects of a single event, but in some cases major changes in concentrations and NMHC ratios occurred coincidentally with the disappearance of a specific emission source.     

Geochronological constraints on the evolution of the Periadriatic Fault System (Alps)

Fault rocks from various segments of the Periadriatic fault system (PAF; Alps) have been directly dated using texturally controlled Rb-Sr microsampling dating applied to mylonites, and both stepwise-heating and laser-ablation ⁴⁰Ar/³⁹Ar dating applied to pseudotachylytes. The new fault ages place better constraints on tectonic models proposed for the PAF, particularly in its central sector. Along the North Giudicarie fault, Oligocene (E)SE-directed thrusting (29-32 Ma) is currently best explained as accommodation across a cogenetic restraining bend within the Oligocene dextral Tonale-Pustertal fault system. In this case, the limited jump in metamorphic grade observed across the North Giudicarie fault restricts the dextral displacement along the kinematically linked Tonale fault to ~30 km. Dextral displacement between the Tonale and Pustertal faults cannot be transferred via the Peio fault because of both Late Cretaceous fault ages (74-67 Ma) and sinistral transtensive fault kinematics. In combination with other pseudotachylyte ages (62-58 Ma), widespread Late Cretaceous-Paleocene extension is established within the Austroalpine unit, coeval with sedimentation of Gosau Group sediments. Early Miocene pseudotachylyte ages (22-16 Ma) from the Tonale, Pustertal, Jaufen and Passeier faults argue for a period of enhanced fault activity contemporaneous with lateral extrusion of the Eastern Alps. This event coincides with exhumation of the Penninic units and contemporaneous sedimentation within fault-bound basins.     

The DAV and Periadriatic fault systems in the Eastern Alps south of the Tauern window

Alpine deformation of Austroalpine units south of the Tauern window is dominated by two kinematic regimes. Prior to intrusion of the main Periadriatic plutons at ~30 Ma, the shear sense was sinistral in the current orientation, with a minor north-side-up component. Sinistral shearing locally overprints contact metamorphic porphyroblasts and early Periadriatic dykes. Direct Rb-Sr dating of microsampled synkinematic muscovite gave ages in the range 33-30 Ma, whereas pseudotachylyte locally crosscutting the mylonitic foliation gave an interpreted ⁴⁰Ar-³⁹Ar age of ~46 Ma. The transition from sinistral to dextral (transpressive) kinematics related to the Periadriatic fault occurred rapidly, between solidification of the earlier dykes and of the main plutons. Subsequent brittle-ductile to brittle faults are compatible with N-S to NNW-SSE shortening and orogen-parallel extension. Antithetic Riedel shears are distinguished from the previous sinistral fabric by their fine-grained quartz microstructures, with local pseudotachylyte formation. One such pseudotachylyte from Speikboden gave a ⁴⁰Ar-³⁹Ar age of 20 Ma, consistent with pseudotachylyte ages related to the Periadriatic fault. The magnitude of dextral offset on the Periadriatic fault cannot be directly estimated. However, the jump in zircon and apatite fission-track ages establishes that the relative vertical displacement was ~4-5 km since 24 Ma, and that movement continued until at least 13 Ma.     

Transmission electron microscopic study of antiphase domains in CaAl2Ge2O8-Feldspar

Transmission electron microscopic study of synthetic CaAl₂Ge₂O₈-feldspar revealed two types of antiphase domains: type “b”-antiphase domains with the displacement vector 1/2 [110] and type “c”-antiphase domains with the displacement vector 1/2 [111]. The “b”-domains were on the order of 0.1 μm in size, while the “c”-domains displayed wall to wall distances mostly between 0.1 and 1 μm. The formation of the two types of antiphase domains is due to reductions in translational symmetry associated with the phase transitions \(C\bar 1 \to I\bar 1 \to P\bar 1\) . The antiphase domain textures of CaAl₂Ge₂O₈-feldspar are very similar to the textures found in natural and synthetic anorthite, CaAl₂Si₂O₈.     

Structure proof and significance of stereoisomeric 28,30-bisnorhopanes in petroleum and petroleum source rocks

Two C₂₈H₄₈-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring $\text{D}\text{E}$cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils.     

Canopy dieback in the upper montane rain forests of Sri Lanka

In 1978 a patch of dying upper montane rain forest had been observed on the slope of Thotupolakanda above Horton Plains. Patches in the upper montane rain forests of Sri Lanka were also recorded in 1980/81. All these sites were on windswept western slopes and ridges with stunted tree growth and shallow soil. From 1971 to 1983 Sri Lanka experienced some exceptionally dry years. The severe droughts of 1976 might have cause or “triggered” that dieback. After heavy rains between 1983 and 1986, these forests showed signs of recovery. Some trees had survived and sprouted again. Tree saplings were found, but regeneration was very low and further impeded by serious frost in February 1986. The influence of drought and frost clearly indicates the vulnerability of the stunted upper montane rain forest in the highest and wind-exposed regions of Sri Lanka.