Arsenic in seawater and brown algae of the Baltic and the North Sea

A long-term study within the pilot environmental specimen bank programme of the Federal Republic of Germany on arsenic levels in coastal and open seawater and their reflection in the brown seaweed (Fucus vesiculosus) has been performed. Dissolved arsenic was on average 0.76 (range 0.45–1.11) μgl⁻¹ for 17 sampling stations in the Baltic Sea, whereas contents of dissolved arsenic are somewhat higher in shallow waters of the coastal zone of the North Sea. Total arsenic levels in algae ranged up to 40 mg kg⁻¹ (dry weight) and showed for the four locations studied obvious seasonal variations for comparatively nonpolluted or nondisturbed locations only. However, probably due to biological influences, the results obtained so far indicate that composite samples integrating a one year period are supposed to be the best strategy for future environmental specimen banking. Using a new efficient speciation technique the percentage of chemically stable organoarsenic compounds in the investigated algae has been found to be 95% of the total arsenic content and thus somewhat lower than in teleost fish. For comparison, typical data for a few other algae species from the Baltic and the Mediterranean Sea are also shown.     

Pulsar nebulae

Several of the exotic supernova remnants are re-interpreted as pulsar-illuminated former windzones. The class of supernova remnants thus splits into (i) (the usual) shell remnants and (ii) pulsar nebulae in which a (fairly young) pulsar blows its relativistic wind into its low-density environs.     

Stockert's chimney — A galactic fountain

A new type of galactic outflow phenomenon has been discovered and published under the name of thermal spur by Mülleret al. (1987). It is argued that this outflow consists of relativistic pair plasma with an admixture of partially ionized hydrogen and cosmic rays, escaping from a large Hii region. This chimney serves as a substantial leak for the cosmic rays, i.e., may be an essential part of the galactic foundtain.     

The critical state behaviour of barodesy compared with the Matsuoka–Nakai failure criterion

Barodesy is a new approach to constitutive modelling of soil. It is based on Goldscheider's principles and maps stretching directions onto corresponding stress directions with the help of a simple exponential function. This mapping also determines a critical state surface in principal stress space. The article investigates this surface and relates it to the well‐known Matsuoka–Nakai failure criterion. It turns out that the difference between these two surfaces is negligible for practical applications. Copyright © 2011 John Wiley & Sons, Ltd.     

Paleontology,sedimentology and paleoenvironment of a new fossiliferous locality of the Jurassic Cañadón Asfalto Formation,Chubut Province,Argentina

A new Late Jurassic assemblage of “conchostracans”, ostracods, bivalves and caddisfly cases from the locality “Estancia La Sin Rumbo”, Chubut Province (Patagonia, Argentina) is recorded. The fossils occur in the upper part of an outcropping 45 m thick volcaniclastic lacustrine sequence of yellowish tuffs and tuffites of the Puesto Almada Member, which is the upper member of the Cañadón Asfalto Formation with U/Pb age of 161 ± 3 Ma. The sequence represents one sedimentary cycle composed of a (lower) hemicycle of expansion and a (higher) hemicycle of contraction of the water body. The invertebrates lived in small freshwater bodies during the periods of expansion of the lake. The occurrence of a great number of small spinicaudatans, associated with mud-cracks, is evidence of dry climatic conditions and suggests several local mortality events. The spinicaudatan record of the fushunograptid–orthestheriid (component of the Eosestheriopsis dianzhongensis fauna) and the presence of Congestheriella rauhuti Gallego and Shen, suggest a Late Jurassic (Oxfordian to Tithonian) age. Caddisfly cases are recorded for the first time in the Cañadón Asfalto Basin.     

Rainfall interception in a lower montane forest in Ecuador: effects of canopy properties

Rainfall interception in forests is influenced by properties of the canopy that tend to vary over small distances. Our objectives were: (i) to determine the variables needed to model the interception loss of the canopy of a lower montane forest in south Ecuador, i.e. the storage capacity of the leaves S and of the trunks and branches S_t, and the fractions of direct throughfall p and stemflow p_t; (ii) to assess the influence of canopy density and epiphyte coverage of trees on the interception of rainfall and subsequent evaporation losses. The study site was located on the eastern slope of the eastern cordillera in the south Ecuadorian Andes at 1900–2000 m above sea level. We monitored incident rainfall, throughfall, and stemflow between April 1998 and April 2001. In 2001, the leaf area index (LAI), inferred from light transmission, and epiphyte coverage was determined. The mean annual incident rainfall at three gauging stations ranged between 2319 and 2561 mm. The mean annual interception loss at five study transects in the forest varied between 591 and 1321 mm, i.e. between 25 and 52% of the incident rainfall. Mean S was estimated at 1·91 mm for relatively dry weeks with a regression model and at 2·46 mm for all weeks with the analytical Gash model; the respective estimates of mean S_t were 0·04 mm and 0·09 mm, of mean p were 0·42 and 0·63, and of mean p_t were 0·003 and 0·012. The LAI ranged from 5·19 to 9·32. Epiphytes, mostly bryophytes, covered up to 80% of the trunk and branch surfaces. The fraction of direct throughfall p and the LAI correlated significantly with interception loss (Pearson's correlation coefficient r = −0·77 and 0·35 respectively, n = 40). Bryophyte and lichen coverage tended to decrease S_t and vascular epiphytes tended to increase it, although there was no significant correlation between epiphyte coverage and interception loss. Our results demonstrate that canopy density influences interception loss but only explains part of the total variation in interception loss. Copyright © 2004 John Wiley & Sons, Ltd.     

Third-order depositional sequences reflecting Milankovitch cyclicity

The origin of third-order depositional sequences remains debatable, and in many cases it is not clear whether they were controlled by tectonic activity and/or by eustatic sea-level changes. In Oxfordian and Berriasian–Valanginian carbonate-dominated sections of Switzerland, France, Germany and Spain, high-resolution sequence-stratigraphic and cyclostratigraphic analyses show that the sedimentary record reflects Milankovitch cyclicity. Orbitally induced insolation changes translated into sea-level fluctuations, which in turn controlled accommodation changes. Beds and bedsets formed in rhythm with the precession and 100-kyr eccentricity cycles, whereas the 400-kyr eccentricity cycle contributed to the creation of major depositional sequences. Biostratigraphical data allow the correlation of many of the 400-kyr sequence boundaries with third-order sequence boundaries recognized in European basins. This implies that climatically controlled sea-level changes contributed to the formation of third-order sequences. Furthermore, this cyclostratigraphical approach improves the relative dating of stratigraphic intervals.     

Proportional stress and strain paths in barodesy

Asymptotic behaviour of soil deserves particular attention: If soil is deformed with a proportional strain path, the resulting stress path approaches asymptotically a proportional stress path. In this arcticle, we review existing experimental evidence on this phenomenon and discuss it in the frame of barodesy. Here, the presented relation is a modification of a barodetic expression and includes Jáky's relation, inhibits tensile stress and is able to predict asymptotic stress ratios based on experimental findings. The proposed relation is compared with experimental data as well as with the so‐called stress‐dilatancy relations and other constitutive relations proposed so far. Copyright © 2015 John Wiley & Sons, Ltd.     

Validation of ERS scatterometer‐derived soil moisture data in the central part of the Duero Basin,Spain

The objective of this study was to validate the soil moisture data derived from coarse‐resolution active microwave data (50 km) from the ERS scatterometer. The retrieval technique is based on a change detection method coupled with a data‐based modelling approach to account for seasonal vegetation dynamics. The technique is able to derive information about the soil moisture content corresponding to the degree of saturation of the topmost soil layer (∼5 cm). To estimate profile soil moisture contents down to 100 cm depth from the scatterometer data, a simple two‐layer water balance model is used, which generates a red noise‐like soil moisture spectrum. The retrieval technique had been successfully applied in the Ukraine in a previous study. In this paper, the performance of the model in a semi‐arid Mediterranean environment characterized by low annual precipitation (400 mm), hot dry summers and sandy soils is investigated. To this end, field measurements from the REMEDHUS soil moisture station network in the semi‐arid parts of the Duero Basin (Spain) were used. The results reveal a significant coefficient of determination (R² = 0·75) for the averaged 0–100 cm soil moisture profile and a root mean square error (RMSE) of 2·2 vol%. The spatial arrangement of the REMEDHUS soil moisture stations also allowed us to study the influence of the small‐scale variability of soil moisture within the ERS scatterometer footprint. The results show that the small‐scale variability in the study area is modest and can be explained in terms of texture fraction distribution in the soil profiles. Copyright © 2004 John Wiley & Sons, Ltd.