BiSON performance

Since 1981 we have been operating the Birmingham Solar-Oscillations Network (BiSON), a global network of resonant-scattering spectrometers, observing the low-l solar p modes. Here we discuss historical developments, culminating in the establishment of a 6-station network in 1992 September, and the subsequent performance of that network. The data record of each station from 1992 to 1994 has been analysed in terms of weather and equipment breakdowns. Our early experience suggests that the best long-term coverage possible with a 6-station network is limited in practice to about 80%, which falls short of previous predictions.     

Manganese chemistry in rivers and streams

The speciation of Mn has been determined in 15 rivers and streams representing a wide variety of physico-chemical conditions. Using the technique of anodic stripping voltammetry (asv), specific for reduced Mn(II) species, it is found that a major part of the <0.015 μm Mn size fraction is present in a reduced Mn(II), asv-labile, form. In some waters there is also a significant asv inactive Mn fraction considered to be present as a ‘small colloidal’ species. The soluble (<0.015 μm) Mn fraction represents 15–95% of total Mn and does not appear to be dependent upon pH, alkalinity, specific conductance or humic substance concentration in the water. It is argued that under the dynamic, short residence time, conditions that apply in most rivers the paniculate and soluble Mn fractions are decoupled, their respective presence being dependent principally upon the catchment hydrogeological conditions. This contrasts with a previously held view that the paniculate phase is coupled to the dissolved phase by the pH dependent oxidation of dissolved Mn(II) to highly insoluble Mn(IV) species (Graham et al., 1976). Consideration of manganese speciation in waters which were incubated for five months showed that pH becomes the controlling factor when equilibrium is approached.     

Size and elemental distributions of nano- to micro-particulates in the geochemically-stratified Great Salt Lake

The characterization of trace elements in terms of their apportionment among dissolved, macromolecular, nano- and micro-particulate phases in the water column of the Great Salt Lake carries implications for the potential entry of toxins into the food web of the lake. Samples from the anoxic deep and oxic shallow brine layers of the lake were fractionated using asymmetric flow field-flow fractionation (AF4). The associated trace elements were measured via online collision cell inductively-coupled plasma mass spectrometry (CC-ICP-MS). Results showed that of the total (dissolved + particulate) trace element mass, the percent associated with particulates varied from negligible (e.g. Sb), to greater than 50% (e.g. Al, Fe, Pb). Elements such as Cu, Zn, Mn, Co, Au, Hg, and U were associated with nanoparticles, as well as being present as dissolved species. Particulate-associated trace elements were predominantly associated with particulates larger than 450 nm in size. Among the smaller nanoparticulates (<450 nm), some trace elements (Ni, Zn, Au and Pb) showed higher percent mass (associated with nanoparticles) in the 0.9–7.5 nm size range relative to the 10–250 nm size range. The apparent nanoparticle size distributions were similar between the two brine layers; whereas, important differences in elemental associations to nanoparticles were discerned between the two layers. Elements such as Zn, Cu, Pb and Mo showed increasing signal intensities from oxic shallow to anoxic deep brine, suggesting the formation of sulfide nanoparticles, although this may also reflect association with dissolved organic matter. Aluminum and Fe showed greatly increased concentration with depth and equivalent size distributions that differed from those of Zn, Cu, Pb and Mo. Other elements (e.g. Mn, Ni, and Co) showed no significant change in signal intensity with depth. Arsenic was associated with <2 nm nanoparticles, and showed no increase in concentration with depth, possibly indicating dissolved arsenite. Mercury was associated with <2 nm nanoparticles, and showed greatly increased concentration with depth, possibly indicating association with dissolved organic matter.     

Natural Infrasound as an Atmospheric Probe

Summary For four years continuous recording of infrasonic signals in the frequency range 0.1 to 1 Hz, known as microbaroms, has been conducted at Palisades, New York. The microbaroms we recorded are radiated into the atmosphere by interfering ocean waves in the North Atlantic as far as 2000 km away. A characteristic diurnal variation in the amplitude of the received signal has been noted, independent of any variation in the source. We conclude that the variation is due to variations of the factors affecting atmospheric sound propagation, namely wind and temperature.
In winter a semidiurnal variation in signal amplitude is observed, with maximum reception around 11 : 00 and 22; 00 local time. Reference to wind and temperature observations in the literature shows that at these times the lowest level of reflection of the vertically propagating signal occurs between 100 and 110 km due to the presence of strong east winds. At 18 : 00, time of minimum amplitudes, the reflection level rises to about 115 km because of a change in tidal wind phase. Viscous dissipation associated with the changed reflection height can account for the observed signal weakening. A third maximum, a less regular effect, is found to be related to more variable winds between 95 and 105 km.
In summer, reflection is found to occur from about 50 km due to the presence of stratospheric easterlies. The summer diurnal variation, different from that of the winter, exhibits only a weak minimum about 20 : 00. This appears to result from a diurnal temperature variation superimposed on a diurnal wind variation. Abnormally high microbaroms were recorded at times that can be related to an atmospheric event known as a stratospheric warming. Microbaroms thus provide a continuously available natural mechanism for probing the upper atmosphere. We conclude that the establishment of microbarom observation systems could give a comprehensive technique for monitoring several upper atmospheric parameters.     

Tidal deformation of a viscoelastic body

Summary. The tidal deformation of a homogeneous viscoelastic sphere due to the gravitational attraction of an external body is calculated. The sphere is modelled as an incompressible Kelvin-Voigt solid. An equation for the displacement field is obtained assuming that strains are small and inertia is negligible. This equation has a series solution in terms of Legendre polynomials. The resulting expression for the displacement field reduces to that for an elastic solid and a viscous fluid in the appropriate limits of the material constants. The first term in the viscoelastic solution is used to calculate the moments induced by tidal deformation assuming a circular orbit. In the absence of obliquity and precession, these moments reduced to a torque about the spin axis. This torque is compared to that predicted by a phase lag analysis. These two approaches are formally equivalent if the tidal dissipation function Q ⁻¹ depends in a specific way on the difference of the spin and orbital angular velocities.     

First Order Seismic Microzonation of Delhi,India Using Geographic Information System (GIS)

A first order seismic microzonation map of Delhi is prepared using five thematic layers viz., Peak Ground Acceleration (PGA) contour, different soil types at 6 m depth, geology, groundwater fluctuation and bedrock depth, integrated on GIS platform. The integration is performed following a pair-wise comparison of Analytical Hierarchy Process (AHP), wherein each thematic map is assigned weight in the 5-1 scale: depending on its contribution towards the seismic hazard. Following the AHP, the weightage assigned to each theme are: PGA (0.333), soil (0.266), geology (0.20), groundwater (0.133) and bedrock depth (0.066). The thematic vector layers are overlaid and integrated using GIS. On the microzonation theme, the Delhi region has been classified into four broad zones of vulnerability to the seismic hazard. They are very high (> 52%), high (38–52%), moderate (23–38%) and less ( < 23%) zones of seismic hazard. The “very high” seismic hazard zone is observed where the maximum PGA varies from 140 to 210 gal for a finite source model of M_w 8.5 in the central seismic gap. A site amplification study from local and regional earthquakes for Delhi region using Delhi Telemetry Network data shows a steeper site response gradient in the eastern side of the Yamuna fluvial deposits at 1.5 Hz. The ‘high’ seismic hazard zone occupies most of the study area where the PGA value ranges from 90 to 140 gal. The ‘moderate’ seismic hazard zone occurs on either side of the Delhi ridge with PGA value varying from 60 to 90 gal. The ‘less’ seismic hazard zone occurs in small patches distributed along the study area with the PGA value less than 60 gal. Site response studies, PGA distribution and destruction pattern of the Chamoli earthquake greatly corroborate the seismic hazard zones estimated through microzonation on GIS platform and also establishes the methodology incorporated in this study.     

The Laurentian Fan: Sohm abyssal plain

The 0.5- to 2-km thick Quaternary Laurentian Fan is built over Tertiary and Mesozoic sediments that rest on oceanic crust. Two 400-km long fan valleys, with asymmetric levees up to 700-m high, lead to an equally long, sandy, lobate basin plain (northern Sohm Abyssal Plain). The muddy distal Sohm Abyssal Plain is a further 400-km long. The sediment supplied to the fan is glacial in origin, and in part results from seismically triggered slumping on the upper continental slope. Sandy turbidity currents, such as the 1929 Grand Banks earthquake event, probably erode the fan-valley floors; but thick muddy turbidity currents build up the high levees.