A critical review of three methods used for the measurement of mercury (Hg)-dissolved organic matter stability constants

Three experimental techniques – ion exchange, liquid–liquid extraction with competitive ligand exchange, and solid-phase extraction with competitive ligand exchange (CLE–SPE) – were evaluated as methods for determining conditional stability constants (K) for the binding of mercury (Hg²⁺) to dissolved organic matter (DOM). To determine the utility of a given method to measure stability constants at environmentally relevant experimental conditions, experimental results should meet three criteria: (1) the data must be experimentally valid, in that they were acquired under conditions that meet all the requirements of the experimental method, (2) the Hg:DOM ratio should be determined and it should fall within levels that are consistent with environmental conditions, and (3) the stability constants must fall within the detection window of the method. The ion exchange method was found to be limited by its detection window, which constrains the method to stability constants with log K values less than about 14. The liquid–liquid extraction method was found to be complicated by the ability of Hg–DOM complexes to partition into the organic phase. The CLE–SPE method was found to be the most suitable of these methods for the measurement of Hg–DOM stability constants. Stability constants for DOM isolates measured using the CLE–SPE method at environmentally relevant Hg:DOM ratios were log K = 25–30 (M⁻¹). These values are consistent with the strong Hg²⁺ binding expected for reduced S-containing binding sites.     

Water masses of the northern part of the Iceland Basin in the late Pleistocene

A core of bottom sediments AMK-4438 with a length of 320 cm was taken in the North-Eastern part of the Iceland Basin from the depth of 2240 m. The continuous sampling (every 2 cm) made it possible to study the core using the principle of high-resolving paleoceanology. For the stratigraphic partition of the core, we applied the paleotemperature analysis by planktonic foraminifera and carbonate analysis; the distribution of the iceberg rafted debris (IRD) was studied. As a result, nine isotopic stages were distinguished. The change in the complexes of benthic foraminifera indicates that the present-day deepwater circulation in the North-Eastern part of the Iceland Basin had no analogs in earlier glacial periods, including the MIS 5 age. During almost 300 ka, there were relatively warm, rich in nutrients, and poor in oxygen water masses. The formation of the modern Northern-Eastern deep water in the Iceland Basin began in the Bolling-Allerod 14 ka B.P.     

Comparing Reservoir and Outcrop Specimens for Mixed Mode I–II Fracture Toughness of a Limestone Rock Formation at Various Conditions

Summary A fracture toughness study was conducted on a limestone rock formation from a petroleum reservoir in Saudi Arabia, and results were compared with those for outcrop specimens from the same geological formation. The objective was to investigate the possibility of using outcrop specimens to estimate the fracture toughness behavior of reservoir rock at in-situ conditions of temperature and confining pressure. The study was made on reservoir specimens from a depth of about 3.5 km, at both ambient and reservoir conditions. Mixed mode I–II fracture toughness at reservoir conditions of high temperature and confining pressure was studied using straight notched Brazilian disk (SNBD) specimens under diametrical compression. Tests were conducted at ambient conditions, at an effective confining pressure (σ₃) of 28 MPa (4000 psi), and at a temperature of 116^°C. The results showed a substantial increase in fracture toughness under confining pressure. Under σ₃=28 MPa, the pure mode-I fracture toughness (K _IC), increased by a factor of about 3.2, and the pure mode-II fracture toughness (K _IIC) increased by a factor of 4.4, compared to those under ambient conditions. On the other hand, K _IC at 116^°C was only 25% more than that at ambient conditions. These results were compared with recent results for outcrop specimens from the same geological formation. The results reveal that outcrop specimens can be successfully used to predict the fracture behavior of reservoir specimens at in-situ conditions, in spite of some differences at ambient conditions. Additionally, fracture toughness envelopes were obtained for reservoir specimens at ambient and high pressure conditions, in both positive and negative regions. Received September 14, 2000; accepted February 22, 2002 Published online September 2, 2002     

Changes in Global Monsoon Circulations Since 1950

We examined changes in several independent intensity indices of four majortropical monsoonal circulations for the period 1950–1998. Theseintensity indices included observed land surface precipitation andobserved ocean surface pressure in the monsoon regions aswell as upper-level divergence calculated at severalstandard levels from the NCAR/NCEP reanalysis. These values wereaveraged seasonally over appropriate regions of southeastern Asian, western Africa, eastern Africa and the Australia/Maritime continent and adjacent ocean areas. Asa consistency check we also examined two secondary indices: mean sea level pressure trends and low level convergence both from theNCEP reanalysis.We find that in each of the four regions examined, a consistentpicture emerges indicating significantly diminished monsoonalcirculations over the period of record, evidence of diminished spatialmaxima in the global hydrological cycle since 1950. Trends since 1979,the period of strongest reported surface warming, do not indicate any change inmonsoon circulations. When strong ENSO years are removed from each of the time series the trends still show a general, significant reduction of monsoon intensity indicating that ENSO variability is not the direct cause for the observed weakening.Most previously reported model simulations of theeffects of rising CO₂ show an increase in monsoonal activity withrising global surface temperature. We find no support in these datafor an increasing hydrological cycle or increasing extremes as hypothesized bygreenhouse warming scenarios.     

The High Concentration Tails Of The Probability Density Function Of A Dispersing Scalar In The Atmosphere

The distribution function for concentrations of a scalar pollutant dispersing in the turbulent atmosphere has a finite domain that is bounded above and below. Three methods, based on extreme value statistics, are used to obtainestimates for the upper bound and to describe the high concentration tailbehaviour of the distribution; all three methods are applied to concentrationdata obtained from experimental atmospheric releases. Quantile quantile (QQ)plots are used to assess the goodness of fit of the resulting estimates of thedistribution, and also to compare the performance of the three methods. Thepredicted values for the upper bound are orders of magnitude less than thesource concentration, illustrating that molecular diffusion has a large effecton the high concentrations.     

Aluminum in surface water of Ukraine: Concentrations, migration forms, distribution among abiotic components

The results of studying the forms of aluminum occurrence in water bodies of Ukraine with different water regime and physical and chemical characteristics are discussed. The quantitative relationships between suspended and dissolved forms of aluminum, the relationship between suspended aluminum and the mass of suspended matter, and the role of complexation in Al(III) migration are considered. The distribution of Al(III) among complex compounds with dissolved organic substances with different chemical nature and molecular mass (anionic fraction) is analyzed. Humic substances are shown to play the major role in Al(III) binding.     

Analytical and experimental investigations on seismic performance of exterior beam–column subassemblages of existing RC‐framed building

Seismic performance of exterior beam–column subassemblages of reinforced concrete structure designed and detailed on the basis of the provisions of Eurocode and Indian Standards at different stages of their evolution is evaluated. Performance of the subassemblages designed and detailed according to the three different stages of codal evolution (gravity load design, ‘Nonductile’, and ‘Ductile’) is evaluated through analytical formulations and experimental investigations. In the ‘NonDuctile’ specimens, it has been observed that the shear distortion and degradation in stiffness and strength are significantly high. Performance of the ‘Ductile’ specimens based on Eurocode and Indian Standards is almost similar in terms of strength and stiffness degradation. Nevertheless, the specimen designed on the basis of Indian Standard shows higher energy dissipation at a given drift ratio. In the analytical study, shear and flexural failure of members of subassemblage and shear failure of the joint are considered as possible modes of failure of the beam–column subassemblage. For evaluating the shear strength of the joint region, a soften strut‐and‐tie model is used. Analytically obtained strengths based on the failure criteria of different components of the specimens have been first validated with experimental results and then used to determine the strength of the specimens. The investigation could indicate even the mode of failure at local level. It is utmost important to mention here that even the ductile specimens dissipate most of the energy through the development of damage in the joint region, which is neither desirable nor safe for the stability of whole structure. Copyright © 2013 John Wiley & Sons, Ltd.     

Geoarchaeological evidence on a Late Bronze Age earthquake,Ohrid Basin (North Macedonia)

Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean.     

First finds of Late Tithonian and middle-late Albian radiolarian assemblages in volcanogenic-siliceous rocks of the Amur River right lower reaches and their tectonic significance

The lithological-stratigraphic study of volcanogenic-siliceous rocks developed on the left side of the Machtovaya River, a right tributary of the Amur River, yielded the first radiolarian assemblages of the late Late Tithonian, the late Late Tithonian-early Valanginian, and the middle-late Albian age. It is established that the stratigraphic succession of volcanogenic-siliceous rocks in this area is composed of upper Tithonian-Valanginian dark red to red-brown cherts with basalts in the lower part of the section and Albian dark gray clayey cherts, olive-gray siliceous-tuffaceous argillites, and tufaceous siltstones in its upper part. The replacement of cherts by their clayey varieties likely occurred in the Aptian. The composition, structure, and age of these strata and the rocks constituting the Kiselevka-Manoma accretionary complex are different, which indicates their different tectonic origin.     

灌注桩后注浆技术应用研究及承载力影响分析

对后注浆技术未能大幅提高灌注桩单桩承载力的工程个案展开分析研判,得出注浆过程控制不力是导致单桩承载力不足的主要原因。严格注浆管、射浆管、逆止阀制作质量管控与安装及注浆过程控制是能否成功注浆进而提高承载力的关键因素。工程案例中对承载力欠缺的区域进行了补桩处理,补桩时规范注浆装置制作、加强注浆过程管控,在补桩达到龄期后进行了静载试验,结果表明其单桩竖向极限承载力满足设计要求。