The Cretaceous-Tertiary fireball layer,ejecta layer and coal seam: Platinum-group element content and mineralogy of size fractions

Abstract— Grain size separates of the Cretaceous-Tertiary (K-T) fireball layer at marine sites and the entire K-T boundary interval at nonmarine sites (fireball layer, ejecta layer, coal seam) were analysed for platinum-group elements (PGE: Ru, Ir, Ft, Pd, Rh) and Au using inductively coupled plasma mass-spectrometry. X-ray diffractometry and scanning electron microscopy were performed on each fraction to establish the mineralogy. It was determined that the most abundant minerals in the finest fraction were a smectite-group mineral at marine K-T sites and illite-smectite mixed layer clay at nonmarine K-T sites. Positive correlation of PGE content and mineralogy indicates that the PGE are presently associated with these clay minerals which were likely formed by alteration of a condensed mafic phase (e.g., olivine or pyroxene). The correlation of clay mineral abundance with PGE content is imperfect because not all of the clay minerals in the fireball layer are derived by alteration of the original condensed ejecta. In addition, undetected PGE host(s), present in trace amounts, are likely also present.     

Bottom-water Hypoxia Effects on Sediment–Water Interface Nitrogen Transformations in a Seasonally Hypoxic,Shallow Bay (Corpus Christi Bay,TX, USA)

Bottom-water hypoxia effects on sediment–water interface nitrogen (N) transformations in Corpus Christi Bay (TX, USA) were examined using continuous-flow intact sediment core incubations. Sediment cores were collected from three sites in August 2002 (summer hypoxia) and April 2003 (normoxia). Oxygen (O₂) and hydrogen sulfide (H₂S) depth profiles were generated with microelectrodes. Membrane inlet mass spectrometry was used to measure sediment O₂ demand and net N₂ flux and combined with isotope pairing to determine potential denitrification and N fixation. Potential dissimilatory nitrate reduction to ammonium (DNRA) was measured using high-performance liquid chromatography. Sediment O₂ penetration depths ranged from 5 to 10 mm. H₂S ranged from being present in overlying water and throughout the sediment column in August to not detectable in overlying water or sediment in April. Sediment O₂ demand was higher during bottom-water normoxia conditions versus hypoxia. Sediments were a significant source of \textNH_\text4^{\text +} {\text{NH}}_{\text{4}}^{\text{ + }} to overlying water during hypoxia but not during normoxia. Net N₂ fixation was observed at one station in August and all stations in April. Denitrification rates were significantly higher during hypoxia at two of three sites. Potential DNRA was observed during both oxic states, but rates were significantly higher during hypoxia, which may reflect sulfide enhancement and absence of cation exchange with ^\text14 \textNH_\text4^{\text +} ^{{\text{14}}} {\text{NH}}_{\text{4}}^{\text{ + }} . DNRA may contribute to formation and maintenance of bottom-water hypoxic events in this system. These results show that N transformation pathways and rates change when bottom-water O₂ concentrations drop to hypoxic levels. Since south Texas is a semiarid region with few episodic runoff events, these results indicate that Corpus Christi Bay sediments are a N source most of the year, and denitrification may drive N limitation between episodic runoff events.     

Bimodal volcanism in northeast Puerto Rico and the Virgin Islands (Greater Antilles Island Arc): Genetic links with Cretaceous subduction of the mid-Atlantic ridge Caribbean spur

Bimodal extrusive volcanic rocks in the northeast Greater Antilles Arc consist of two interlayered suites, including (1) a predominantly basaltic suite, dominated by island arc basalts with small proportions of andesite, and (2) a silicic suite, similar in composition to small volume intrusive veins of oceanic plagiogranite commonly recognized in oceanic crustal sequences. The basaltic suite is geochemically characterized by variable enrichment in the more incompatible elements and negative chondrite-normalized HFSE anomalies. Trace element melting and mixing models indicate the magnitude of the subducted sediment component in Antilles arc basalts is highly variable and decreases dramatically from east to west along the arc. In the Virgin Islands, the sediment component ranges between< 0.5 to  1% in Albian rocks, and between  1 and 2% in succeeding Cenomanian to Campanian strata. In comparison, sediment proportions in central Puerto Rico range between 0.5 to 1.5% in the Albian to 2 to > 4% during the Cenomanian-Campanian interval. The silicic suite, consisting predominantly of rhyolites, is characterized by depleted Al₂O₃ (average < 16%), low Mg-number (molar Mg/Mg + Fe < 0.5), TiO₂ (< 1.0%), and Sr/Y (< 10), oceanic or arc-like Sr, Nd, and Pb isotope signatures, and by the presence of plagioclase. All of these features are consistent with an anatexic origin in gabbroic sources, of both oceanic and arc-related origin, within the sub-arc basement. The abundance of silicic lavas varies widely along the length of the arc platform. In the Virgin Islands on the east, rhyolites comprise up to 80% of Lower Albian strata (112 to 105 Ma), and about 20% in post-Albian strata (105 to 100 Ma). Farther west, in Puerto Rico, more limited proportions (< 20%) of silicic lavas were erupted. The systematic variation of both sediment flux and abundance of crustally derived silicic lavas are consistent with current tectonic models of Caribbean evolution involving approximately perpendicular subduction of the Caribbean spur of the mid-Atlantic Ridge, which was located approximately midway between North and South America until Campanian times. Within this hypothetical setting the centrally positioned Virgin Islands terrain remained approximately fixed above the subducting ridge as the Antilles arc platform swept northeastward into the slot between the Americas. Accordingly, heat flow in the Virgin Islands was elevated throughout the Cretaceous, giving rise to widespread crustal melting, whereas the subducted sediment flux was limited. Conversely, toward the west in central Puerto Rico, which was consistently more remote from the subducting ridge, heat flow was relatively low and produced limited crustal melting, while the sediment flux was comparatively elevated.     

Frequency Domain Electromagnetic Induction Sounding Surveys for Landfill Site Characterization Studies

A frequency domain electromagnetic induction sounding survey (FDEM) was conducted on a landfill in northern Illinois to determine the depth of fill, locate areas of drum disposal, and locate areas of heavy metal sludge disposal. Sketchy information obtained from interviews of the site personnel identified specific exploration targets and areas of concern. The results of the geophysical survey verified much of the reported disposal history and identified areas suspected to contain hazardous waste.
Based on the results of the survey, the thickness of fill was estimated and two areas with highly conductive fill were located. These areas could represent leachate pockets or sludge disposal areas. An area in which the fill appears to be thicker than expected was identified. This area is thought to represent industrial sludge disposal in trenches excavated into the existing fill and underlying soils. An area with several linear in-phase, quadrature, and conductivity highs was detected. A subsequent magnetometer survey detected linear magnetic anomalies that are believed to be caused by parallel trenches filled with steel drums. This area is believed to be a previously unreported hazardous waste drum disposal cell excavated into the native soil.
As of this writing, the results of this survey have not been verified by traditional intrusive methods. When these investigations begin, we expect that information provided by the FDEM survey will reduce project costs by directing subsequent investigations, thereby reducing the number of borings and test pits required to characterize the site. While there is an unavoidable margin of error and uncertainty in remote sensing methods, the subsurface coverage provided by this geophysical survey could not have been reproduced by traditional methods without substantial expense. This paper presents the results of the survey and discusses application of the FDEM method on landfills.     

Complementary Investigative Techniques for Site Assessment with Low-Level Contaminants

A remedial investigation (RI) was performed in an area downgradient from an abandoned missile silo at Vandenberg Air Force Base, California, as part of the United States Air Force Installation Restoration Program (IRP). A number of complementary investigative techniques were used to assure a reliable assessment of site contamination. These included the review of aerial photographs, the use of an organic vapor analyzer (OVA) and carbon adsorption/mass spectrometer (MS) method to conduct a soil-gas survey; magnetic and electromagnetic geophysical surveys; bedrock permeability testing; and the chemical analysis of soil, sediment, surface water, and ground water samples. The results from this investigation revealed the presence of an undocumented landfill and a small trichloroethylene plume in ground water at concentrations ranging from 6.7 ppb to 31 ppb. The investigation also identified local ground water flow direction, provided strong evidence of the location of potential sources of contamination, and defined the downgradient extent of ground water contamination. Because the identified contaminants have not as yet reached the environmentally sensitive wetland at the base of the slope below this facility, there is still time to propose remedial alternatives that would serve to protect this environmentally sensitive area.     

Measurement of sediment resuspension rates in Long Island Sound

Resuspension rates have been measured on Long Island Sound sediments (New York/Connecticut, USA) under an oscillating grid, using a flume, and in place, using high frequency acoustics, transmissometers, and sediment traps. Despite differences, the results compare favorably. The methods all provide an order-of-magnitude estimate of the resuspension rate and increases under storm conditions can be estimated.     

Bedload yields for sand‐bed streams in the Ngarradj Creek catchment,Northern Territory,Australia

Bedload yields were calculated by 39 methods at the East Tributary gauge, nine methods at Upper Swift Creek gauge and 11 methods at Swift Creek gauge in the Ngarradj Creek catchment in northern Australia. These methods involved combining various significant bedload rating curves determined for a measured bedload data set for a 4‐year period with either the hourly or daily hydrographs or flow duration curves for the same period, 1 September 1998 to 31 August 2002. Bedload ratings were both statistically significant (ρ ≤ 0.05) and explained at least 60% of the variance in bedload flux. Bias corrections were used with all methods based on log₁₀‐transformed ratings. Estimated mean annual bedload yields varied by three orders of magnitude at the East Tributary gauge and by two orders of magnitude at Upper Swift Creek and Swift Creek gauges. Hourly discharges usually produced higher estimated yields than daily discharges. The bedload rating‐flow duration curve technique overestimates yields and bias correction methods always produce even higher yields. Ratings using both immersed bedload weight and adjusted immersed bedload weight always under‐predicted yields because they contain an implicit threshold of motion condition that is at least four times greater than that predicted by Bagnold's threshold equation. Such a result questions the applicability of Bagnold's threshold equation to the Ngarradj Creek catchment. The best estimates of mean annual bedload yield at East Tributary, Upper Swift Creek and Swift Creek gauges are 600 ± 170 (SE), 1065 ± 150 and 1795 ± 270 t/year, respectively. © 2015 Commonwealth of Australia. Hydrological Processes © 2015 John Wiley & Sons Ltd.