Spectroscopic Study of Carbon Stars with the ISO-SWS

We have observed ten carbon stars with different mass-loss rates using the Short Wavelength Spectrometer (SWS) on board ISO. We found that not only the spectral energy distribution and the dust features, but that also that the strength and/or shape of molecular absorption features in the infrared spectrum varies with the near-infrared color temperature, i.e. with the thickness of the circumstellar envelope. This revised version was published online in August 2006 with corrections to the Cover Date.     

ISO-SWS Spectra of AGB Stars

In this contribution, we present a few highlights of the guaranteed time program to observe AGB stars with differing chemical compositions and mass loss rates using ISO¹ SWS. We briefly discuss C₂H₂ absorption in C-stars and O-rich stars with the 13 μm dust emission. This revised version was published online in September 2006 with corrections to the Cover Date.     

Spitzer observations of acetylene bands in carbon-rich asymptotic giant branch stars in the Large Magellanic Cloud

We investigate the molecular bands in carbon-rich asymptotic giant branch (AGB) stars in the Large Magellanic Cloud (LMC), using the Infrared Spectrograph (IRS) onboard the Spitzer Space Telescope ( SST ) over the 5–38 μm range. All 26 low-resolution spectra show acetylene (C₂H₂) bands at 7 and 14 μm. The hydrogen cyanide (HCN) bands at these wavelengths are very weak or absent. This is consistent with low nitrogen abundances in the LMC. The observed 14 μm C₂H₂  band is reasonably reproduced by an excitation temperature of 500 K. There is no clear dilution of the 14 μm C₂H₂  band by circumstellar dust emission. This 14-μm band originates from molecular gas in the circumstellar envelope in these high mass-loss rate stars, in agreement with previous findings for Galactic stars. The C₂H₂ column density, derived from the 13.7 μm band, shows a gas mass-loss rate in the range 3 × 10⁻⁶ to 5 × 10⁻⁵ M_⊙ yr⁻¹. This is comparable with the total mass-loss rate of these stars estimated from the spectral energy distribution. Additionally, we compare the line strengths of the 13.7 μm C₂H₂  band of our LMC sample with those of a Galactic sample. Despite the low metallicity of the LMC, there is no clear difference in the C₂H₂  abundance among LMC and Galactic stars. This reflects the effect of the third dredge-up bringing self-produced carbon to the surface, leading to high carbon-to-oxygen ratio at low metallicity.     

Reviews

Petrology of the Metamorphic Rocks, 2nd Edn. By R. Mason. Unwin Hyman
Atlas of Metamorphic Rocks and their Textures. By B. W. D. Yardley, W. S. Mackenzie and C. Guilford.     

The application of P–T–X(CO2) modelling in constraining metamorphism and hydrothermal alteration at the Damang gold deposit,Ghana

Orogenic gold mineralization at the Damang deposit, Ghana, is associated with hydrothermal alteration haloes around gold‐bearing quartz veins, produced by the infiltration of a H₂O–CO₂–K₂O–H₂S fluid following regional metamorphism. Alteration assemblages are controlled by the protoliths with sedimentary rocks developing a typical assemblage of muscovite, ankerite and pyrite, while intrusive dolerite bodies contain biotite, ankerite and pyrrhotite, accompanied by the destruction of hornblende. Mineral equilibria modelling was undertaken with the computer program thermocalc , in subsets of the model system MnO–Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–CO₂–H₂O–TiO₂–Fe₂O₃, to constrain conditions of regional metamorphism and the subsequent gold mineralization event. Metapelites with well‐developed amphibolite facies assemblages reliably constrain peak regional metamorphism at ~595 °C and 5.5 kbar. Observed hydrothermal alteration assemblages associated with gold mineralization in a wide compositional range of lithologies are typically calculated to be stable within P–T–X(CO₂) arrays that trend towards lower temperatures and pressures with increasing equilibrium fluid X(CO₂). These independent P–T–X(CO₂) arrays converge and the region of overlap at ~375–425 °C and 1–2 kbar is taken to represent the conditions of alteration approaching equilibrium with a common infiltrating fluid with an X(CO₂) of ~0.7. Fluid‐rock interaction calculations with M–X(CO₂) diagrams indicate that the observed alteration assemblages are consistent with the addition of a single fluid phase requiring minimum fluid/rock ratios on the order of 1.     

Volume Contents

Volume Contents

Volume Contents     

Assessing the extent of disequilibrium and overstepping of prograde metamorphic reactions in metapelites from the Bushveld Complex aureole, South Africa

Andalusite–staurolite–biotite hornfels metamorphosed beneath the mafic layered rocks of the Bushveld Complex, South Africa, preserves a detailed record of the relative timing of porphyroblast growth and metamorphic reactions. The sequence inferred from microstructures shows considerable overlap of the period of growth of porphyroblasts of staurolite, cordierite, biotite and andalusite, and the persistence over a similar interval of the reactant porphyroblastic phase chloritoid. This is inconsistent with calculations of equilibrium phase relations, and implies that disequilibrium processes controlled the prograde reaction sequence, despite the slow heating rates involved (1 °C per 10 000 yr). The early appearance of cordierite by a metastable reaction and its subsequent disappearance indicates that delayed nucleation of porphyroblastic phases, rather than simply sluggish reaction, is required to account for the sequence of growth. The predicted reactions for the first appearance of andalusite and staurolite have low entropy of reaction, and do not occur until they have been overtaken in terms of reaction affinity by high‐entropy devolatilisation reactions involving the breakdown of chlorite. Once the porphyroblasts have nucleated, metastable chloritoid‐breakdown reactions also contribute to their growth. The implied magnitude of the critical overstepping for andalusite nucleation is around 5 kJ mole^?1 (equivalent to 40 °C for the chlorite‐breakdown reaction), and that for other phases is expected to decrease in the order andalusite>staurolite>cordierite. Coupling between nucleation rate, crystal growth rates and the resulting grain size distribution suggests that the rate constants of natural reactions are at least an order of magnitude lower than those measured in the laboratory. Pseudomorphs after chloritoid and cordierite conserve volume but not Al or other species of low mobility, suggesting a breakdown mechanism controlled by an interface process such as the slow dissolution of the refractory porphyroblast phase, rather than by a transport step.     

Sediment records of phosphorus-driven shifts to phytoplanktondominance in shallow Florida lakes

Primary producer community structure (PPCS) in shallow lakes isinfluenced by phosphorus (P) load and water column P concentration.Theoretically PPCS may shift between phytoplankton and macrophyte states withintermediate P loading, but phytoplankton dominate when P loading exceeds acritical threshold. We analyzed sediment cores from five shallow, eutrophiclakes (size range: 0.6 to 125 km²) that arephytoplankton dominated to determine whether the development of the currentstate was associated stratigraphically with an increase in sediment total P(TP) and a shift in PPCS. We used sponge biogenic silica(BSi_Sponges) concentrations and total carbon to total nitrogenratios (TC:TN) as proxies for macrophyte abundance and sediment organic mattersource, respectively. Three stratigraphic groups of sediments were identifiedwith k-means cluster analysis. These samples were grouped by increasing TPconcentrations and decreasing age and identified as macrophyte, transitionaland phytoplankton sediments. Results show that as P loading increased in thelate 19th and early 20th centuries, the lakes producedsediments with an increasing contribution from phytoplankton. Four of our lakesmay represent a subset of shallow lakes because of their large size (30 to 125km²) and relatively rapid historic P enrichment. Inthese Florida lakes, PPCS shifted to phytoplankton dominance with nopaleolimnological record of lake-wide alternating stable states or of lake-widephytoplankton dominance before anthropogenic P enrichment.