Diagenetic evolution of Aptian evaporites in the Namibe Basin (south‐west Angola)

The widespread and dissected nature of the Angolan gypsiferous salt residuals offers a uniquely detailed view of the lateral and vertical relations inherent to secondary evaporite textures, which typify exhumed salt masses worldwide. Such secondary textures are sometimes misinterpreted as primary evaporite textures. Thin, metre‐scale and patchy, dome‐like gypsum accumulations are well‐exposed within strongly incised present‐day river valleys along the eastern margin of the Namibe and Benguela basins (south‐west Angola). These sections are time equivalent to the main basinward subsurface evaporites (Aptian Loeme Formation) which mostly consist of halite. The gypsum (here called the Bambata Formation) is interpreted to represent the final residual product of fractional dissolution and recrystallization of the halite mass that occurred during Late Cretaceous margin uplift and continues today. This halite underwent multiple episodes of diagenetic alteration between its deposition and its final exhumation, leading to the formation of various secondary gypsum fabrics and solution‐related karst and breccia textures that typify the current evaporite outcrop. Four different diagenetic gypsum fabrics are defined: thinly bedded alabastrine, nodular alabastrine, displacive selenite rosettes and fibrous satin‐spar gypsum. Current arid conditions are responsible for a thin weathered crust developed at the top of the outcropping gypsum, but the fabrics in the main core of the current at‐surface evaporite unit mostly formed during the telogenetic stage of uplift prior to complete subaerial exposure. Alteration occurred as various dissolving and rehydrating saline minerals encountered shallow aquifers in the active phreatic and vadose zones. Geomorphological and petrographic analyses, mostly based on the cross‐cutting relations and crystallographic patterns in the outcrop, are used to propose a sequence of formation of these different fabrics.     

Using monazite and zircon petrochronology to constrain the P–T–t evolution of the middle crust in the Bhutan Himalaya

The growth and dissolution behaviour of accessory phases (and especially those of geochronological interest) in metamorphosed pelites depends on, among others, the bulk composition, the prograde metamorphic evolution and the cooling path. Monazite and zircon are arguably the most commonly used geochronometers for dating felsic metamorphic rocks, yet crystal growth mechanisms as a function of rock composition, pressure and temperature are still incompletely understood. Ages of different growth zones in zircon and monazite in a garnet‐bearing anatectic metapelite from the Greater Himalayan Sequence in NW Bhutan were investigated via a combination of thermodynamic modelling, microtextural data and interpretation of trace‐element chemical ‘fingerprint’ indicators in order to link them to the metamorphic stage at which they crystallized. Differences in the trace‐element composition (HREE, Y, Eu_N/Eu*_N) of different phases were used to track the growth/dissolution of major (e.g. plagioclase, garnet) and accessory phases (e.g. monazite, zircon, xenotime, allanite). Taken together, these data constrain multiple pressure–temperature–time (P–T–t) points from low temperature (<550 °C) to upper amphibolite facies (partial melting, >700 °C) conditions. The results suggest that the metapelite experienced a cryptic early metamorphic stage at c. 38 Ma at <550 °C, ≥0.85 GPa during which plagioclase was probably absent. This was followed by a prolonged high‐T, medium‐pressure (~600 °C, 0.55 GPa) evolution at 35–29 Ma during which the garnet grew, and subsequent partial melting at >690 °C and >18 Ma. Our data confirm that both geochronometers can crystallize independently at different times along the same P–T path and that neither monazite nor zircon necessarily provides timing constraints on ‘peak’ metamorphism. Therefore, collecting monazite and zircon ages as well as major and trace‐element data from major and accessory phases in the same sample is essential for reconstructing the most coherent metamorphic P–T–t evolution and thus for robustly constraining the rates and timescales of metamorphic cycles.     

Solute and isotope constraint of groundwater recharge simulation in an arid environment,Abu Dhabi Emirate,United Arab Emirates

A simple, well-constrained simulation of solute increases in a downgradient direction was used in the shallow unconfined aquifer of eastern Abu Dhabi Emirate (United Arab Emirates). The simulation indicates that the observed exponential increase in solute concentrations results from a combination of upward transport of solutes from underlying mudstones and evaporites, and groundwater losses by evaporation. Groundwater recharge and discharge flux in unconfined regional aquifers in arid regions commonly are difficult to estimate because there are few constraints on the flux of water lost or gained from the system. Total dissolved solids (TDS) and deuterium isotopes (δ²H) in groundwater are used to constrain estimated fluxes to the shallow aquifer of eastern Abu Dhabi Emirate. Vertical upward transport of solutes from underlying mudstones and evaporites accounts for solute increases along approximately the first 80 km of the simulated flow path, but a combination of upward solute transport and evaporation is necessary to explain observed solute concentrations beyond 80 km. Mobilization and transport of solutes in the unsaturated zone by recharging precipitation is not a significant factor.

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Résumé Une simulation simple et bien contrainte de l’augmentation des solutés dans la direction de l’écoulement a été réalisée sur l’aquifère phréatique et libre de l’Est de l’émirat d’Abu Dhabi (émirats Arabes Unis). La simulation indique que l’augmentation observée de solutés, de forme exponentielle, est le produit de la combinaison du transport ascendant de solutés provenant des mudstones et des évaporites sous-jacents, et de l’évaporation des eaux souterraines. La recharge des eaux souterraines et les flux de vidange dans les aquifères régionaux libres des régions arides sont habituellement difficiles à estimer du fait du peu de contraintes agissant sur la perte ou le gain d’eau dans le système. La charge dissoute totale (TDS, en anglais) et les isotopes deutérium (δ²H) des eaux souterraines sont utilisés pour contraindre l’estimation des flux en direction de l’aquifère phréatique de l’Est de l’émirat d’Abu Dhabi. Le transport vertical ascendant des solutés à partir des mudstones et des évaporites fait parti des processus qui concentrent les solutés approximativement le long des 80 premiers kilomètres du trajet des écoulements simulés, mais une combinaison du transport ascendant des solutés et de l’évaporation est nécessaire pour expliquer les concentrations observées en soluté au delà des 80 km. La mobilisation et le transport des solutés par les précipitations efficaces dans la zone non saturée ne représentent pas des facteurs significatifs.

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Resumen Se utilizó una simulación simple y muy restringida, de incrementos de soluto en la dirección del flujo, en el acuífero libre poco profundo del Emirato oriental de Abu Dhabi, (Emiratos árabes Unidos). La simulación indica que el aumento exponencial observado en las concentraciones del soluto, resulta de una combinación de transporte ascendente de solutos desde las evaporitas y lodolitas subyacentes, y por pérdidas del agua subterránea por evaporación. Los flujos de recarga y descarga de agua subterránea, en los acuíferos libres regionales en regiones áridas, normalmente son difíciles estimar, porque hay algunas restricciones en el flujo de agua perdido o ganado por el sistema. Los sólidos disueltos totales (TDS) y los isótopos de deuterio (δ²H) en el agua subterránea, se usan para forzar los flujos estimados hacia el acuífero poco profundo del Emirato oriental de Abu Dhabi. El transporte ascendente vertical de solutos desde las lodolitas y evaporitas subyacentes, involucra los aumentos del soluto a lo largo de aproximadamente los primeros 80 Km. de la dirección de flujo simulada, pero es necesaria una combinación de transporte ascendente del soluto y la evaporación para explicar las concentraciones del soluto observadas más allá de 80 Km. La movilización y transporte de solutos en la zona no saturada, por recarga debida a precipitación, no es un factor significante.

     

Baily’s Beads Atlas in 2005 – 2008 Eclipses

In the annular or total eclipses of 3 October 2005, 29 March 2006, 22 September 2006, and 1 August 2008, observational campaigns were organized to record the phenomenon of Baily’s beads. These campaigns were internationally coordinated through the International Occultation Timing Association (IOTA) at both its American and European sections. From the stations in the northern and southern zones of grazing eclipse, the eclipses have been recorded on video. Afterward, as many beads as possible have been identified by analyzing the video data of each observing station. The atlas presented in this paper includes 598 data points, obtained by 23 observers operating at 28 different observing stations. The atlas lists the geographic positions of the observing stations and the observed time instants of disappearance or reappearance of beads, identified by an angle measured relative to the Moon’s axis of rotation. The atlas will serve as a basis for determining the solar diameter. Electronic Supplementary Material  The online version of this article () contains supplementary material, which is available to authorized users.     

Development of a tidal marsh in a New England river valley

A model for the geomorphic and vegetation development of a river valley tidal marsh in southern New England (Connecticut) is based on both the species composition of roots and rhizomes and on the mineralogic sediments preserved in peat. The maximum depth of salt marsh peat is 3.8 m and in the deepest areas this can overlie up to 1.9 m of fresh to brackish water peat. Based on a radiocarbon date of 3670±140 yr before the present (B.P.) for basal peat at a depth of 4.0 m, vertical accretion rates have averaged ca. 1.1 mm yr^?1. Salt marsh formation began in response to rising sea level 3800–4000 yr B.P., as brackish marshes, dominated by bulrush (Scirpus sp.), replaced freshwater wetlands along stream and river channels. Gradually salt marsh vegetation developed over submerging brackish marshes, adjacent uplands, and accreting tidal flats. By 3000 yr B.P. the lower estuary was tidal, with sufficient salinity for salt marsh to dominate most wetlands. Spikegrass (Distichlis spicata) was an important early colonizer in salt marsh formation and its role in marsh development has not been documented previously. Blackgrass (Juncus gerardi), currently a typical upper border species, appears in the peat record relatively recently, perhaps within the last few centuries. In contrast, reed (Phragmites australis) has been present for at least 3500 yr. The dominance of reed along the upper border today, however, appears to be a relatively recent phenomenon.     

The hydrochemistry of a semi-arid pan basin case study: Sua Pan,Makgadikgadi, Botswana

This study presents results on the fluid and salt chemistry for the Makgadikgadi, a substantial continental basin in the semi-arid Kalahari. The aims of the study are to improve understanding of the hydrology of such a system and to identify the sources of the solutes and the controls on their cycling within pans. Sampling took place against the backdrop of unusually severe flooding as well as significant anthropogenic extraction of subsurface brines. This paper examines in particular the relationship between the chemistry of soil leachates, fresh stream water, salty lake water, surface salts and subsurface brines at Sua Pan, Botswana with the aim of improving the understanding of the system’s hydrology. Occasionally during the short wet season (December–March) surface water enters the saline environment and precipitates mostly calcite and halite, as well as dolomite and traces of other salts associated with the desiccation of the lake. The hypersaline subsurface brine (up to TDS 190,000 mg/L) is homogenous with minor variations due to pumping by BotAsh mine (Botswana Ash (Pty) Ltd.), which extracts 2400 m³ of brine/h from a depth of 38 m. Notable is the decrease in TDS as the pumping rate increases which may be indicative of subsurface recharge by less saline water. Isotope chemistry for Sr (⁸⁷Sr/⁸⁶Sr average 0.722087) and S (δ³⁴S average 34.35) suggests subsurface brines have been subject to a lithological contribution of undetermined origin. Recharge of the subsurface brine from surface water including the Nata River appears to be negligible.     

Simulation of the effect of wind speedup in the formation of transverse dune fields

A computer simulation model for transverse‐dune‐field dynamics, corresponding to a uni‐directional wind regime, is developed. In a previous formulation, two distinct problems were found regarding the cross‐sectional dune shape, namely the erosion in the lee of dunes and the steepness of the windward slopes. The first problem is solved by introducing no erosion in shadow zones. The second issue is overcome by introducing a wind speedup (shear velocity increase) factor, which can be accounted for by adding a term to the original transport length, which is proportional to the surface height. By incorporating these features we are able to model dunes whose individual shape and collective patterns are similar to those observed in nature. Moreover we show how the introduction of a non‐linear shear‐velocity‐increase term leads to the reduction of dune height, and this may result in an equilibrium dune field configuration. This is thought to be because the non‐linear increase of the transport length makes the sand trapping efficiency lower than unity, even for higher dunes, so that the incoming and the outgoing sand flux are in balance. To fully describe the inter‐dune morphology more precise dynamics in the lee of the dune must be incorporated. Copyright © 2000 John Wiley & Sons, Ltd.     

Mineralogical and geochemical characterization of precipitates on stream receiving acid mine water, Korea

Seasonal variations of water chemistry occurred in acid mine drainage receiving mine and leachate water. Sulfate and metal concentrations were low in winter but high in spring and summer. Mine waters were highly acidic (up to pH 3.4) in nature with high concentrations of manganese, copper and zinc but high electrical conductivity and sulfate in leachate. The blue and brownish yellow precipitates were formed under different chemical environments of acid mine drainage. Brownish yellow (Munsell color 7.5YR 8/12), blue (Munsell color 2.5B 9/7) and light blue (Munsell color 2.5B 9/3) precipitates deposited on the stream bottom receiving acid mine water. The brownish yellow precipitates formed in the acid mine water, whereas the blue and light blue precipitates formed in the leachate water. The brownish yellow precipitates consisted mainly of ferrihydrite, whereas the blue and light blue precipitates consisted of glaucocerinite and/or woodwardite.     

Secondary‐volatiles linked metallic iron in eucrites: The dual‐origin metals of Camel Donga

The unique occurrence of abundant (~1 vol%) near‐pure‐Fe metal in the Camel Donga eucrite is more complicated than previously believed. In addition to that component of groundmass metal, scattered within the meteorite are discrete nodules of much higher kamacite abundance. We have studied the petrology and composition of two of these nodules in the form of samples we call CD2 and CD3. The nodules are ovoids 11 (CD2) to 15 (CD3) mm across, with metal, or inferred preweathering metal, abundances of 12–17 vol% (CD2 is unfortunately quite weathered). The CD3 nodule also includes at its center a 5 mm ovoid clumping (6 vol%) of F‐apatite. Both nodules are fine‐grained, so the high Fe metal and apatite contents are clearly not flukes of inadequate sampling. The metals within the nodules are distinctly Ni‐rich (0.3–0.6 wt%) compared to the pure‐Fe (Ni generally 0.01 wt%) groundmass metals. Bulk analyses of three pieces of the CD2 nodule show that trace siderophile elements Ir, Os, and Co are commensurately enriched; Au is enriched to a lesser degree. The siderophile evidence shows the nodules did not form by in situ reduction of pyroxene FeO. Moreover, the nodules do not show features such as silica‐phase enrichment or pyroxene with reduced FeO (as constrained by FeO/MgO and especially FeO/MnO) predicted by the in situ reduction model. The oxide minerals, even in groundmass samples well away from the nodules, also show little evidence of reduction. Although the nodule boundaries are generally sharp, groundmass‐metal Ni content is anti‐correlated with distance from the CD3 nodule. We infer that the nodules represent materials that originated within impactors into the Camel Donga portion of the eucrite crust, but probably were profoundly altered during later metamorphism/metasomatism. Origin of the pure‐Fe groundmass metal remains enigmatic. In situ reduction probably played an important role, and association in the same meteorite of the Fe‐nodules is probably significant. But the fluid during alteration was probably not (as previously modeled) purely S and O, of simple heat‐driven internal derivation. We conjecture a two‐stage metasomatism, as fluids passed through Camel Donga after impact heating of volatile‐rich chondritic masses (survivors of gentle accretionary impacts) within the nearby crust. First, reduction to form troilite may have been triggered by fluids rich in S₂ and CO (derived from the protonodules?), and then in a distinct later stage, fluids were (comparatively) H₂O‐rich, and thus reacted with troilite to form pure‐Fe metal along with H₂S and SO₂. The early eucrite crust was in places a dynamic fluid‐bearing environment that hosted complex chemical processes, including some that engendered significant diversity among metal+sulfide alterations.     

Evidence from Ar/Ar Ages of Individual Hornblende Grains for Varying Laurentide Sources of Iceberg Discharges 22,000 to 10,500 yr B.P.

The abundance and lithic content of ice rafted detritus in glacial North Atlantic sediment cores vary abruptly on millennial time scales that have been correlated to Dansgaard-Oeschger cycles in the Greenland ice cores. There is growing evidence that various ice sheet outlets contributed increased iceberg fluxes at multiple discrete intervals, and the relative timing of iceberg discharges from different sources is important for understanding interactions between oceans and ice sheets. We present a provenance study based on ⁴⁰Ar/³⁹Ar dates of individual hornblende grains from 20 samples taken at 600 to 700 yr spacing between 10,500 and 22,000 yr B.P., from Orphan Knoll core EW9303-GGC31. Heinrich layers are characterized by a dominant Paleoproterozoic hornblende provenance consistent with published studies. A change in provenance between Heinrich events H2 and H1 indicates contributions of iceberg calving from the Newfoundland and southern Labrador margins. Between H1 and the Younger Dryas interval, Paleoproterozoic ice rafted grains remained dominant. The dominance of Baffin Island (or Greenland?) sources to the ice rafted detritus is ascribed to the retreat of the southern Laurentide ice sheet at about the time of H1—a retreat that isolated Newfoundland and southern Labrador ice from the shelf-slope boundary.