Analysis of seawater for dissolved cadmium, copper and lead: An intercomparison of voltammetric and atomic absorption methods

An intercomparison study of voltammetric and atomic absorption spectrometric methods for determining cadmium, lead and copper in seawater samples was conducted. The voltammetric approach utilizes differential pulse anodic stripping voltammetry using a rotating, glassy carbon, mercury film electrode under conditions developed to minimize contamination sources and to enhance sensitivity for seawater matrices. The atomic absorption approach involves a concentration step using either an organic solvent extraction of metal dithiocarbamate chelates or a Chelex-100 column with detection by graphite furnace atomic absorption spectrometry. Similar and consistent results were obtained using both methods for the three trace metals studied on a wide range of natural seawater samples. Both methods are comparable in sensitivity for cadmium and copper, however the voltammetric method is better suited for the analysis of lead in seawater because of its enhanced sensitivity and low blank. An advantage of the voltammetric approach is its amenability towards real-time shipboard analysis.     

Bioerosion by chemosynthetic biological communities on Holocene submarine slide scars

Geomorphic, stratigraphic, and faunal observations of submarine slide scars that occur along the flanks of Monterey Canyon in 2.0–2.5 km water depths were made to identify the processes that continue to alter the surface of a submarine landslide scar after the initial slope failure. Deep-sea chemosynthetic biological communities and small caves are common on the sediment-free surfaces of the slide scars, especially along the headwall. The chemosynthetic organisms observed on slide scars in Monterey Canyon undergo a faunal succession based in part on their ability to maintain their access to the redox boundaries in the sediment on which they depend on as an energy source. By burrowing into the seafloor, these organisms are able to follow the retreating redox boundaries as geochemical re-equilibration occurs on the sole of the slide. As these organisms dig into the seafloor on the footwall, they often generate small caves and weaken the remaining seafloor. While chemosynthetic biological communities are typically used as indicators of fluid flow, these communities may be supported by methane and hydrogen sulfide that are diffusing out of the fresh seafloor exposed at the sole of the slide by the slope failure event. If so, these chemosynthetic biological communities may simply mark sites of recent seafloor exhumation, and are not reliable fluid seepage indicators.     

Seagrass landscape-scale changes in response to disturbance created by the dynamics of barrier-islands: A case study from Ria Formosa (Southern Portugal)

This study documents long-term changes of a Zostera noltii landscape induced by a natural cyclic event in a coastal lagoon. The barrier-islands forming this system are very dynamic with drifting movements controlling ecological patterns and processes occurring in this area. Changes in the areal extent of the Z. noltii meadows were assessed using historical aerial photographs from 1940, 1980, 1989, 1996 and 1998. Landscape indices such as total patch area (TA), mean patch size (MPS), number of patches (NP), mean shape coefficient of variation (CV) and landscape fractal dimension (D) were calculated for each year and related to an index of disturbance intensity. The spatial distribution of the Z. noltii meadows varied greatly during the studied period and changes observed were related to the disturbance created by the barrier-islands' spatial dynamics. After an artificial inlet relocation the Z. noltii area, number of patches, patch mean size and coefficient of variation decreased. The fractal dimension of the Z. noltii landscape increased by 50% showing that besides a decrease in total area, number of patches, and patch mean area, patch fragmentation was an important consequence of this anthropogenic disturbance.Seagrass natural distribution patterns changed in response to natural and human-induced activities. This study emphasizes the importance of the landscape approach and the historical perspective when studying seagrass changes and the importance of taking into consideration long-term changes in seagrass landscapes to avoid confusion between man-induced effects with natural cyclic events.     

Hotspots in ambient noise caused by ice-edge eddies in the Greenland and Barents Seas

Mesoscale eddies are frequently observed in the Greenland and Barents Seas' marginal ice zone (MIZ). The objective of this study was to investigate the hypothesis that acoustic hotspots along the ice-edge region are due to mesoscale eddy currents interacting with the broken-up ice floes in the MIZ. To test this hypothesis, ambient-noise case studies were carried out during the MIZEX 85-87 and SIZEX 89 field experiments. In each experiment, ice-edge eddies were localized visually from aircraft and by use of satellite remote-sensing data obtained in near real time. Sonobuoys were, thereafter, deployed by fix-wing aircraft and helicopters in selected eddy areas. Ambient-noise data, recorded over several hours by aircraft, were analyzed estimating averaged ambient-noise levels at four selected frequencies: 40, 100, 315, and 1000 Hz. The analysis showed high mean levels and large gradients in ambient noise near ice-edge eddies and during strong wind and wave forcing against the ice edge. The conclusion of this study is that mapping of the ice edge and localization of mesoscale ocean processes using remote sensing from space will provide important input to ambient-noise prediction in the MIZ.     

Application of wavelet transforms to the decoupling of free-roll decay data

This study presents the results of the decoupling of a free-roll decay test by wavelet transforms. A free-roll decay test was performed to determine the coefficients of damping terms in equations of motion. No motion of the model was restricted during the experiment. A slight yaw motion was found while the model was in the free-roll decay motion. It was necessary to extract a pure roll motion from the experimental data. Wavelet transforms were applied to the signals to extract the pure roll motion. The results were compared to those found through the Fourier transform. Discrete wavelet transforms were able to efficiently decouple the test signals, while the continuous wavelet transform and the Fourier transform could not.     

Acute toxicity of bromochlorinated seawater to selected estuarine species with a comparison to chlorinated seawater toxicity

The acute toxicity of bromochlorinated estuarine water (ca. 20%) was determined for several estuarine organisms. The most sensitive species were oysters (Crassostrea virginica, larvae and juveniles) and copepods (Acartia tonsa) with 48-h LC₅₀'s of 0·10 to 0·21 mg BrCl/litre. Palaemonetes pugio was most tolerant with a 96-h LC₅₀ of 0·70 mg BrCl/litre. The fish species tested (Menidia menidia, Brevoortia tyrannus and Leiostomus xanthurus) all had a 96-h LC₅₀ of 0·21–0·23 mg BrCl/litre.The BrCl toxicity data are compared with Cl₂ toxicity data for the same species. When the LC₅₀'s are expressed as equivalents per litre, BrCl is found to be two to four times less toxic than Cl₂. The ranking of species in terms of sensitivity is the same for both disinfectants.Some data are provided concerning the decay rates of BrCl and Cl₂ in estuarine water. BrCl was found to decay more rapidly than Cl₂ at higher ammonia levels (0·25 mg NH₄-N/litre). The question of chemical speciation is discussed with particular reference to the differential toxicities.     

积极推进海域使用管理两项制度的落实

海域使用管理两项制度的推进,是国家海洋局2000年重点工作任务之一。在局党组的高度关注下,在海域管理司领导和全司同志的共同努力下,在财政部综合司的大力支持下,2000年海域使用管理工作成效显著,管理力度明显加大。 1 稳打稳扎,逐步贯彻落实海域使用管理的两项制度     

Free spanning analysis of offshore pipelines

A rigorous procedure was established on the free span analysis of offshore pipelines. The closed form solutions of the beam–column equation, considering tension and compressive force, were derived for the various possible boundary conditions. The solutions can be used to find the natural frequencies of the free spans using the energy balance concept. The results can be applied to improve the current design codes. The improved procedure will yield more realistic calculations of the allowable free span lengths of offshore pipelines. Some calculations are included to present the sensitivity of the axial forces on the allowable free spanning lengths.     

温度、光强和盐度对鹧鸽菜幼体生长发育的影响

从野外采集鹤鸪菜Ｃａｌｏｇｌｏｓｓａｌｅｐｒｉｅｕｒｉｉ（Ｍｏｎｔ．）Ｊ．Ａｇ．幼体，在室内控制条件下，以温、盐、光等不同条件进行模拟培养试验。所获得的数据经生物统计检验表明：鹧鸪菜幼体生长最适水温为２３℃；光照强度为４０００ｌｘ；海水盐度为１８。此结果与我们多年来在汕头港内观察鹧鸪菜的生长及其季节变化相似。     

南海中北部表层沉积物的矿物沉积

本文研究了南海中北部500多个样品的矿物学。认为,本区表层沉积物中矿物种类繁多,分布较为普遍,碎屑矿物(含火山物质)、粘土矿物、自生矿物常有出现。以前者为最显著(共60多种,其中重矿物50多种,轻矿物近10种),主要分布于陆架区及深海盆;粘土矿物次之,多分布于陆坡～深海盆;自生矿物较少,陆架～深海盆均有分布。文中根据矿物沉积特征和环境差异,把它划分为6个矿物区。