Structure and origin of terpenoid hydrocarbons in some German coals

Hydrocarbon extracts of coal samples from major coal fields in West Germany have been investigated by gas chromatography-mass spectrometry (GC/MS). The samples are of Carboniferous and Tertiary age and derive from limnic and paralic environments, the Saar District, the Ruhr Area and the Lower Rhine Basin.Differences in facies, maturity and age reflected in the distribution patterns of the extracted alkylcyclohexanes. An unexpected occurrence of cyclic diterpenoid hydrocarbons in some samples of Carboniferous age has been found. The tetracyclic compounds mainly show phyllocladane type structures and can serve as source indicators.Hydrocarbons obtained from chemical degradation of the macromolecular material of the samples also revealed phyllocladane-type compounds which are normally associated to resins of modern and extinct familes of conifers. Origin and structural variations of this class of hydrocarbons are discussed in terms of maturity and palaeobotanical implications.     

The accessibility of nodes in the Belgian road network

This paper presents an analysis of the accessibility of nodes in the Belgian road network. The intersection of roads are considered as the nodes and their connecting roads as the edges of a network. By means of the Dijkstra algorithm accessibility values are computed for each node by summing shortest travel times to a reference system of 158 nodes spread evenly over the Belgian territory. A comparison of the measured actual accessibility with that determined from an optimal situation provides an indication of the quality of directness of the Belgian road system. Accessibility and directness are shown cartographically. An isochronal map illustrates the access to Brussels.     

Factors influencing the salinity regime of Lake Pontchartrain,Lousiana, a shallow coastal lagoon: Analysis of a long-term data set

Lake Pontchartrain., Louisiana is a 1,630 km² shallow brackish lagoon with a mean salinity from 1.2‰ in the west to 5.4‰ in the east., The construction of a 120 km long deep-water connection to the Gulf of Mexico in 1963, was expected to cause a 5‰ increase in lagoon salinity. However, the actual increase was everywhere in the lagoon less than 2‰ Analysis of 31 years of daily salinity and discharge records indicates that discharge is the most important factor controlling salinity variations in Lake Pontchartrain., Seventy-four percent of low-frequency salinity variations are explained by freshwater discharge and the completion of the deep-water canal. Lake Pont.-chartrain experiences annual variations of salinity as high as 8‰ This salinity signal has remained constant since the beginning of the salinity records in 1946. It appears that the deep-water canal is not responsible for observed die-back of freshwater swamps and retreat of lagoon shorelines.     

The Application of Telemetry to Large-Scale Horizontal Anisotropic Permeability Determinations by Surface Tiltmeter Survey

An advanced two-way radio link (transceiver units) and data logging system have provided a powerful means of real-time series data collection and analysis. The application of this telemetry system to surface tiltmeter surveys provides significant cost savings for testing and analysis of deep, large-scale horizontal anisotropic permeability and heterogeneity determinations.
The determination of horizontal anisotropic properties requires one pumping well and eight to 10 tiltmeter monitoring stations. The validity of the depth of the test may reach 4,000 feet below land surface. With the addition of one partially penetrating observation well, the entire three-dimensional anisotropic permeability can be determined. With the addition of a fully penetrating well, the storage coefficient can be determined as well as leakage property (including vertical permeability of the confining layers). An example test case was analyzed for horizontal anisotropic permeability with remarkable success despite relatively unfavorable detection conditions.
A thorough understanding of the geology overlying the aquifer system must be made in order to assess the applicability of the surface tiltmeter survey to large-scale horizontal anisotropic permeability determinations.     

Lower Cretaceous turbiditic sediments from the Rif chain (Northern Marocco) — palynology,stratigraphy and palaeogeographic setting

The paper describes the palynology, stratigraphy, sedimentology and palaeogeographic setting of Lower Cretaceous turbiditic and terrigenous deep-sea sediments at the Tethyan margins of Africa and Alboran (External Domain of the Rif, and Flysch Nappes). During the Early Cretaceous terrigenous turbiditic deep-water sedimentation characterizes two different palaeogeographic domains in the southern part of the western Tethys:

In the northern area of the External Domain (Ketama Unit of the Rif) alternating turbiditic arenites and pelites are interpreted as sediments of a distal part of a fan system on the Tethyan margin of Africa. The main sources for the terrigenous material were situated in Central and Western Algeria; only little sand transited through the Prerif and the Mesorif zones of Morocco. The terrigenous sedimentation began in the Hauterivian, but the main turbiditic cycles are of Aptian to Lower and Middle Albian age.

The Flysch Domain probably was situated far to the Northeast with respect to the Rif basin, at the western and southern margins of the Alboran microplate. Relatively proximal turbidites form most of the Tisirène Nappe, whereas more distal turbidites constitute the series of the Melloussa and the Chouamat Nappes. The existence of two different source areas is demonstrated, one to the NE and the other to the NW of the depositional area. The turbidites probably were deposited on a E-W oriented fan system which progradated into a longitudinal trench-like trough. In the Central Rif area, the Tisirène Flysch is of Valanginian to Albian (pre-Vraconian) age. In the Western Rif and in the Melloussa and Chouamat Nappes of the whole area no sediments older than Aptian have been found.

The stratigraphy of the investigated series is based on a new tentative palynostratigraphic zonation, using pollen, spores and dinoflagellate cysts. Rich and well preserved assemblages have been found in the Western Rif only, whereas the samples of the Tisirène Nappe and the Chouamat Nappe in the Central and Eastern Rif have been affected by some thermal alteration. Black and mostly opaque palynomorphs from the Ketama Unit reflect the strong thermal influence in the External Domain of the Central and Eastern Rif.     

Long-term erosion on granitic roadcuts based on exposed tree roots

Exposed roots were used to estimate soil and bedrock erosion on the cut slopes of a 45-year-old road constructed in granitic soils of the Idaho Batholith. The original roadcut surface was defined by projecting a straight line from the toe of the cut past the end of the exposed root to the intersection of a straight line projected along the surface of the hillslope. A cross-sectioning technique was then used to determine erosion to the present roadcut surface. A total of 41 exposed root sites were used to estimate erosion on a 1350 m-long section of road. Average erosion was 1·0 and 1·1 cm/year for soil and bedrock respectively. Buttressing by tree roots caused lower erosion rates for soil as compared to bedrock. Both soil and bedrock erosion rates showed statistically significant correlations with the gradients of the original cut slope. The bedrock erosion data provide a reasonable estimate of the disintegration rate of exposed granitic bedrock exhibiting the weathering and fracturing properties common to this area. The road is located in a study watershed where long-term sediment yield data are available. Sediment data from adjacent study watersheds with no roads were compared to sediment data from the roaded watershed to estimate the long-term increase in sediment yield caused by the road. The increase amounts to about 2·4 m³/year. This figure, compared to the average annual on-site road erosion, provides an erosion to sediment delivery ratio of less than 10 per cent. Based on study results, road construction and maintenance practices are suggested for helping reduce roadcut erosion.     

On the relationship of thunderstorm ice hydrometeor characteristics and total lightning measurements

Satellite-borne and ground-based devices for the detection of lightning offer the opportunity to explore relationships–on all significant scales up to global–between lightning frequency, f, and other thundercloud parameters. Calculations predict that f is proportional to the product of the downflux p of solid precipitation and the upward mass flux, I, of ice crystals. This prediction has received support from limited computational studies. The physical reasons for such a relationship are explained in terms of the paramount role of ice in the electrification of thunderstorms. Herein, this prediction is subjected to further, preliminary examination through analysis of lightning and dual-polarimetric radar data collected during the STERAO experiment conducted in Northern Colorado during the summer of 1996. The analysis has yielded some highly provisional support for this flux hypothesis. Computed trends of radar derived hydrometeor fractions of solid precipitation and small ice show correlation to the total lightning frequency and raise the possibility of determining values of p and/or I from lightning measurements.It is shown that the extent to which the observed correlations between f and both solid precipitation and small ice trends are or are not strong can provide an indication as to whether the lightning activity is limited by the available concentrations of precipitating or non-precipitating ice in the upper regions of the charging zone of the thundercloud, where most of the charge transfer occurs. It is demonstrated that the most accurate determinations of precipitation rate p from measurements of lighting frequency f are likely to be for conditions where the field-growth is limited by the availability of graupel pellets. It is shown that the simultaneous time variations of f and solid precipitation trends of the type obtained in the STERAO experiment could enable us to determine the nature of the dominant glaciation process operative in the thunderclouds studied.     

Structural evolution of the contact between two Penninic nappes (Zermatt-Saas zone and Combin zone,Western Alps) and implications for the exhumation mechanism and palaeogeography

The boundary zone between two Penninic nappes, the eclogite-facies to ultrahigh-pressure Zermatt-Saas zone in the footwall and the blueschist-facies Combin zone in the hanging wall, has been interpreted previously as a major normal fault reflecting synorogenic crustal extension. Quartz textures of mylonites from this fault were measured using neutron diffraction. Together with structural field observations, the data allow a refined reconstruction of the kinematic evolution of the Pennine nappes. The main results are: (1) the contact is not a normal fault but a major thrust towards northwest which was only later overprinted by southeast-directed normal faulting; (2) exhumation of the footwall rocks did not occur during crustal extension but during crustal shortening; (3) the Sesia-Dent Blanche nappe system originated from a continental fragment (Cervinia) in the Alpine Tethys ocean, and the Combin zone ophiolites from the ocean basin southeast of Cervinia; (4) out-of-sequence thrusting played a major role in the tectonic evolution of the Penninic nappes. An erratum to this article can be found at     

Late Quaternary paleoenvironments of an ephemeral wetland in North Dakota,USA: relative interactions of ground-water hydrology and climate change

This study of fossils (pollen, plant macrofossils, stomata and fish) and sediments (lithostratigraphy and geochemistry) from the Wendel site in North Dakota, USA, emphasizes the importance of considering ground-water hydrology when deciphering paleoclimate signals from lakes in postglacial landscapes. The Wendel site was a paleolake from about 11,500 ¹⁴C yr BP to 11,100 ¹⁴C yr BP. Afterwards, the lake-level lowered until it became a prairie marsh by 9,300 ¹⁴C yr BP and finally, at 8,500 ¹⁴C yr BP, an ephemeral wetland as it is today. Meanwhile, the vegetation changed from a white spruce parkland (11,500 to 10,500 ¹⁴C yr BP) to deciduous parkland, followed by grassland at 9,300 ¹⁴C yr BP. The pattern and timing of these aquatic and terrestrial changes are similar to coeval kettle lake records from adjacent uplands, providing a regional aridity signal. However, two local sources of ground water were identified from the fossil and geochemical data, which mediated atmospheric inputs to the Wendel basin. First, the paleolake received water from the melting of stagnant ice buried under local till for about 900 years after glacier recession. Later, Holocene droughts probably caused the lower-elevation Wendel site to capture the ground water of up-gradient lakes.