Co-diagenesis of iron and phosphorus in hydrothermal sediments from the southern East Pacific Rise: Implications for the evaluation of paleoseawater phosphate concentrations

We present a detailed study of the co-diagenesis of Fe and P in hydrothermal plume fallout sediments from ∼19°S on the southern East Pacific Rise. Three distal sediment cores from 340-1130 km from the ridge crest, collected during DSDP Leg 92, were analysed for solid phase Fe and P associations using sequential chemical extraction techniques. The sediments at all sites are enriched in hydrothermal Fe (oxyhydr)oxides, but during diagenesis a large proportion of the primary ferrihydrite precipitates are transformed to the more stable mineral form of goethite and to a lesser extent to clay minerals, resulting in the release to solution of scavenged P. However, a significant proportion of this P is retained within the sediment, by incorporation into secondary goethite, by precipitation as authigenic apatite, and by readsorption to Fe (oxyhydr)oxides. Molar P/Fe ratios for these sediments are significantly lower than those measured in plume particles from more northern localities along the southern East Pacific Rise, and show a distinct downcore decrease to a depth of ∼12 m. Molar P/Fe ratios are then relatively constant to a depth of ∼35 m. The Fe and P speciation data indicate that diagenetic modification of the sediments is largely complete by a depth of 2.5 m, and thus depth trends in molar P/Fe ratios can not solely be explained by losses of P from the sediment by diffusion to the overlying water column during early diagenesis. Instead, these sediments are likely recording changes in dissolved P concentrations off the SEPR, possibly as a result of redistribution of nutrients in response to changes in oceanic circulation over the last 10 million years. Furthermore, the relatively low molar P/Fe ratios observed throughout these sediments are not necessarily solely due to losses of scavenged P by diffusion to the overlying water column during diagenesis, but may also reflect post-depositional oxidation of pyrite originating from the volatile-rich vents of the southern East Pacific Rise. This study suggests that the molar P/Fe ratio of oxic Fe-rich sediments may serve as a proxy of relative changes in paleoseawater phosphate concentrations, particularly if Fe sulfide minerals are not an important component during transport and deposition.     

Possible forerunners of droughts in agricultural areas of Russia

Considered is the regional index of anticyclonic circulation IpH taking account of the percentage of the area occupied by the significant positive anomalies of the geopotential at the level of 500 hPa for the main agricultural areas of Russia. Analyzed are the variations of the index in the 20th and 21st centuries using the NCEP/NCAR reanalysis data and the outputs of model experiments with the ECHAM5 climate model (Germany). Discussed is the possibility of revealing the drought forerunners using the combination of indices of anticyclonic circulation, quasi-biennial cyclicity in the wintertime equatorial stratosphere, and teleconnections.     

Application of the Genetic Algorithm to the Problem of Reconstruction of Missing Data

We study the problem of reconstruction (interpolation and extrapolation) of the vertical profiles of hydrochemical and hydrobiological elements according to incomplete sets of data with simultaneous filtration of short-period components based on expansions in empirical orthogonal functions. The genetic algorithm is used to compute the coefficients of expansion of profiles with missing data. We present the results of processing the data arrays on oxygen, chlorophyll A, and biogenic elements collected in the Black Sea in 1982–1993. The mean error of reconstruction of the profiles enables us to conclude that the proposed method has considerable advantages over the conventional approaches.     

An ephemeral turbidity maximum generated by resuspension of organic-rich matter in a macrotidal estuary, S.W. Wales

An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom). A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates, a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I⁻¹ by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I⁻¹, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R³ where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles in the ETM have effective densities (120–160 kg m⁻³) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal sand flats.     

Mean Profiles of Moisture Fluxes in Snow-Filled Boundary Layers

Profiles of moisture fluxes have been examined for convective boundary layers containing clouds and snow, using data derived from aircraft measurements taken on four dates during the 1983/1984 University of Chicago lake-effect snow project. Flux profiles were derived from vertical stacks of aircraft cross-wind flight legs taken at various heights over Lake Michigan near the downwind shore. It was found that, if ice processes are taken into account, profiles of potential temperature and water content were very similar to those presented in past studies of convective boundary layers strongly heated from below. Profiles of total water content and equivalent potential temperature adjusted for ice were nearly invariant with height, except very near the top of the boundary layer, suggesting that internal boundary-layer mixing processes were rapid relative to the rates at which heat and vapour were transported into the boundary layer through entrainment and surface fluxes. Ice was found to play a significant, measurable role in boundary-layer moisture fluxes. It was estimated that 40 to 57% of the upward vapour flux was returned to the surface in the form of snow, converting about 45 to 64% of the surface latent heat flux into sensible heat in the snow-producing process. Assuming advective fluxes are relatively small (thought to be appropriate after the first few tens of km over the lake as suggested by past studies), the boundary layer was found to warm at a rate faster than could be explained by surface heat fluxes and latent heat releases alone, the remainder of the heating presumably coming from radiational processes and entrainment. Discussions of moisture phase change processes throughout the boundary layer and estimates of errors of these flux measurements are presented.     

ON THE DETERMINATION OF THE ROUGHNESS COEFFICIENT IN NATURAL AND ARTIFICIAL WATERWAYS

SYNOPSIS

It has always been a problem for the hydraulic engineer to obtain reasonable values for the roughness in a waterway. The writer feels that the idea put forward in this essay could help the parcticing engineer to obtain a roughness value without complicated procedure.     

A new technique to determine geoid and orthometric heights from satellite positioning and geopotential numbers

This paper takes advantage of space-technique-derived positions on the Earth’s surface and the known normal gravity field to determine the height anomaly from geopotential numbers. A new method is also presented to downward-continue the height anomaly to the geoid height. The orthometric height is determined as the difference between the geodetic (ellipsoidal) height derived by space-geodetic techniques and the geoid height. It is shown that, due to the very high correlation between the geodetic height and the computed geoid height, the error of the orthometric height determined by this method is usually much smaller than that provided by standard GPS/levelling. Also included is a practical formula to correct the Helmert orthometric height by adding two correction terms: a topographic roughness term and a correction term for lateral topographic mass–density variations.