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961.
Galina P. Bulanova Michael J. Walter Chris B. Smith Simon C. Kohn Lora S. Armstrong Jon Blundy Luiz Gobbo 《Contributions to Mineralogy and Petrology》2010,160(4):489-510
We report on a suite of diamonds from the Cretaceous Collier 4 kimberlite pipe, Juina, Brazil, that are predominantly nitrogen-free
type II crystals showing complex internal growth structures. Syngenetic mineral inclusions comprise calcium- and titanium-rich
phases with perovskite stoichiometry, Ca-rich majoritic-garnet, clinopyroxene, olivine, TAPP phase, minerals with stoichiometries
of CAS and K-hollandite phases, SiO2, FeO, native iron, low-Ni sulfides, and Ca–Mg-carbonate. We divide the diamonds into three groups on the basis of the carbon
isotope compositions (δ13C) of diamond core zones. Group 1 diamonds have heavy, mantle-like δ13C (−5 to −10‰) with mineral inclusions indicating a transition zone origin from mafic protoliths. Group 2 diamonds have intermediate
δ13C (−12 to −15‰), with inclusion compositions indicating crystallization from near-primary and differentiated carbonated melts
derived from oceanic crust in the deep upper mantle or transition zone. A 206Pb/238U age of 101 ± 7 Ma on a CaTiSi-perovskite inclusion (Group 2) is close to the kimberlite emplacement time (93.1 ± 1.5 Ma).
Group 3 diamonds have extremely light δ13C (−25‰), and host inclusions have compositions akin to high-pressure–temperature phases expected to be stable in pelagic
sediments subducted to transition zone depths. Collectively, the Collier 4 diamonds and their inclusions indicate multi-stage,
polybaric growth histories in dynamically changing chemical environments. The young inclusion age, the ubiquitous chemical
and isotopic characteristics indicative of subducted materials, and the regional tectonic history, suggest a model in which
generation of sublithospheric diamonds and their inclusions, and the proto-kimberlite magmas, are related genetically, temporally
and geographically to the interaction of subducted lithosphere and a Cretaceous plume. 相似文献
962.
Vincent Sastre Jean-Luc Loizeau Jens Greinert Lieven Naudts Philippe Arpagaus Flavio Anselmetti Walter Wildi 《Swiss Journal of Geoscience》2010,103(1):33-42
The current topographic maps of the Rhone Delta—and of Lake Geneva in general—are mainly based on hydrographic data that were
acquired during the time of F.-A. Forel at the end of the nineteenth century. In this paper we present results of a new bathymetric
survey, based on single- and multi-beam echosounder data. The new data, presented as a digital terrain model, show a well-structured
lake bottom morphology, reflecting depositional and erosional processes that shape the lake floor. As a major geomorphologic
element, the sub-aquatic Rhone Delta extends from the coastal platform to the depositional fans of the central plain of the
lake at 310 m depth. 9 canyons cut the platform edge of the delta. These are sinuous (“meandering”) channels formed by erosional
and depositional processes, as indicated by the steep erosional canyon walls and the depositional levees on the canyon shoulders.
Ripples or dune-like morphologies wrinkle the canyon bottoms and some slope areas. Subaquatic mass movements are apparently
missing on the delta and are of minor importance on the lateral lake slopes. Morphologies of the underlying bedrock and small
local river deltas are located along the lateral slopes of Lake Geneva. Based on historical maps, the recent history of the
Rhone River connection to the sub-aquatic delta and the canyons is reconstructed. The transition from three to two river branches
dates to 1830–1840, when the river branch to the Le Bouveret lake bay was cut. The transition from two to one river branch
corresponds to the achievement of the correction and dam construction work on the modern Rhone River channel between 1870
and 1880. 相似文献
963.
Julien Nikiema Mario Schirmer Walter Gläßer Ronald Krieg 《Environmental Earth Sciences》2010,61(1):11-26
About 24 samples from hand-dug wells and boreholes were used to characterize concentrations of the main inorganic ions in
a laterite environment under semi-arid climatic conditions in Tikaré, northern Burkina Faso. It was found that the most represented
groundwater anion in groundwater was HCO3
− with average levels of 49.1 mg/L in the dry season and 33.5 mg/L in the rainy season. The most represented cation was Ca2+ with mean concentrations of 13.7 and 9.5 mg/L, respectively. The main processes, which influence the concentrations of these
ions, are evaporation (dry season), local enrichment of recharge water in some elements, ion exchange and fixation by clay
minerals (in case of K+). The best correlations were found between Ca2+ and Mg2+ (r = 0.95), Cl− and Na+ (r = 0.95), HCO3
− and Mg2+ (r = 0.89), HCO3
− and Ca2+ (r = 0.89), and between HCO3
− and Na+ (r = 0.80). In general, the quality of the groundwater from the different wells sampled for this study was good enough to serve
as drinking water. However, there were situations where the quality of water was polluted because of anthropogenic contaminants
(mainly NO3
−, K+, Cl−) from septic tanks and manure pits located in the vicinity of some sampled wells. In addition, application of fertilizers
also represents a potential anthropogenic contamination source with regard to SO4
2−, Ca2+, K+, Na+, and Mg2+. Considering the high concentrations of SO4
2−, Mg2+, Na+ and Ca2+ found in one borehole, the deeper, fractured aquifers were also likely to be enriched in these elements. In contrast, the
shallow aquifers are likely to be contaminated with Cl−, NO3
− and K+. Cl− and K+ seem to be locally present in recharge water as shown by their relative higher mean concentrations in the rainy season samples. 相似文献
964.
A.?R.?ThomsonEmail author S.?C.?Kohn G.?P.?Bulanova C.?B.?Smith D.?Araujo EIMF M.?J.?Walter 《Contributions to Mineralogy and Petrology》2014,168(6):1081
Forty-one diamonds sourced from the Juina-5 kimberlite pipe in Southern Brazil, which contain optically identifiable inclusions, have been studied using an integrated approach. The diamonds contain <20 ppm nitrogen (N) that is fully aggregated as B centres. Internal structures in several diamonds revealed using cathodoluminescence (CL) are unlike those normally observed in lithospheric samples. The majority of the diamonds are composed of isotopically light carbon, and the collection has a unimodal distribution heavily skewed towards δ13C ~ ?25 ‰. Individual diamonds can display large carbon isotope heterogeneity of up to ~15 ‰ and predominantly have isotopically lighter cores displaying blue CL, and heavier rims with green CL. The light carbon isotopic compositions are interpreted as evidence of diamond growth from abiotic organic carbon added to the oceanic crust during hydrothermal alteration. The bulk isotopic composition of the oceanic crust, carbonates plus organics, is equal to the composition of mantle carbon (?5 ‰), and we suggest that recycling/mixing of subducted material will replenish this reservoir over geological time. Several exposed, syngenetic inclusions have bulk compositions consistent with former eclogitic magnesium silicate perovskite, calcium silicate perovskite and NAL or CF phases that have re-equilibrated during their exhumation to the surface. There are multiple occurrences of majoritic garnet with pyroxene exsolution, coesite with and without kyanite exsolution, clinopyroxene, Fe or Fe-carbide and sulphide minerals alongside single occurrences of olivine and ferropericlase. As a group, the inclusions have eclogitic affinity and provide evidence for diamond formation at pressures extending to Earth’s deep transition zone and possibly the lower mantle. It is observed that the major element composition of inclusions and isotopic compositions of host Juina-5 diamonds are not correlated. The diamond and inclusion compositions are intimately related to subducted material and record a polybaric growth history across a depth interval stretching from the lower mantle to the base of the lithosphere. It is suggested that the interaction of slab-derived melts and mantle material combined with subsequent upward transport in channelised networks or a buoyant diapir explains the formation of Juina-5 diamonds. We conclude that these samples, despite originating at great mantle depths, do not provide direct information about the ambient mantle, instead, providing a snapshot of the Earth’s deep carbon cycle. 相似文献
965.
地震层析成像研究清晰给出了地球深部俯冲板片的大尺度形态,但与俯冲过程相关的地幔流动特征仍不明确.在俯冲地幔楔系统中,前人观测到了与海沟平行和垂直的快波偏振方向.本文研究了西北太平洋俯冲板片在地幔过渡带中停滞形成的"大地幔楔"中的各向异性特征.对具有长期稳定观测数据的MDJ台站SKS震相和区域深源地震的直达S波震相进行了... 相似文献
966.
K. Walter 《Astronomische Nachrichten》1968,291(3):89-95
For this typical Algol system with the period 5.24 days, complete light curves in two colours have been derived from 160 photoelectric measurements in B and 173 in V. The primary minimum has been found to be total and asymmetric. To get a satisfactory photometric solution it was necessary to allow for the dissimilarity of the components. For the coefficients of limbdarkening of the Ao-component the values x = 0.35 · 0.11 (B) and 0.44 · 0.10 (V) have been deduced. 相似文献
967.
Geochemistry of soil, soil water, and soil gas was characterized in representative soil profiles of three Michigan watersheds. Because of differences in source regions, parent materials in the Upper Peninsula of Michigan (the Tahquamenon watershed) contain only silicates, while those in the Lower Peninsula (the Cheboygan and the Huron watersheds) have significant mixtures of silicate and carbonate minerals. These differences in soil mineralogy and climate conditions permit us to examine controls on carbonate and silicate mineral weathering rates and to better define the importance of silicate versus carbonate dissolution in the early stage of soil-water cation acquisition.Soil waters of the Tahquamenon watershed are the most dilute; solutes reflect amphibole and plagioclase dissolution along with significant contributions from atmospheric precipitation sources. Soil waters in the Cheboygan and the Huron watersheds begin their evolution as relatively dilute solutions dominated by silicate weathering in shallow carbonate-free soil horizons. Here, silicate dissolution is rapid and reaction rates dominantly are controlled by mineral abundances. In the deeper soil horizons, silicate dissolution slows down and soil-water chemistry is dominated by calcite and dolomite weathering, where solutions reach equilibrium with carbonate minerals within the soil profile. Thus, carbonate weathering intensities are dominantly controlled by annual precipitation, temperature and soil pCO2. Results of a conceptual model support these field observations, implying that dolomite and calcite are dissolving at a similar rate, and further dissolution of more soluble dolomite after calcite equilibrium produces higher dissolved inorganic carbon concentrations and a Mg2+/Ca2+ ratio of 0.4.Mass balance calculations show that overall, silicate minerals and atmospheric inputs generally contribute <10% of Ca2+ and Mg2+ in natural waters. Dolomite dissolution appears to be a major process, rivaling calcite dissolution as a control on divalent cation and inorganic carbon contents of soil waters. Furthermore, the fraction of Mg2+ derived from silicate mineral weathering is much smaller than most of the values previously estimated from riverine chemistry. 相似文献