Central Mediterranean tephrochronology between 313 and 366 ka: New insights from the Fucino palaeolake sediment succession

Thirty-two tephra layers were identified in the time-interval 313–366 ka (Marine Isotope Stages 9–10) of the Quaternary lacustrine succession of the Fucino Basin, central Italy. Twenty-seven of these tephra layers yielded suitable geochemical material to explore their volcanic origins. Investigations also included the acquisition of geochemical data of some relevant, chronologically compatible proximal units from Italian volcanoes. The record contains tephra from some well-known eruptions and eruptive sequences of Roman and Roccamonfina volcanoes, such as the Magliano Romano Plinian Fall, the Orvieto–Bagnoregio Ignimbrite, the Lower White Trachytic Tuff and the Brown Leucitic Tuff. In addition, the record documents eruptions currently undescribed in proximal (i.e. near-vent) sections, suggesting a more complex history of the major eruptions of the Colli Albani, Sabatini, Vulsini and Roccamonfina volcanoes between 313 and 366 ka. Six of the investigated tephra layers were directly dated by single-crystal-fusion ⁴⁰Ar/³⁹Ar dating, providing the basis for a Bayesian age–depth model and a reassessment of the chronologies for both already known and dated eruptive units and for so far undated eruptions. The results provide a significant contribution for improving knowledge on the peri-Tyrrhenian explosive activity as well as for extending the Mediterranean tephrostratigraphical framework, which was previously based on limited proximal and distal archives for that time interval.     

Hydrogeochemical exploration for barite, Ouachita Mountains, U.S.A.

Approximately 100 springs were sampled as part of a general geochemical survey in a 130 by 140 km multi-mineralized area of the Ouachita Mountains. The study area was subdivided into Area I and Area II based on differences in lithology and mineralization. Area I is composed primarily of the Paleozoic Stanley Shale and the Arkansas Novaculite Formation, and has considerable manganese (often present as psilomelane) and barite mineralization. The barite occurs primarily as replacement deposits in shale in Area I. Area II is composed of Paleozoic and Cretaceous sedimentary rocks, and Quaternary alluvium. Mercury, antimony, strontium and barite mineralization is present. The barite mineralization occurs as cement in the Cretaceous sandstone and gravel in this area.The widely prevalent barite cement in Area II is reflected by higher median and upper range values of barium concentration and also higher median and threshold % BaSO₄ saturation values. The presence of barite as cement in the sediments of Area II tends to mask the detection of the barite deposits in this area. Approximately 83% of the sites within 1.7 km of known barite mineralization in Area I were characterized by anomalous barium concentration, and 67% within 3.4 km. Anomalous % BaSO₄ saturation values and Ba/Sr ratios produced success rates generally similar to those of anomalous barium concentrations. Anomalous strontium concentrations did not prove effective in detecting barite mineralization.     

Formation of kyanite–quartz veins of the Alpe Sponda,Central Alps,Switzerland: implications for Al transport during regional metamorphism

In this study, we have investigated the formation of quartz–kyanite veins of the Alpe Sponda, Central Alps, Switzerland. We have integrated field observations, fluid inclusion and stable isotope data and combined this with numerical geochemical modeling to constrain the chemical processes of aluminum transport and deposition. The estimated P–T conditions of the quartz–kyanite veins, based on conventional geothermometry (garnet–biotite, white mica solvus and quartz–kyanite oxygen isotope thermometry) and fluid inclusion data, are 550 ± 30°C at 5.0 ± 0.5 kbar. Geochemical modeling involved construction of aqueous species predominance diagrams, calculation of kyanite and quartz solubility, and reaction–path simulations. The results of the modeling demonstrate that (1) for the given chemical composition of the vein-forming fluids mixed Al–Si aqueous species are dominant in transporting Al, and that (2) fluid cooling along a small temperature gradient coupled with a pH decrease is able to explain the precipitation of the quartz–kyanite assemblages in the proportions that are observed in the Alpe Sponda veins. We conclude that sufficient amounts of Al can be transported in typical medium- to high-grade regional metamorphic fluids and that immobile behavior of Al is not very likely in advection–dominanted fluid–rock systems in the upper and middle crust.     

Die geologische Vereinigung im „Deutschen Ausschuss“

Ohne Zusammenfassung     

The filtering effect of orbit correction on geopotential errors

Summary The geophysical interpretation of satellite tracking residuals generally ignores the filtering effect of initial orbit correction on the true errors of the model. While the filtered information is usually regarded as lost, knowing the spectral characteristics of the filter is a great aid in the detailed interpretation of residuals, especially of global data sets. In this regard, we derive the filter characteristics (admittances) of orbit correction in the presence of geopotential-caused trajectory errors. We then apply the filter to determine the likely power of the lost radial information in crossover differences of sea heights determined from satellite altimetry or in the latitude lumped coefficients derived from them. For example, we find that resonant geopotential information with periods longer than the corrected orbit's arc length is largely lost in residual crossover data. Results are given for GEOSAT, ERS-1 and TOPEX/Poseidon in their Exact Repeat Missions, using calibrated variancecovariance matrices of the harmonic geopotential coefficients of several recent Earth gravity models. To prove that filtering is important, we first employed a simple cut of all perturbing terms with periods longer than the general tracking period (4 days for GEOSAT and ERS-1, and 10 days for TOPEX). But the cut is too crude a method from a theoretical viewpoint, and thus, we developed two new filters. A comparison of their admittances explains the differences (and sometimes anomalous behaviour) between them and the cut. Many numerical examples (single-satellite crossover errors and latitude lumped coefficient errors, as projected from the variance-covariance matrices) are presented.This paper has been presented during the Panel on Satellite Dynamics, at COSPAR 1994, in Hamburg, Germany.     

Holocene environmental change in the Skallingen area,eastern North Greenland,based on a lacustrine record

A lacustrine record from a small lake, Lille Sneha Sø, in the Skallingen area indicates that the region was deglaciated in the early Holocene, prior to 8000 cal. a BP. Deglaciation was probably triggered by high temperatures, but it took more than 1000 years for the lake and the catchment to stabilize. Chironomids were amongst the first invertebrates to colonize the lake. The fossil chironomid assemblage is fairly rich and comparable to other records from further south in Greenland. The pioneer vegetation in the area consisted of mosses and herbaceous plants. The oldest remains of woody plants (Salix arctica) are dated to c. 7700 cal. a BP, and remains of Dryas integrifolia appear at around 6700 cal. a BP; these are the only woody plants recorded. Maximum concentrations of chironomids, maximum occurrence of ephippia of the water flea Daphnia pulex, highest organic matter contents and lowest minerogenic input from c. 7700 to 4400 cal. a BP probably reflect the Holocene thermal maximum (HTM). The highest temperatures during the HTM are indicated around 7000 cal. a BP, when Salix arctica, which is considered a warmth‐loving plant, had a maximum. Comparisons with Holocene records from East and North Greenland show similar immigration histories and similar trends, with the Little Ice Age as the coldest period during the Holocene, culminating about 150 years ago. Subsequent warming does not indicate environmental conditions comparable to the HTM yet at this stage. The occurrence of several warmth‐demanding species particularly in the early Holocene sediments indicates redeposition and implies that temperatures in the past, most likely during an interglacial period, were significantly higher than during the HTM.     

Pyroxene glasses — candidates for the interstellar silicate dust component

Experimentelle Arbeiten, die von der Universitäts-Sternwarte Jena in Zusammenarbeit mit chemischen Institutionen durchgeführt wurden, haben gezeigt, daß Pyroxengläser vielversprechende Kandidaten zur Identifizierung von Silikatstaubteilchen in der Umgebung sehr junger Objekte in Molekülwolken, z. B. BN-Objekten und T-Tauri-Sternen, sind. Die Wichtigkeit dieser Experimente besteht darin, daß sie die zur Modellierung der Quellen benötigren optischen Daten liefern und daß sie es ermöglichen, die mineralogische Beschaffenheit des Teilchenmaterials zu verstehen. In dieser Arbeit werden die Schritle, die in der jüngsten Zeit von der Jenaer Staubarbeitsgruppe in beide Richtungen unternommen wurden, beschrieben.