Magnetic properties of sheet silicates; 2:1:1 layer minerals

Magnetization, susceptibility and Mössbauer spectra are reported for representative chlorite samples with differing iron content. The anisotropy of the susceptibility and magnetization of a clinochlore crystal is explained using the trigonal effective crystal-field model developed earlier for 1:1 and 2:1 layer silicates, with a splitting of theT _2g triplet of 1,120K. Predominant exchange interactions in the iron-rich samples are ferromagnetic withJ=1.2 K, as for other trioctahedral ferrous minerals. A peak in the susceptibility of thuringite occurs atT _m=5.5 K, and magnetic hyperfine splitting appears at lower temperatures in the Mössbauer spectrum. However neutron diffraction reveals no long-range magnetic order in thuringite (or biotite, which behaves similarly). The only magnetic contribution to the diffraction pattern at 1.6 K is increased small angle scattering (q<0.4 Å^?1). A factor favouring this random ferromagnetic ground state over the planar antiferromagnetic state of greenalite and minnesotaite is the presence of pairs of ferric ions on adjacent sites, in conjunction with magnetic vacancies in the octahedral sheets. Monte Carlo simulations of the magnetic ground state of the sheets illustrate how long range ferromagnetic order may be destroyed by vortices forming around the Fe³⁺-Fe³⁺ pairs.     

Collisional plateaus

In the fifteen years since the importance of collisional plateaus with thickened continental crust began to be recognized as one of the inevitable consequences of the processes of plate tectonics, rapid progress in their understanding has come from studies of the world's only active terminal collision zones in the Himalayan-Tibetan and Turkish-Iranian plateaus.Ancient collisional plateaus are being recognized throughout the geological record (back to 3.8 Ga) from the occurrence of extensive areas (typically > 500,000 km²) of 8 kbar metamorphism in granulite facies or from the occurrence of extensive areas of higher level minimum-melt composition granite rocks whose isotopic signatures indicate reactivation of existing continental crust rather than addition of new crust from the mantle at the time of collision. Recognition of strike-slip faulting in the ancient collisional plateau areas indicates that “tectonic escape” may have been as important in the past as it is today.Earth may not be the only planet on which collisional plateaus are important. The highlands of Venus (approximately 7% of the surface with elevations over 1.5 km above mean planetary radius) can only exist as a result of crustal thickening, and not as a product of lithospheric thinning. Most of these highlands can be explained by models involving volcanic construction. However, the highest peaks, including Maxwell Montes, the highest mapped area of Venus rising over 10 km above mean planetary radius, require much greater crustal thickening to support them than can reasonably be explained by a volcanic mechanism. Geological features of Maxwell Montes inferred from radar images suggest some analogy between Maxwell Montes and the Tibetan plateau.It is somewhat paradoxical that extensional tectonics are commonly associated with continental collision, and that collision-related rifts may be the only sites where the uppermost layers of a collision-thickened crust are preserved from erosion. Extensional stress fields are generated during continental collision, primarily in areas associated with strike-slip faulting and “tectonic escape”. Additional extensional stresses are gravitationally generated associated with the topography and thickened crust in a collision zone. Tectonically thickened crust is particularly susceptible to rifting as its lithosphere is weak as a result of heating associated with magmatism. This lithosphere is also compositionally weak because of the relatively thick crust, dominated by a weak quartz rheology, and thin mantle lithosphere, dominated by a strong olivine rheology, in comparison with a lithosphere with a more normal crustal thickness. Thus, the common association of rifts and collision zones may be a consequence of both stresses generated during collision and modification of the lithosphere by collision.     

Neotectonics of Hispaniola: plate motion, sedimentation, and seismicity at a restraining bend

A series of different plutons from the Lhasa-Xigaze segment of the Gangdese (Transhimalaya) belt has been studied by high-resolution UPb analyses of zircon (using zircon fractions of 5–100 grains each, selected upon specific grain characteristics). For two diorites, located east of Xigaze (Dazhuka), the zircons yield concordant ages of 93.4 ± 1.0 and 94.2 ± 1.0 m.y., respectively. Also concordant ages of 41.1 ± 0.4 and 41.7 ± 0.4 m.y. have been obtained for two granodiorites, collected southwest of Lhasa (Qushui). The precision on the ages of two granites from the Xigaze and Lhasa area, is limited by two factors: the presence of inherited radiogenic lead and the occurrence of subsequent lead loss. However, some concordant zircons, detected in both granites, define approximate ages of about 67 and 53 m.y., respectively. The inherited lead components show that melting of Precambrian material was involved in magma genesis.The UPb ages substantiate a magmatic activity lasting from mid-Cretceous (Cenomanian) to Eocene (Lutetian) time. Such a period of plutonism at the southern margin of Eurasia, as well as the occurrence of magma generation from continental crust, suggest that the Gangdese range results from the subduction of Tethys oceanic lithosphere (Indian plate) underneath Eurasia (Eurasian plate). If this model is true, the collision of India with Eurasia (along the Lhasa-Xigaze sector) postdates the emplacement of the 41 m.y. old Gangdese granodiorites, i.e. the collision occurred after Lutetian time.     

Plasma bubbles near the dawn terminator in the topside ionosphere

The physical properties of plasma bubbles in the topside ionosphere near the dawn terminator are investigated. It is assumed that the bubbles result from either a Rayleigh-Taylor or an $\text{E}\text{×}\text{B}$ instability on the bottom side of the F-layer. While the E-region is in darkness, the top and bottomsides of the ionosphere are electrically decoupled and the motion of bubbles can be described by non-linear, two-dimensional theory. After sunrise, electric fields within the bubbles discharge through the conducting lower ionosphere. The upward drift of the bubbles is effectively halted. To achieve a dayside state of diffusive equilibrium the bubbles slowly begin to collapse from the bottom.     

The deglaciation of the western sector of the Irish Ice Sheet from the inner continental shelf to its terrestrial margin

This paper provides a new deglacial chronology for retreat of the Irish Ice Sheet from the continental shelf of western Ireland to the adjoining coastline, a region where the timing and drivers of ice recession have never been fully constrained. Previous work suggests maximum ice-sheet extent on the outer western continental shelf occurred at ~26–24 cal. ka BP with the initial retreat of the ice marked by the production of grounding-zone wedges between 23–21.1 cal. ka BP. However, the timing and rate of ice-sheet retreat from the inner continental shelf to the present coast are largely unknown. This paper reports 31 new terrestrial cosmogenic nuclide (TCN) ages from erratics and ice-moulded bedrock and three new optically stimulated luminescence (OSL) ages on deglacial outwash. The TCN data constrain deglaciation of the near coast (Aran Islands) to ~19.5–18.5 ka. This infers ice retreated rapidly from the mid-shelf after 21 ka, but the combined effects of bathymetric shallowing and pinning acted to stabilize the ice at the Aran Islands. However, marginal stability was short-lived, with multiple coastal sites along the Connemara/Galway coasts demonstrating ice recession under terrestrial conditions by 18.2–17. ka. This pattern of retreat continued as ice retreated eastward through inner Galway Bay by 16.5 ka. South of Galway, the Kilkee–Kilrush Moraine Complex and Scattery Island moraines point to late stage re-advances of the ice sheet into southern County Clare ~14.1–13.3 ka, but the large errors associated with the OSL ages make correlation with other regional re-advances difficult. It seems more likely that these moraines are the product of regional ice lobes adjusting to internal ice-sheet dynamics during deglaciation in the time window 17–16 ka.     

Identification of the last glacial maximum in the Upper Paleolithic of Portugal using magnetic susceptibility measurements of Caldeirão Cave sediments

We have sampled Upper and Middle Paleolithic sediments in Caldeirão Cave, Portugal, for paleoclimatic analysis. This work involved measuring magnetic susceptibility (MS) on continuous vertical profiles of a series of ∼8 cc sediment samples, and using the MS data as a paleoclimate proxy. Previous work has shown that caves can be ideal recorders of paleoclimatic variations because they are protected environments. Pedogenesis outside the cave during time of cool climate produces sediments with low MS magnitudes, while warmer climates yield higher MS magnitudes. Eroded soils collect in caves in sediment sequences where futher pedogenesis and biological disturbance is minimal. Continuously sampled profiles of those sediments found in an archaeological context then allow paleoclimatic estimates for all archaeological levels. Results of our work here include identification of the last glacial maximum, at ca. 24,000–22,000 B.P. (calibrated), defined by very low MS values found in basal Solutrean levels in the cave. Distinctive ca. 2500 year Neo-glacial cycles, defined by the MS data within the Early Upper Paleolithic and Solutrean, are consistent with published ¹⁴C duration estimates for the Upper Paleolithic in Caldeirão Cave. © 1998 John Wiley & Sons, Inc.     

High Arctic sea ice conditions influence marine birds wintering in Low Arctic regions

Ocean climate change is having profound biological effects in polar regions. Such change can also have far-reaching downstream effects in sub-polar regions. This study documents an environmental relationship between High Arctic sea ice changes and mortality events of marine birds in Low Arctic coastal regions. During April 2007 and March 2009, hundreds of beached seabird carcasses and moribund seabirds were found along the east and northeast coasts of Newfoundland, Canada. These seabird “wrecks” (i.e. dead birds on beaches) coincided with a period of strong, persistent onshore winds and heavily-accumulated sea ice that blocked bays and trapped seabirds near beaches. Ninety-two percent of wreck seabirds were Thick-billed Murres (Uria lomvia). Body condition and demographic patterns of wreck murres were compared to Thick-billed Murres shot in the Newfoundland murre hunt. Average body and pectoral masses of wreck carcasses were 34% and 40% lighter (respectively) than shot murres, indicating that wreck birds had starved. The acute nature of each wreck suggested that starvation and associated hypothermia occurred within 2–3 days. In 2007, first-winter murres (77%) dominated the wreck. In 2009, there were more adults (78%), mostly females (66%). These results suggest that spatial and temporal segregation in ages and sexes can play a role in differential survival when stochastic weather conditions affect discrete areas where these groups aggregate. In wreck years, southward movement of Arctic sea ice to Low Arctic latitudes was later and blocked bays longer than in most other years. These inshore conditions corresponded with recent climate-driven changes in High Arctic ice break-up and ice extent; coupled with local weather conditions, these ice conditions appeared to be the key environmental features that precipitated the ice-associated seabird wrecks in the Low Arctic region.     

Ontogenetic patterns of concentration indicate lagoon nurseries are essential to common grunts stocks in a Puerto Rican bay

Estimates of abundance and size of three commercially exploited grunt species indicate ontogenetic changes in habitat utilization concentrate their juveniles within the lagoon of the Bay of La Parguera, Puerto Rico. Eleven biotopes, defined by four benthic structures (reef, mangrove, vegetation beds and unconsolidated sediments) and three geographic zones (inner lagoon, outer lagoon and bank shelf) were sampled randomly by visual surveys. French, bluestriped and white grunt (Haemulon flavolineatum, Haemulon sciurus and Haemulon plumeri) were common in the bay and appeared to exhibit similar life history patterns of cross-shelf migration and habitat selection. Recently settled grunts were dispersed over vegetated and unconsolidated soft-bottom sediments of the bay. The juvenile stage occurred in highest densities in shallow lagoon biotopes among the submerged prop-roots of mangrove stands and on inshore reefs. Length data indicates that grunts migrate offshore to adult habitat via increasingly deep reefs. Indices of biotope nursery function based on standing stock estimates of juveniles identified three biotopes, all within the inner lagoon as essential habitat for juveniles of 5–10 cm length interval. This concentration of juveniles within biotopes of the lagoon could represent a bottleneck to recruitment for grunt stocks. Evidence that quantity and quality of lagoon nurseries may limit recruitment indicates that these areas represent a key component of a marine protected area designed to restore fisheries within the bay.     

Improving sub-salt imaging using 3D basin model derived velocities

The quality of depth imaging is directly related to the accuracy of the underlying velocity model. In most sub-salt settings, lack of angular illumination severely degrades the resolution and accuracy of velocity information derived from the seismic data itself. A standard approach for building a starting velocity model uses more reliable velocity information outboard of salt which is subsequently extrapolated to populate the sub-salt regions. The shortcoming of this method lies in the assumption that the effective stress observed outboard of salt can be extrapolated beneath salt solely as a function of depth below mudline.