Origin of dacites of Taupo Volcanic Zone, New Zealand

Dacites form a relatively small proportion of lavas in the Taupo Volcanic Zone, New Zealand (5km³), and occur mainly on the eastern side. In this paper their origin is considered in terms of three processes: (a) partial melting of crustal rocks; (b) fractional crystallisation of basalt and andesite; and (c) sub-surface mixing of basic and acid magma. Modelling techniques are used to calculate the most acceptable degree of fractional crystallisation and magma mixing to fit major-element data, and these values are used to compare calculated and observed trace-element values. The success or failure of the model is determined by the closeness of the two sets of values. For partial-melt models, trace-element values alone are calculated by the batch-melting equation.Results indicate that White Island dacite can best be modelled by fractional crystallisation; Manawahe by fractional crystallisation plus limited crustal contamination; Maungaongaonga by partial melting of Western Basement greywacke, and Tauhara by partial melting of this greywacke together with minor mixing with a more basic magma. Results from Parekauau and Horohoro indicate that these lavas are unlikely to have formed by any of the processes examined.     

THREE-WAY METHODS FOR THE CALIBRATION OF CHROMATOGRAPHIC SYSTEMS:COMPARING PARAFAC AND THREE-WAY PLS

For the calibration of chromatographic systems,different methods can be used.One class of methodsutilizes three-way approaches.The calibration problem is stated in such a way that the decompositionof a three-way array can serve for the prediction of retention on new stationary phases.Two three-way approaches are presented:the Unfold-PCA and PARAFAC models.The theory ofboth methods is presented and the differences are highlighted,the main difference being that PARAFACis a trilinear decomposition whereas Unfold-PCA is not.Both three-way methods are evaluated on asmall data set consisting of retention measurements of eight solutes at six mobile phase compositions onsix stationary phases.The differences in performance of the two models are minor,For calibration purposes,two variants of the methods are discussed:three-way PLS and an extensionof PARAFAC.Again the theory and differences between the two methods are explained.The predictiveperformance of the two methods is compared using the same data set as earlier.The differences inpredictive performance,however,are minor.Both methods are capable of predicting 98% of thevariation in the test sets.Yet,there are other considerations when comparing methods than predictiveperformance,e.g.the quality of the predictions.     

Correction of the ionospheric distortion on the MARSIS surface sounding echoes

Mars Advanced Radar for Subsurface and Ionospheric Sounding (MARSIS) on the Mars Express (MEX) spacecraft has made numerous measurements of the Martian surface and subsurface. However, all of these measurements are distorted by the ionosphere and must be compensated before any analysis. We have developed a technique to compensate for the ionospheric distortions. This technique provides a powerful tool to derive the total electron content (TEC) and other higher-order terms of the limited expansion of the plasma dispersion function that are related to overall shape of the electron column profile. The derived parameters are fitted by using a Chapman model to derive ionospheric parameters like n₀, electron density primary peak (maximum for solar zenith angle (SZA) equal 0), and the neutral height scale H.

Our estimated ionospheric parameters are in good agreement with Mars Global Surveyor (MGS) radio-occultation data. However, since MARSIS does not have the observation geometry limitations of the radio occultation measurements, our derived parameters extend over a large range of SZA for each MEX orbit.

The first results from our technique have been discussed by Safaeinili et al. [2007, Estimation of the total electron content of the Martian ionosphere using radar sounder surface echoes. Geophys. Res. Lett. 34, L23204, doi:10.1029/2007GL032154].     

The formation of small cones in Isidis Planitia,Mars through mobilization of pyroclastic surge deposits

We investigate the distinctive distribution and pattern of subkilometer-sized cones in Isidis Planitia, and their relationship to the material that fills the basin. We observe that: (1) the cones show uniform size, spacing, and morphology across the entire basin; (2) they have large central depressions (relative to cone basal diameters) that are generally filled in and commonly show layering; (3) cone chains form highly organized spatial patterns; cones are also found in isolation and in dense fields; (4) many adjacent chains are parallel, and evenly spaced, creating a pattern that mimics lava flows that have experienced compressional folding; (5) no flows are associated with the cones, even where summit crater rims are breached; (6) the cones are at least temporally related to basin fill; (7) the basin fill material is largely fine-grained, but with locally indurated layers at shallow depth; blocks ejected by small craters from these locally indurated layers are commonly dark in color; and (8) relationships between cones along a chain show no systematic temporal formation sequence along the chain. We conclude that the basin was likely inundated by one or more hot, partially welded pyroclastic flows; devolatilization of these flows remobilized volcaniclastic material to form the cones without associated lava flows. The volume of gas required to account for the observed number of cones is low and does not require the presence of ground water or ice.     

Geochemical reconstruction of late Holocene drainage and mixing in Kluane Lake,Yukon Territory

The level of Kluane Lake in southwest Yukon Territory, Canada, has fluctuated tens of metres during the late Holocene. Contributions of sediment from different watersheds in the basin over the past 5,000 years were inferred from the elemental geochemistry of Kluane Lake sediment cores. Elements associated with organic material and oxyhydroxides were used to reconstruct redox fluctuations in the hypolimnion of the lake. The data reveal complex relationships between climate and river discharge during the late Holocene. A period of influx of Duke River sediment coincides with a relatively warm climate around 1,300 years BP. Discharge of Slims River into Kluane Lake occurred when Kaskawulsh Glacier advanced to the present drainage divide separating flow to the Pacific Ocean via Kaskawulsh and Alsek rivers from flow to Bering Sea via tributaries of Yukon River. During periods when neither Duke nor Slims river discharged into Kluane Lake, the level of the lake was low and stable thermal stratification developed, with anoxic and eventually euxinic conditions in the hypolimnion.     

Simulation and projection of climate change using CMIP6 Muti-models in the Belt and Road Region

Climate condition over a region is mostly determined by the changes in precipitation, temperature and evaporation as the key climate variables. The countries belong to the Belt and Road region are subjected to face strong changes in future climate. In this paper, we used five global climate models from the latest Sixth Phase of Coupled Model Intercomparison Project (CMIP6) to evaluate future climate changes under seven combined scenarios of the Shared Socioeconomic Pathways and the Representative Concentration Pathways (SSP1-1.9, SSP1-2.6, SSP2-4.5, SSP3-7.0, SSP4-3.4, SSP4-6.0 and SSP5-8.5) across the Belt and Road region. This study focuses on undertaking a climate change assessment in terms of future changes in precipitation, air temperature and actual evaporation for the three distinct periods as near-term period (2021-2040), mid-term period (2041-2060) and long-term period (2081-2100). To discern spatial structure, K?ppen-Geiger Climate Classification method has been used in this study. In relative terms, the results indicate an evidence of increasing tendency in all the studied variables, where significant changes are anticipated mostly in the long-term period. In addition to, though it is projected to increase under all the SSP-RCP scenarios, greater increases will be happened under higher emission scenarios (SSP5-8.5 and SSP3-7.0). For temperature, robust increases in annual mean temperature is found to be 5.2 °C under SSP3-7.0, and highest 7.0 °C under SSP5-8.5 scenario relative to present day. The northern part especially Cold and Polar region will be even more warmer (+6.1 °C) in the long-term (2081-2100) period under SSP5-8.5. Similarly, at the end of the twenty-first century, annual mean precipitation is inclined to increase largely with a rate of 2.1% and 2.8% per decade under SSP3-7.0 and SSP5-8.5 respectively. Spatial distribution demonstrates that the largest precipitation increases are to be pronounced in the Polar and Arid regions. Precipitation is projected to increase with response to increasing warming most of the regions. Finally, the actual evaporation is projected to increase significantly with rate of 20.3% under SSP3-7.0 and greatest 27.0% for SSP5-8.5 by the end of the century. It is important to note that the changes in evaporation respond to global mean temperature rise consistently in terms of similar spatial pattern for all the scenarios where stronger increase found in the Cold and Polar regions. The increase in precipitation is overruled by enhanced evaporation over the region. However, this study reveals that the CMIP6 models can simulate temperature better than precipitation over the Belt and Road region. Findings of this study could be the reliable basis for initiating policies against further climate induced impacts in the regional scale.     

Möglichkeiten der photometrischen Untersuchung von Kugelhaufen mittels photographischer Äquidensiten

A method of estimating the surface-brightness of globular cluster with equidensity curves is described. (Russian abstract)     

Kampfer ein Rauschgift für Fische

Ohne Zusammenfassung     

Intrusion and differentiation of granitic magma at a high level in the crust: the Puscao pluton, Lima Province, Peru

Regression surface techniques have been used on partial whole-rockchemical analyses from the Puscao pluton to establish the three-dimensionalnature of the chemical variations within this body, which wasemplaced at a depth of between 4 km and 8 km within the crust.Block diagrams produced by the computer program are consistentwith the hypothesis that during the period preceding the totalconsolidation of the magma, the pluton has undergone in situdifferentiation to give a layered structure. Statistical analysis confirms that there is a large scale variationwithin the pluton and that local variation, such as might beexpected to result from the contamination of the Puscao magmaby assimilated volcanic material, did not contribute significantlyto the overall variation. Evidence is presented which suggests that the layering withinthe Puscao pluton was disturbed as a result of the emplacementof the much later Cañhas pluton, and that this disturbancehas the form of a simple doming centred upon the site of thepresent Cañas intrusion.