Pathways and regulation of carbon, sulfur and energy transfer in marine sediments overlying methane gas hydrates on the Opouawe Bank (New Zealand)

This study combines sediment geochemical analysis, in situ benthic lander deployments and numerical modeling to quantify the biogeochemical cycles of carbon and sulfur and the associated rates of Gibbs energy production at a novel methane seep. The benthic ecosystem is dominated by a dense population of tube-building ampharetid polychaetes and conspicuous microbial mats were unusually absent. A 1D numerical reaction-transport model, which allows for the explicit growth of sulfide and methane oxidizing microorganisms, was tuned to the geochemical data using a fluid advection velocity of 14 cm yr⁻¹. The fluids provide a deep source of dissolved hydrogen sulfide and methane to the sediment with fluxes equal to 4.1 and 18.2 mmol m⁻² d⁻¹, respectively. Chemosynthetic biomass production in the subsurface sediment is estimated to be 2.8 mmol m⁻² d⁻¹ of C biomass. However, carbon and oxygen budgets indicate that chemosynthetic organisms living directly above or on the surface sediment have the potential to produce 12.3 mmol m⁻² d⁻¹ of C biomass. This autochthonous carbon source meets the ampharetid respiratory carbon demand of 23.2 mmol m⁻² d⁻¹ to within a factor of 2. By contrast, the contribution of photosynthetically-fixed carbon sources to ampharetid nutrition is minor (3.3 mmol m⁻² d⁻¹ of C). The data strongly suggest that mixing of labile autochthonous microbial detritus below the oxic layer sustains high measured rates of sulfate reduction in the uppermost 2 cm of the sulfidic sediment (100-200 nmol cm⁻³ d⁻¹). Similar rates have been reported in the literature for other seeps, from which we conclude that autochthonous organic matter is an important substrate for sulfate reducing bacteria in these sediment layers. A system-scale energy budget based on the chemosynthetic reaction pathways reveals that up to 8.3 kJ m⁻² d⁻¹ or 96 mW m⁻² of catabolic (Gibbs) energy is dissipated at the seep through oxidation reactions. The microorganisms mediating sulfide oxidation and anaerobic oxidation of methane (AOM) produce 95% and 2% of this energy flux, respectively. The low power output by AOM is due to strong bioenergetic constraints imposed on the reaction rate by the composition of the chemical environment. These constraints provide a high potential for dissolved methane efflux from the sediment (12.0 mmol m⁻² d⁻¹) and indicates a much lower efficiency of (dissolved) methane sequestration by AOM at seeps than considered previously. Nonetheless, AOM is able to consume a third of the ascending methane flux (5.9 mmol m⁻² d⁻¹ of CH₄) with a high efficiency of energy expenditure (35 mmol CH₄ kJ⁻¹). It is further proposed that bioenergetic limitation of AOM provides an explanation for the non-zero sulfate concentrations below the AOM zone observed here and in other active and passive margin sediments.     

Did Paleogene North Atlantic rift-related eruptions drive early Eocene climate cooling?

The delivery of volcanogenic sulphur into the upper atmosphere by explosive eruptions is known to cause significant temporary climate cooling. Therefore, phreatomagmatic and phreatoplinian eruptions occurring during the final rifting stages of active flood basalt provinces provide a potent mechanism for triggering climate change.

During the early Eocene, the northeast Atlantic margin was subjected to repeated ashfall for 0.5 m.y. This was the result of extensive phreatomagmatic activity along 3000 km of the opening northeast Atlantic rift. These widespread, predominantly basaltic ashes are now preserved in marine sediments of the Balder Formation and its equivalents, and occur over an area extending from the Faroe Islands to Denmark and southern England. These ash-bearing sediments also contain pollen and spore floras derived from low diversity forests that grew in cooler, drier climates than were experienced either before or after these highly explosive eruptions. In addition, coeval plant macrofossil evidence from the Bighorn Basin, Wyoming, USA, also shows a comparable pattern of vegetation change. The coincidence of the ashes and cooler climate pollen and spore floras in northwest Europe identifies volcanism as the primary cause of climate cooling. Estimates show that whilst relatively few phreatomagmatic eruptive centres along the 3000 km opening rift system could readily generate 0.5–1 °C cooling, on an annual basis, only persistent or repeated volcanic phases would have been able to achieve the long-term cooling effect observed in the floral record. We propose that the cumulative effect of repeated Balder Formation eruptions initiated a biodiversity crisis in the northeast Atlantic margin forests. Only the decline of this persistent volcanic activity, and the subsequent climatic warming at the start of the Eocene Thermal Maximum allowed the growth of subtropical forests to develop across the region.     

A very large scale GIS-based groundwater flow model for the Nubian sandstone aquifer in Eastern Sahara (Egypt,northern Sudan and eastern Libya)

A three-dimensional GIS-based groundwater flow model for the Nubian Sandstone Aquifer in the eastern Sahara was developed and calibrated under steady-state and transient conditions. The model was used to simulate the response of the aquifer to climatic changes that occurred during the last 25,000 years. The simulation results indicated that the groundwater in this aquifer was formed by infiltration during the wet periods 20,000 and 5,000 years b.p. The recharge of groundwater due to regional groundwater flow from more humid areas in the south was excluded. It also indicates that the Nubian Aquifer System is a fossil aquifer, which had been in an unsteady state condition for the last 3,000 years.

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Resumen Fue desarrollado un modelo de flujo de agua subterránea en tres dimensiones, basado en un SIG, para el Acuífero Arenisca Nubian en el Sahara Oriental, el cual fue calibrado para condiciones de estado estacionario y transitorio. El modelo se usó para simular la respuesta del acuífero a los cambios climáticos que ocurrieron durante los últimos 25000 años. Los resultados de esta simulación indicaron que el agua subterránea en este acuífero, se formó por infiltración, durante los períodos húmedos que hubo hace 20000 y 5000 años, antes del presente. Fue excluida la recarga del acuífero debida a un flujo regional de agua subterránea proveniente de áreas con un clima más húmedo en el sur. El modelo también muestra, que el Sistema Acuífero Nubian es un acuífero fósil, el cual ha permanecido en una condición de estado no estacionario, durante los últimos tres mil años.

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Résumé Pour laquifère gréseux Nubien de Sahara -Est on a mis au points un modèle tridimensionnel, basé sur GIS. Le modèle a été calibré tant pour lécoulement stationnaire que pour lécoulement transitoire. On a simulé après la réponse de laquifère aux changements climatiques des derniers 25000 ans. Les résultats des simulations indiquent que la nappe a été rechargée par des infiltrations pendant une période humide qui sétend 5000 et 20000 ans, dès temps actuel. On na pas pris en compte la recharge de laquifère par la zone plus humide située dans sa partie sud. Le modèle indique aussi que leau de laquifère Nubien est une eau fossile qui a eu un écoulement transitoire pendant les derniers 3000 ans.

     

Statistical analysis of factors affecting landslide distribution in the new Madrid seismic zone, Tennessee and Kentucky

More than 220 large landslides along the bluffs bordering the Mississippi alluvial plain between Cairo, Ill., and Memphis, Tenn., are analyzed by discriminant analysis and multiple linear regression to determine the relative effects of slope height and steepness, stratigraphic variation, slope aspect, and proximity to the hypocenters of the 1811-12 New Madrid, Mo., earthquakes on the distribution of these landslides. Three types of landslides are analyzed: (1) old, coherent slumps and block slides, which have eroded and revegetated features and no active analogs in the area; (2) old earth flows, which are also eroded and revegetated; and (3) young rotational slumps, which are present only along near-river bluffs, and which are the only young, active landslides in the area.

Discriminant analysis shows that only one characteristic differs significantly between bluffs with and without young rotational slumps: failed bluffs tend to have sand and clay at their base, which may render them more susceptible to fluvial erosion.

Bluffs having old coherent slides are significantly higher, steeper, and closer to the hypocenters of the 1811-12 earthquakes than bluffs without these slides. Bluffs having old earth flows are likewise higher and closer to the earthquake hypocenters.

Multiple regression analysis indicates that the distribution of young rotational slumps is affected most strongly by slope steepness: about one-third of the variation in the distribution is explained by variations in slope steepness. The distribution of old coherent slides and earth flows is affected most strongly by slope height, but the proximity to the hypocenters of the 1811-12 earthquakes also significantly affects the distribution.

The results of the statistical analyses indicate that the only recently active landsliding in the area is along actively eroding river banks, where rotational slumps formed as bluffs are undercut by the river. The analyses further indicate that the old coherent slides and earth flows in the area are spatially related to the 1811-12 earthquake hypocenters and were thus probably triggered by those earthquakes. These results are consistent with findings of other recent investigations of landslides in the area that presented field, historical, and analytical evidence to demonstrate that old landslides in the area formed during the 1811-12 New Madrid earthquakes.

Results of the multiple linear regression can also be used to approximate the relative susceptibility of the bluffs in the study area to seismically induced landsliding.     

Testing and modeling of the mechanical behavior of dolomite in the Wudongde hydropower plant

In order to understand the mechanical behaviours of the surrounding rocks in the underground caverns of the Wudongde hydropower plant, triaxial tests are performed on a type of dolomite. It is revealed that damage induced by crack development is the main factor controlling the nonlinear plastic deformation and failure behaviour of the dolomite in both pre- and post-peak regimes. Based on this understanding, a coupled elastoplastic damage model is developed for capturing the dolomite’s mechanical behaviours. In the model, the effects of plasticity and damage on rocks is described by introducing plastic hardening and damage softening commonly in the plastic yield surface. Which are both derived from a suitable Helmholtz free energy function. The model is used to simulate the triaxial tests. Comparisons between test results and the numerical modelling show that the developed model is capable of describing the macro mechanical behaviours of the Wudongde dolomite.     

Soil moisture potential and water content in the unsaturated zone within the arid Ejina Oasis in Northwest China

Three soil profiles were selected in the Ejina Oasis, northwest China, to determine water content profiles and evolution of soil moisture potentials in the unsaturated zone within the arid area. The total soil moisture potentials have been monitored for about 3 months in 2001 at different depths in the soil profiles. The occurrence and movement of water in the unsaturated zone was analyzed using the zero flux plane (ZFP) method. It is shown that convergent ZFPs and divergent ZFPs may occur at depths between 0.5 and 3.0 m, and that the depth of the ZFPs was controlled by the root zone of plants growing on the land surface. Profiles of the total soil moisture potentials were observed to be coincident with those of the water contents at the three experimental sites. The total soil moisture potential showed a slight increasing trend and the ZFPs tend to vanish from summer to winter as the water extraction by roots decreased. Evapotranspiration through vegetation has an important bearing on the water content and the total potential in the unsaturated zone.