Zur massenspektrometrischen Bestimmung von Gasen des Systems C-H-O aus Mineralen

Zusammenfassung Die massenspektrometrische Analyse kleinster Gasmengen von H₂, O₂, CO, CO₂, CH₄ und H₂O ist infolge der Beeinflussung durch das Meßsystem mit beachtlichen Schwierigkeiten verbunden. Die Beeinflussung erfolgt einerseits durch Reaktionen der Gase mit heißen Metalloberflächen und andererseits durch im System vorhandene Glasoberflächen. Bei einer entprechenden apparativen Anordnung, Erhitzen der Proben und Trennung der Gase durch Kühlfallen, können Gasmengen in und auf Mineralen bis zu 0,005 mm³/NDT quantitativ bestimmt werden. Die Apparatur ist durch thermische Zersetzung von Muskovit-, Calcitkristallen usw. geeicht. Die Anwendung dieser Methode auf das Gebiet der Chemie und Mineralogie sowie die Grenzen und Möglichkeiten einer quantitativen Analyse von Restgasen wird gezeigt.

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Mass-spectrometric analysis of gases of the system C-H-O in minerals

Summary The analysis by mass-spectrometer of smallest amounts of gases H₂, O₂, CO, CO₂, CH₄ and H₂O, respectively, meets with considerable difficulties, because of the influence by the measuring system. The influence is caused by interactions of the gases with hot metal surfaces on one hand, and glass surfaces on the other hand. By a suitable arrangement of apparatus and procedures, such as heating the samples and separating the gases by cooling traps, the gas amounts in and on minerals can be quantitatively determined up to 0.005 mm³/SPT. The apparatus is calibrated by thermal dissociation of crystals like muscovite, calcite etc. The application of this method in chemistry and mineralogy is treated as well as the limits and the possibility of the quantitative analysis of residual gas.

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Mit 5 Abbildungen     

Geochemical processes in the saltwater–freshwater transition zone: comparing results of a sand tank experiment with field data

Geochemical processes, occurring in a stable transition zone between saltwater and freshwater, were simulated in a 2D, multi-layer flow chamber experiment. Mixing, calcite dissolution, and oxidative degradation of organic matter were identified as the main controlling factors. The results of the chamber experiment were compared to field data and verified by thermodynamic modeling. Similarity in most ion distributions suggests the general applicability of the experimental method. Differences in the redox conditions between field and experiment were reflected by the oxidants involved in the mineralization of organic carbon; while field data show evidence of sulfate reduction, the presence of oxygen in the laboratory experiment resulted in the reoxidation of sulfides.     

A 50-year record of NO<Subscript>x</Subscript> and SO<Subscript>2</Subscript> sources in precipitation in the Northern Rocky Mountains,USA

Ice-core samples from Upper Fremont Glacier (UFG), Wyoming, were used as proxy records for the chemical composition of atmospheric deposition. Results of analysis of the ice-core samples for stable isotopes of nitrogen (δ¹⁵N, ) and sulfur (δ³⁴S, ), as well as and deposition rates from the late-1940s thru the early-1990s, were used to enhance and extend existing National Atmospheric Deposition Program/National Trends Network (NADP/NTN) data in western Wyoming. The most enriched δ³⁴S value in the UFG ice-core samples coincided with snow deposited during the 1980 eruption of Mt. St. Helens, Washington. The remaining δ³⁴S values were similar to the isotopic composition of coal from southern Wyoming. The δ¹⁵N values in ice-core samples representing a similar period of snow deposition were negative, ranging from -5.9 to -3.2 ‰ and all fall within the δ¹⁵N values expected from vehicle emissions. Ice-core nitrate and sulfate deposition data reflect the sharply increasing U.S. emissions data from 1950 to the mid-1970s.     

Characteristics of pegmatoidal granite exposed near Bayalan,Ajmer district,Rajasthan

The study involves the characterization of pegmatoidal granite, southeast of Beawar, Ajmer district, Rajasthan. Earlier researchers had described this granite as part of the BGC, basement to the Bhim Group of the Delhi Super Group rocks. However, the present study indicates that it is younger than the rocks of Bhim Group of South Delhi Fold Belt, into which it is intrusive. The intrusion is structurally controlled and the outcrop pattern is phacolithic. The granite had intruded post-D₂ deformation of the Delhi orogeny along the axial planes of D₂ folds. The intrusion has also resulted in the formation of a contact aureole about the calc gneisses.     

Gas emission prediction and recovery in underground coal mines

Strata gas can be released and captured from non-active and active gas resources either from virgin or relaxed strata, both prior to and when mining activities take place. The high and irregular gas emissions associated with high production longwall mining have provided a need to optimise the methods used to predict these gas levels and the ventilation requirements for gas dilution. A forecast of gas emissions during development drivage and longwall mining indicated possible gas and ventilation problems requiring the introduction of various gas drainage techniques and in maintaining the necessary air quantities in ventilation systems to satisfy the statutory gas limitations for various coal production rates. Although there are sound principles used in world-recognised methods of gas emission prediction, a new approach developed from long-term practical experience in underground gassy coal mine practices and gas-rock mechanics studies appear most suitable for local conditions and mining systems in use. The Lunagas ‘Floorgas' and ‘Roofgas' geomechanical and gas emission models offer an effective solution to these problems. Both programs are the most advanced engineering, numerical tools available to calculate gas source contributions to total gassiness and improve the accuracy and quality of gas control, gas capture technologies and ventilation system design.     

Isotopic evidence on the origin of the Shamrocke copper mine,Rhodesia

The Shamrocke ore body is a stratiform deposit of disseminated copper-iron sulphides found within lenses of calcareous meta-arkose occurring in Lomagundi Group graphitic schist (Late Precambrian) at Karoi, Rhodesia. Both sulphides and sediments were subjected to high grades of regional metamorphism. Argon/argon isochron ages indicate a major metamorphic event at 550 m. y. (Damaran orogeny) with later minor argon losses. Ore sulphide ³⁴S values range from +3.0 to +14.8 CDT and a general decrease from footwall to hanging-wall reflects an original sedimentary environment where sulphides formed about the sea bed from hydrothermal fluids progressively mixing with sea water. Isotopically lighter sulphides formed syngenetically in the host rocks from bacterial reduction of sulphate. The pyrrhotite was probably formed from pyrite during metamorphism, and owing to reducing conditions maintained similar ³⁴S values to the original pyrite. Oxygen and carbon isotopic analyses of mineralised and unmineralised carbonate lenses are consistent with deposition as marine limestones in an evaporitic environment and/or near hot spring vents.I. N. S. Contribution No 734     

Late Pleistocene and Early Holocene lake‐level fluctuations in the Lahontan Basin,Nevada: Implications for the distribution of archaeological sites

The Great Basin of the western U.S. contains a rich record of Late Pleistocene and Holocene lake‐level fluctuations as well as an extensive record of human occupation during the same time frame. We compare spatial‐temporal relationships between these records in the Lahontan basin to consider whether lake‐level fluctuations across the Pleistocene‐Holocene transition controlled distribution of archaeological sites. We use the reasonably well‐dated archaeological record from caves and rockshelters as well as results from new pedestrian surveys to investigate this problem. Although lake levels probably reached maximum elevations of about 1230–1235 m in the different subbasins of Lahontan during the Younger Dryas (YD) period, the duration that the lakes occupied the highest levels was brief. Paleoindian and Early Archaic archaeological sites are concentrated on somewhat lower and slightly younger shorelines (_1220–1225 m) that also date from the Younger Dryas period. This study suggests that Paleoindians often concentrated their activities adjacent to large lakes and wetland resources soon after they first entered the Great Basin. © 2008 Wiley Periodicals, Inc.     

Geophysical investigation using resistivity and GPR methods: a case study of a lubricant oil waste disposal area in the city of Ribeirão Preto,São Paulo,Brazil

Geophysics has been shown to be effective in identifying areas contaminated by waste disposal, contributing to the greater efficiency of soundings programs and the installation of monitoring wells. In the study area, four trenches were constructed with a total volume of about 25,000 m³. They were almost totally filled with re-refined lubricating oil waste for approximately 25 years. No protection liners were used in the bottoms and laterals of the disposal trenches. The purpose of this work is to evaluate the potential of the resistivity and ground penetrating radar (GPR) methods in characterizing the contamination of this lubricant oil waste disposal area in Ribeirão Preto, SP, situated on the geological domain of the basalt spills of the Serra Geral Formation and the sandstones of the Botucatu Formation. Geophysical results were shown in 2D profiles. The geophysical methods used enabled the identification of geophysical anomalies, which characterized the contamination produced by the trenches filled with lubricant oil waste. Conductive anomalies (smaller than 185 Ωm) immediately below the trenches suggest the action of bacteria in the hydrocarbons, as has been observed in several sites contaminated by hydrocarbons in previously reported cases in the literature. It was also possible to define the geometry of the trenches, as evidenced by the GPR method. Direct sampling (chemical analysis of the soil and the water in the monitoring well) confirmed the contamination. In the soil analysis, low concentrations of several polycyclic aromatic hydrocarbons (PAHs) were found, mainly naphthalene and phenanthrene. In the water samples, an analysis verified contamination of the groundwater by lead (Pb). The geophysical methods used in the investigation provided an excellent tool for environmental characterization in this study of a lubricant oil waste disposal area, and could be applied in the study of similar areas.