Workplace environmental demands and energizers at two Kuwait oil companies

The Work Compatibility Improvement Framework was developed and used to assess the environmental and ergonomic work conditions at two oil companies in Kuwait: One is a government-owned company, while the other is a private subcontractor of the government-owned company. The work compatibility presents demand–energizer environmental factors that act upon the individuals in the workplace. The reliability coefficients were tested and considered good (0.752) and excellent (0.855) for two domain conditions environment and ergonomics, respectively. Results reveal that in all of the three regions of the government-owned company (north, southwest, east) the ‘overall’ compatibility data for the ‘environment’ is perceived to be poor. The ‘ergonomics’ compatibility data seem to be average in the southeast and west, while it is considered to be poor in the north. As for the private subcontractor, the perceived ‘environment’ is considered to be poor for two departments out of four (slickline and wellhead maintenance), while considered moderate for the remaining two (maintenance and crude/chemical handling). The ‘ergonomics’ compatibility is reported to be poor for crude/chemical handling and wellhead maintenance jobs; while the conditions seem to be moderate for the maintenance and slickline jobs. The major conclusion extracted from this study is that the oil sector organizations in Kuwait are not managed as ergo-environmental enterprises where there is disharmony in the ergonomics system, environmental system, and the ergo-environmental interface interaction. These gaps in the enterprise-wide systems have a significant impact on work productivity and the environment conditions.     

Holocene profile changes along a California coastal stream

Walker Creek in Marin County, California is a coastal stream draining to Tomales Bay, which lies in the San Andreas Rift Zone. Its valley contains an alluvial fill with a basal gravel dated at 5000 years BP. In upstream parts of the watershed, channels are incised arroyo-like in the fill leaving the valley floor standing as a high terrace averaging 5·5 m (18 ft) high. Below this terrace is an inner terrace of historic age that stands 2·4 m (8 ft) above the streambed. The stratigraphy and morphology of this valley are seen in others nearby, and indicate that in the last half of Holocene time in this region a single episode of valley alluviation was followed by two episodes of valley cutting. The second episode of valley cutting is occurring in the present time. During the last 60 years the flow has become seasonal, the stream has incised 1·5 m (5 ft) below the inner terrace in upstream reaches, aggraded 1·2 m (4 ft) in downstream reaches, and extended its estuary. Incision upstream has begun to re-expose the bedrock valley floor and is associated with aggradation downstream that has caused the flood plain to overtop both terraces. This has decreased the stream's gradient. Using a stream that is currently effecting major changes in its valley and channel morphology, two aspects of hydraulic adjustment in fluvial systems are examined. The changes in the average slope of the longitudinal profile are small but measureable. Profile concavity has not changed measurably. The various profiles that have existed in Holocene time show that stream gradient can be, but is not necessarily, slightly adjusted during valley filling and cutting. Flow measurements at a high discharge show that the channel has begun to assume the hydraulic geometry of an ephemeral channel. Adjustments of depth, velocity, and roughness appear to be hydraulic adjustments in response to changing watershed conditions.     

Mathematical models for petroleum-forming processes: carbon isotope fractionation

A mathematical model has been developed in which carbon isotope fractionation during thermal cracking of n-paraffins can be simulated. The model has been calibrated based on data from laboratory cracking experiments carried out on n-octadecane. Relative rate constants for cleavage of C¹²-C¹², C¹²-C¹³ and C¹³-C¹³ bonds agree with the experimental values obtained by other workers.Application of this model to the process of petroleum formation gives good agreement with some existing experimental data, but suggests that a review of our understanding of isotope fractionation during thermal cracking may be necessary. The relative importance of the degree to which the organic material has been cracked and of the type of the organic material in influencing δC¹³ values is discussed.The present model predicts that cracking of n-paraffin distributions having initial odd or even carbon number predominances can induce isotopic inhomogeneity among the homologs of the resulting distribution. The model exhibits some deficiencies in explaining or predicting the δC¹³ values of ethane and propane in relation to methane in gases and of oils and associated methane. Explanations for these discrepancies may lie in the simplicity of our mathematical model, in our assumption of initial isotopic homogeneity within molecules and in our use of only n-paraffins as the source molecules for the cracking reactions.     

Stratification and bottom-water hypoxia in the Pamlico River estuary

Relationships among bottom-water dissolved oxygen (DO), vertical stratification, and the factors responsible for stratification-destratification in this shallow, low tidal-energy estuary were studied using a 15-yr set of biweekly measurements, along with some recent continuous-monitoring data. Hypoxia develops only when there is both vertical water-column stratification and warm water temperature (>15°C). In July, 75% of the DO readings were <5 mg 1^?1, and one-third were <1 mg 1^?1. Severe hypoxia occurs more frequently in the upper half of the estuary than near the mouth. Both the time series data and correlation analysis results indicate that stratification events and DO levels are tightly coupled with variations in freshwater discharge and wind stress. Stratification can form or disappear in a matter of hours, and episodes lasting from one to several days seem to be common. Estimated summertime respiration rates in the water and sediments are sufficient to produce hypoxia if the water is mixed only every 6–12 d. There has been no trend toward lower bottom water DO in the Pamlico River Estuary over the past 15 yr. *** DIRECT SUPPORT *** A01BY059 00002     

Melt extraction and melt refertilization in mantle peridotite of the Coast Range ophiolite: an LA–ICP–MS study

The middle Jurassic Coast Range Ophiolite (CRO) is one of the most important tectonic elements in western California, cropping out as tectonically dismembered elements that extend 700 km from south to north. The volcanic and plutonic sections are commonly interpreted to represent a supra-subduction zone (SSZ) ophiolite, but models specifying a mid-ocean ridge origin have also been proposed. These contrasting interpretations have distinctly different implications for the tectonic evolution of the western Cordillera in the Jurassic. If an SSZ origin is confirmed, we can use the underlying mantle peridotites to elucidate melt processes in the mantle wedge above the subduction zone. This study uses laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) to study pyroxenes in peridotites from four mantle sections in the CRO. Trace element signatures of these pyroxenes record magmatic processes characteristic of both mid-ocean ridge and supra-subduction zone settings. Group A clinopyroxene display enriched REE concentrations [e.g., Gd (0.938–1.663 ppm), Dy (1.79–3.24 ppm), Yb (1.216–2.047 ppm), and Lu (0.168–0.290 ppm)], compared to Group B and C clinopyroxenes [e.g., Gd (0.048–0.055 ppm), Dy (0.114–0.225 ppm), Yb (0.128–0.340 ppm), and Lu (0.022–0.05 ppm)]. These patterns are also evident in orthopyroxene. The differences between these geochemical signatures could be a result of a heterogeneous upper mantle or different degrees of partial melting of the upper mantle. It will be shown that CRO peridotites were generated through fractional melting. The shapes of REE patterns are consistent with variable degrees of melting initiated within the garnet stability field. Models call for 3% dry partial melting of MORB-source asthenosphere in the garnet lherzolite field for abyssal peridotites and 15–20% further partial melting in the spinel lherzolite field, possibly by hydrous melting for SSZ peridotites. These geochemical variations and occurrence of both styles of melting regimes within close spatial and temporal association suggest that certain segments of the CRO may represent oceanic lithosphere, attached to a large-offset transform fault and that east-dipping, proto-Franciscan subduction may have been initiated along this transform.     

Radium uptake during barite recrystallization at 23 ± 2 °C as a function of solution composition: An experimental Ba and Ra tracer study

High-purity synthetic barite powder was added to pure water or aqueous solutions of soluble salts (BaCl₂, Na₂SO₄, NaCl and NaHCO₃) at 23 ± 2 °C and atmospheric pressure. After a short pre-equilibration time (4 h) the suspensions were spiked either with ¹³³Ba or ²²⁶Ra and reacted under constant agitation during 120-406 days. The pH values ranged from 4 to 8 and solid to liquid (S/L) ratios varied from 0.01 to 5 g/l. The uptake of the radiotracers by barite was monitored through repeated sampling of the aqueous solutions and radiometric analysis. For both ¹³³Ba and ²²⁶Ra, our data consistently showed a continuous, slow decrease of radioactivity in the aqueous phase.Mass balance calculations indicated that the removal of ¹³³Ba activity from aqueous solution cannot be explained by surface adsorption only, as it largely exceeded the 100% monolayer coverage limit. This result was a strong argument in favor of recrystallization (driven by a dissolution-precipitation mechanism) as the main uptake mechanism. Because complete isotopic equilibration between aqueous solution and barite was approached or even reached in some experiments, we concluded that during the reaction all or substantial fractions of the initial solid had been replaced by newly formed barite.The ¹³³Ba data could be successfully fitted assuming constant recrystallization rates and homogeneous distribution of the tracer into the newly formed barite. An alternative model based on partial equilibrium of ¹³³Ba with the mineral surface (without internal isotopic equilibration of the solid) could not reproduce the measured activity data, unless multistage recrystallization kinetics was assumed. Calculated recrystallization rates in the salt solutions ranged from 2.8 × 10⁻¹¹ to 1.9 × 10⁻¹⁰ mol m⁻² s⁻¹ (2.4-16 μmol m⁻² d⁻¹), with no specific trend related to solution composition. For the suspensions prepared in pure water, significantly higher rates (∼5.7 × 10⁻¹⁰ mol m⁻² s⁻¹ or ∼49 μmol m⁻² d⁻¹) were determined.Radium uptake by barite was determined by monitoring the decrease of ²²⁶Ra activity in the aqueous solution with alpha spectrometry, after filtration of the suspensions and sintering. The evaluation of the Ra uptake experiments, in conjunction with the recrystallization data, consistently indicated formation of non-ideal solid solutions, with moderately high Margules parameters (W_AB = 3720-6200 J/mol, a₀ = 1.5-2.5). These parameters are significantly larger than an estimated value from the literature (W_AB = 1240 J/mol, a₀ = 0.5).In conclusion, our results confirm that radium forms solid solutions with barite at fast kinetic rates and in complete thermodynamic equilibrium with the aqueous solutions. Moreover, this study provides quantitative thermodynamic data that can be used for the calculation of radium concentration limits in environmentally relevant systems, such as radioactive waste repositories and uranium mill tailings.     

Absolute magnitudes of OB and Be stars based on Hipparcos parallaxes – III

The absolute visual magnitudes, M_V , of A–M stars are based on calculated Hipparcos trigonometric parallaxes. The sample used consists of 30 986 unreddened and reddened A–M stars in luminosity classes Ia, Iab, Ib, II, III, IV and V. The colour excesses of the reddened stars were calculated using the mean colour indices, according to the SIMBAD data base and the intrinsic B − V values calibrated for the given spectral types and luminosity classes by Schmidt-Kaler. The values of the total-to-selective extinction,   R_V = A_V / E ( B − V )  , for all the reddened stars were calculated from previously published near-infrared photometric measurements. The calculated visual magnitudes, M_V , of A–M stars compare with the earlier determinations of Schmidt-Kaler. The mean absolute magnitudes published by Schmidt-Kaler are generally brighter (except for the stars in luminosity classes V and IV) than those determined in this paper.     

Fast magnetoacoustic solitary waves in dense magnetoplasmas in a cylindrical geometry

Nonlinear properties of the quantum magnetoacoustic wave are studied in electron-ion magnetoplasmas. In this regard, cylindrical Korteweg deVries (CKdV) equation is derived for small amplitude perturbations. The solution of the planar KdV equation is obtained using the tanh method and is subsequently used as an initial profile to solve the CKdV equation. It is found that the system under consideration admits compressive solitary structures. Finally, it is found that the amplitude as well as the width of the nonplanar magnetosonic solitary structure increases with the increase in the magnetic field whereas a decrease is observed with the increase in number density of the system. The present study may be beneficial to understand the nonlinear wave propagation in nonplanar geometries in dense plasmas.     

Solar Flare Prediction Using Advanced Feature Extraction, Machine Learning, and Feature Selection

Novel machine-learning and feature-selection algorithms have been developed to study: i) the flare-prediction-capability of magnetic feature (MF) properties generated by the recently developed Solar Monitor Active Region Tracker (SMART); ii) SMART’s MF properties that are most significantly related to flare occurrence. Spatiotemporal association algorithms are developed to associate MFs with flares from April 1996 to December 2010 in order to differentiate flaring and non-flaring MFs and enable the application of machine-learning and feature-selection algorithms. A machine-learning algorithm is applied to the associated datasets to determine the flare-prediction-capability of all 21 SMART MF properties. The prediction performance is assessed using standard forecast-verification measures and compared with the prediction measures of one of the standard technologies for flare-prediction that is also based on machine-learning: Automated Solar Activity Prediction (ASAP). The comparison shows that the combination of SMART MFs with machine-learning has the potential to achieve more accurate flare-prediction than ASAP. Feature-selection algorithms are then applied to determine the MF properties that are most related to flare occurrence. It is found that a reduced set of six MF properties can achieve a similar degree of prediction accuracy as the full set of 21 SMART MF properties.