Solar radio spectrography in Europe

Recent technical progress of solar radio spectrography is concerned with digital data recording, the achievement of high time and frequency resolution, and with an improved coverage of the radio range at short and long wavelengths. A spatially-distributed network of radio spectrographs allows for complementary information about solar events and periods of activity selected for detailed investigation.By modern radio spectrographs a wealth of not yet adequately classified spectral fine structures can be observed, some of them potentially intimately related to effects of fragmentation of flare energy and/or to processes related to coronal heating. Requirements for the choice of technical parameters of solar spectrographs for checking theoretical models of fundamental processes of energy release are reflected in modern instruments. Prospects for future observations are briefly included.     

Electrical conductivity measurements on olivines and pyroxenes under defined thermodynamic activities as a function of temperature and pressure

Electrical conductivities of Ni₂SiO₄, Fe₂SiO₄, and MgSiO₃ were measured on synthetic powders in the temperature range 340° to 1,100° C and at pressures up to 20 kbars. For ternary compounds such as olivines and pyroxenes the control of two further variables, like the chemical activities of two components are needed, besides temperature and pressure. The activities of the corresponding binary oxides were controlled by equilibrating the samples with their neighbour-phases. Control of the oxygen partial pressure was achieved by buffer techniques. From the slopes of the lg σ vs. 1/T lines the activation energies were calculated for 10 kbar: 0.56 eV and 2.7 eV for Ni₂SiO₄ in equilibrium with SiO₂ and Ni/NiO-buffer for the temperature range 500°–800°C and 800°–1,000°C resp. 0.52 eV for Fe₂SiO₄ in equilibrium with SiO₂ and metallic iron, and 0.38 eV in equilibrium with SiO₂ and magnetite; 1.11 eV for MgSiO₃ in equilibrium with SiO₂, and 1.25 eV in equilibrium with Mg₂SiO₄.     

Assessment of groundwater residence times in the pore aquifers of the River Elbe Basin

An area covering assessment of the groundwater residence times for the upper pore aquifers in the River Elbe Basin was performed. Residence times were determined by combining groundwater velocities and flow distances along each flow-path to the surface waters using a two-dimensional model approach. Groundwater velocity was calculated as a function of hydraulic conductivity, hydraulic gradient and effective yield of pore space. Flow paths were obtained by an analysis of the morphology of the groundwater table. The mean groundwater residence time in the pore aquifers of the River Elbe Basin was quantified to about 25 years. A strong temporal blurring in the different regions between less than one year and more than 250 years was obtained. For the regional groundwater management in the Elbe Basin the groundwater residence times are an important parameter, which helps to take into account the temporal dimension in the assessment of the impact of political measures aiming at the improvement of groundwater quality with regard to diffuse pollutants (e.g. nitrate).     

Cenomanian palaeotemperatures derived from the oxygen isotopic composition of brachiopods and belemnites: evaluation of Cretaceous palaeotemperature proxies

Sixty low-magnesium-calcite samples from Cenomanian articulate brachiopods, belemnites and oysters from the epicontinental shelf sea of Europe were geochemically and microscopically studied in order to evaluate their preservation and potential as carriers of palaeoenvironmental information. The sampled localities in northern Spain, Germany and southern England cover the transition between subtropical (25-30°N) and temperate (33-38°N) climates. Mean Cenomanian salinity-adjusted palaeotemperatures of diagenetically unaltered terebratulid and rhynchonellid brachiopods are 25.5ǃ.3 °C in Spain and 19.4ǃ.9 °C in southern England. The resulting low-to-mid-latitude meridional temperature gradient of ~0.7 °C per degree latitude is similar to the gradient today and suggests modern heat transport values for Cenomanian low latitudes. Oxygen isotopic composition of unaltered specimens of the Upper Cenomanian belemnite Praeactinocamax plenus (mean: 0.2‰) is enriched in ¹⁸O by 1‰ in comparison to brachiopod shells. Correspondingly, Upper Cenomanian palaeotemperatures derived from belemnite calcite (~13.0ǃ.3 °C) underestimate modelled mid-latitude sea surface temperatures by ~6 °C. Since P. plenus occurs as Boreal pulse fauna during a short interval in the Late Cenomanian, its heavy oxygen isotopic composition can be attributed either to migration from a cooler and/or deeper water mass or to unknown vital effects.     

Settlement History As Reflection Of Climate Change: The Case Study Of Lake Jues (Harz Mountains, Germany)

Postglacial sediments from Lake Jues, located at the SW margin of the Harz Mountains, were investigated for pollen, diatoms and sediment characteristics. The paper focuses on the time period between 7600 and 1200 y cal. BP (calibrated years before present), during which human impact began to influence the environnment of the lake. Climate variability was mainly inferred from sediment characteristics and changes in algal assemblages. The observed climatic changes coincide well with those recorded from other sites. Neolithic settlement started during the warm and dry Atlantic period. Intensive land use occurred under favourable climatic conditions during the Bronze and the Iron Ages, while human activities declined during cool and wet periods around 4000 and 2700 y cal. BP and after 2300 y cal. BP. The study shows that climate strongly influenced human settlement at remote locations like Lake Jues.     

Sea-level change, carbon cycling and palaeoclimate during the Late Cenomanian of northwest Europe; an integrated palaeoenvironmental analysis

A new high resolution sea-level curve for the Late Cenomanian M. geslinianum Zone has been generated using sequence stratigraphic analysis on transects through the margins of the Anglo-Paris Basin in the UK and Saxony Basin in Germany. Transgressive sediments that bury a rocky shoreline in the Dresden area have proved particularly useful in determining both the absolute amount of sea-level change and the rate of rise. After a brief fall at the base of the M. geslinianum Zone, sea level rose rapidly through the higher part of the zone, resulting in an overall short term eustatic rise of 22–28 m. Biostratigraphy and carbon isotope stratigraphy have enabled detailed correlations to be made between marginal locations and thick, relatively complete, basinal successions. The basinal successions at Eastbourne, UK, and Gröbern, Germany, provide both geochemical proxies for palaeoenvironmental change, including oxygen and carbon isotope records, and an orbital timescale graduated in precession and eccentricity cycles. Integration of the sea-level history with palaeoclimate evolution, palaeoceanography and changes in carbon cycling allows a detailed reconstruction of events during the Late Cenomanian. Orbital forcing on long eccentricity maxima provides the underlying drive for these changes, but amplification by tectonic events and feedback mechanisms augmented the orbital effects and made the Cenomanian/Turonian Boundary Event distinctive. In particular, variations in atmospheric CO₂ caused by oceanic drawdown and a brief period of intense volcanic outgassing resulted respectively in short term cooling and warming events. The magnitude and high rates (up to 1 m/1 kyr) of sea-level rise are diagnostic of glacioeustasy, however improbable this may appear at the height of the Cretaceous greenhouse.     

A mathematical magnetospheric field model with independent physical parameters

A quantitative magnetospheric magnetic field model has been calculated in three dimensions. The model is based on an analytical solution of the Chapman-Ferraro problem. For this solution, the magnetopause was assumed to be an infinitesimally thin discontinuity with given geometry. The shape of the dayside magnetopause is in agreement with measurements derived from spacecraft boundary crossings.The magnetic field of the magnetopause currents can be derived from scalar potentials. The scalar potentials result from solutions of Laplace's equation with Neumann's boundary conditions. The boundary values and the magnetic flux through the magnetopause are determined by all magnetic sources which are located inside and outside the magnetospheric cavity. They include the Earth's dipole field, the fields of the equatorial ring current and tail current systems, and the homogeneous interplanetary magnetic field. In addition, the flux through the magnetopause depends on two constants of interconnection which provide the possibility of calculating static interconnection between magnetospheric and interplanetary field lines. Realistic numerical values for both constants have been derived empirically from observed displacements of the polar cusps which are due to changes in the orientation of the interplanetary field. The transition from a closed to an open magnetosphere and vice versa can be computed in terms of a change of the magnetic boundary conditions on the magnetopause. The magnetic field configuration of the closed magnetosphere is independent of the amount and orientation of the interplanetary field. In contrast, the configuration of the open magnetosphere confirms the observational finding that field line interconnection occurs primarily in the polar cusp and high latitude tail regions.The tail current system reflects explicitly the effect of dayside magnetospheric compression which is caused by the solar wind. In addition, the position of the plasma sheet relative to the ecliptic plane depends explicitly on the tilt angle of the Earth's dipole. Near the tail axis, the tail field is approximately in a self-consistent equilibrium with the tail currents and the isotropic thermal plasma.The models for the equatorial ring current depend on the D_st-parameter. They are self-consistent with respect to measured energy distributions of ring current protons and the axially symmetric part of the magnetospheric field.     

Influence of subsolidus processes on the chromium number in spinel in ultramafic rocks

The chromium number of spinel Cr#^sp (atomic ratio of Cr/(Cr+Al)) is an important geochemical parameter for the estimation of the degree of partial melting, temperatures, and provenance in peridotites. In this study, a model has been developed in order to determine the effect of subsolidus reactions on the Cr#^sp in ultramafic rocks. The final model includes temperature-dependent distribution coefficients of relevant reactions as well as solubility data and has been applied to lithologies common in mid-ocean ridge settings. Significant changes in the Cr#^sp are predicted from the application of this model during cooling from 1300 to 800°C at mantle pressures. For spinel lherzolites and harzburgites, the Cr#^sp is predicted to decrease proportional to the absolute values of the Cr#^sp at (constantly) increasing spinel mass. Cpx-dunites show the same trend, although to a lower extent. Websterites show a different behavior with a slight increase in the Cr#^sp due to their lack of olivine. Modal abundance of spinel correlates with the magnitude in Cr#^sp change, too. Finally, these results were tested for possible effects on the calculated degree of partial melting as function of the Cr#^sp. Application of the Cr#^sp from a peridotite equilibrated down to 800°C would result in an underestimation of only 1.5 % in the degree of melting, justifying the use of Cr#^sp for estimations of this parameter.     

Calcium isotope record of Phanerozoic oceans: Implications for chemical evolution of seawater and its causative mechanisms

A total of 280 brachiopods of Ordovician to Cretaceous age, complemented by published data from belemnites and planktonic foraminifera, are used to reconstruct the evolution of calcium isotope composition of seawater (δ^44/40Ca_SW) over the Phanerozoic. The compiled δ^44/40Ca_SW record shows a general increase from ∼1.3‰ (NIST SRM 915a) at the beginning of the Ordovician to ∼2‰ at present. Superimposed on this trend is a major long-term positive excursion from the Early Carboniferous to Early Permian as well as several short-term, mostly negative, oscillations.A numerical model of the global cycles of calcium, carbon, magnesium and strontium was used to estimate whether the recorded δ^44/40Ca_SW variations can be explained by varying magnitudes of input and output fluxes of calcium to the oceans. The model uses the record of marine ⁸⁷Sr/⁸⁶Sr ratios as proxy for seafloor spreading rates, a record of oceanic Mg/Ca ratios to estimate rates of dolomite formation, and reconstructed atmospheric CO₂, discharge and erosion rates to estimate continental weathering fluxes.The model results indicate that varying magnitudes of the calcium input and output fluxes cannot explain the observed δ^44/40Ca_SW trends, suggesting that the isotope signatures of these fluxes must also have changed. As a possible mechanism we suggest variable isotope fractionation in the sedimentary output flux controlled by the dominant mineralogy in marine carbonate deposits, i.e. the oscillating ‘calcite-aragonite seas’. The ultimate control of the calcium isotope budget of the Phanerozoic oceans appears to have been tectonic processes, specifically variable rates of oceanic crust production that modulated the hydrothermal calcium flux and the oceanic Mg/Ca ratio, which in turn controlled the dominant mineralogy of marine carbonates, hence the δ^44/40Ca_SW. As to the causes of the short-term oscillations recorded in the secular δ^44/40Ca_SW trend, we tentatively propose that these are related to variable rates of dolomite formation and/or to changing chemical composition of the riverine flux, in particular and ratios, induced by variable proportions of silicate vs. carbonate weathering rates on the continents.