A New Method for Low‐Temperature Decomposition of Chromites and Dichromium Trioxide using Bromic Acid Evaluated by Chromium Isotope Measurements

In recent years, routine application of the stable isotope determination of chromium (Cr) in environmental and health protection research has led to the search for simpler chromite decomposition techniques. As the range of Cr isotope abundance ratios in nature is very narrow, conventional chromite decomposition techniques are no longer suitable, due to the relatively high risk of contamination during laboratory procedures. We have developed a protocol for the decomposition of chromites based on oxidation by bromic acid at room temperature. The procedure takes 15 d and requires two doses of bromic acid during the reaction period (day 1 and 8), due to the limited stability of the reagent. Chromium extracted by alkaline oxidative fusion and by bromic acid decomposition yielded statistically indistinguishable δ⁵³Cr values, measured by multi‐collector inductively coupled plasma‐mass spectrometry following addition of a ⁵⁰Cr‐⁵⁴Cr double‐spike.     

Boundaries of mantle–lithosphere domains in the Bohemian Massif as extinct exhumation channels for high-pressure rocks

Five domains (microplates) have been recognized by seismic anisotropy in the mantle lithosphere of the Bohemian Massif. The mantle domains correspond to major crustal units and each of the domains bears a consistent fossil olivine fabric formed before their Variscan assembly. The present-day mantle fabric indicates that this process consisted of at least three oceanic subductions, each followed by an underthrusting of the continental lithosphere. The seismic anisotropy does not detect remnants of the oceanic subductions, but it can trace boundaries of the preserved continental domains subsequently underthrust along the paths of previous oceanic subductions. The most robust continent–continent collision was followed by westward underthrusting of the Brunovistulian mantle lithosphere, still detectable by seismic anisotropy more than 100 km beneath the Moldanubian mantle lithosphere. Major occurrences of the high-pressure/ultra high-pressure (HP–UHP) rocks follow the ENE and NNE oriented sutures and boundaries of the mantle–lithosphere domains mapped from three-dimensional modeling of body-wave anisotropy. The HP–UHP rocks are products of oceanic subductions and the following underthrusting of the continental crust and mantle lithosphere exhumed along the mantle boundaries. The close relation of the mantle sutures and occurrences of the HP–UHP rocks near the paleosubductions testifies for models interpreting the granulite–garnet peridotite association by oceanic/continental subduction/underthrusting followed by the exhumation of deep-seated rocks. Our findings support the bivergent subduction model of tectonic development of the central part of the Bohemian Massif. The inferences from seismic anisotropy image the Bohemian Massif as a mosaic of microplates with a rigid mantle lithosphere preserving a fossil olivine fabric. The collisional mantle boundaries, blurred by tectonometamorphic processes in easily deformed overlying crust, served as major exhumation channels of the HP–UHP rocks.     

Lithogenic thallium behavior in soils with different land use

In order to evaluate the effect of different land use on lithogenic Tl geochemistry, two forest and grassland soils developed on an identical Tl-rich substrate were examined. For this purpose a complex soil-plant investigation supplemented by mineralogical methods was performed. The modified BCR sequential extraction combined with X-ray diffraction analysis (XRD) and voltammetry of microparticles (VMP) were performed for a detailed insight on lithogenic Tl speciation and availability in both contrasting soils. It was revealed that soil forming processes like bioturbation and probably dust deposition may influence the increased input of lithogenic Tl into the forest floor. Thallium was predominantly bound within the residual fraction (up to 95%) corresponding to primary silicates (mainly orthoclase and muscovite) and probably secondary illite, which were detected by XRD in all studied horizons. Thus, stable silicates can be thought as the phases controlling the solubility of lithogenic Tl in both the forest and grassland soils. The highest portion (~ 5%) of “labile” Tl was found in the organic horizons of the forest soil indicating a distinct role of forest soil organic matter (SOM) on Tl mobilization and availability. Thallium adsorption was dominated by an identified non-crystalline Mn(III,IV) oxide detected by VMP proving thus its strong affinity for Mn oxides in mineral soils. On the contrary, Tl adsorption by more abundant Fe(III) oxides (goethite and ferrihydrite) was evaluated to be negligible. Organically bound Tl in the forest floor was found to be associated with primary SOM corresponding to the raw and partially decomposed litter of Norway spruce (Picea abies L.). Moreover, a relatively high Tl uptake was recorded by this species. In contrast, lithogenic Tl uptake by common grasses like red clover (Trifolium pratense L.) or timothy grass (Phleum pratense L.) seems to be very low.     

On the circular Sitnikov problem: the alternation of stability and instability in the family of vertical motions

This paper is devoted to the special case of the restricted circular three-body problem, when the two primaries are of equal mass, while the third body of negligible mass performs oscillations along a straight line perpendicular to the plane of the primaries (so called periodic vertical motions). The main goal of the paper is to study the stability of these periodic motions in the linear approximation. A special attention is given to the alternation of stability and instability within the family of periodic vertical motions, whenever their amplitude is varied in a continuous monotone manner.     

Surface Miners: Evaluation of the Production Rate and Cutting Performance Based on Rock Properties and Specific Energy

The purpose of this research was to evaluate the production rate (PR) and cutting performance of surface miners (SM) based on rock properties and specific energy (SE). We use data from equipment manufacturers and experimental data in this study and propose a new method and equations to determine both the PR and the cutting speed of SM. The unconfined compressive strength (UCS) of the rock, its abrasivity, and the machine’s engine power are the three most important factors influencing the PR. Moreover, the cutting depth, UCS, and engine power have a significant impact on the cutting speed. We propose a new method and equations to determine the energy required to cut a volume unit and a surface unit, i.e., specific energy, and establish the relationship between SE, UCS, and PR. The results of this study can be used by surface miner operators to evaluate the applicability of the machines to a specific mine site.     

Distribution of thallium and accompanying metals in tree rings of Scots pine (Pinus sylvestris L.) from a smelter-affected area

Distribution of Tl, Zn, Cd, Pb, K, Ca, Mg and Mn and Pb isotopic composition in tree rings of Scots pine (Pinus sylvestris L.) from an area affected by primary Zn smelting (Olkusz, southern Poland) were investigated. Elevated concentrations of Tl (up to 0.8 mg kg⁻¹) in pine trees imply that conifers tend to accumulate this metal to some extent. A generally positive relationship between soil and tree-ring Tl levels was identified. The Tl patterns in stem wood did not correspond to changes in Tl deposition; the lateral translocation of Tl in the sapwood and its accumulation at the sapwood-heartwood boundary (i.e., in the inner sapwood) is suggested. It is probable that the specific behavior of Tl in trees results from its biogeochemical analogy with K. In contrast, tree-ring patterns of Zn and Cd significantly correlated with their deposition; nevertheless, a partial shift of these metals towards the stem center cannot be excluded. The isotopic composition of Pb (²⁰⁶Pb/²⁰⁷Pb ~ 1.172–1.184) in trees and underlying soils revealed the predominant influence of smelter emissions (²⁰⁶Pb/²⁰⁷Pb ~ 1.17) on Pb contamination. Analysis of main nutrients (Ca, Mg and Mn) in wood reflected environmental changes related to acid deposition.     

Mean-field equations for weakly nonlinear two-scale perturbations of forced hydromagnetic convection in a rotating layer

We consider stability of regimes of hydromagnetic thermal convection in a rotating horizontal layer with free electrically-conducting boundaries, to perturbations involving large spatial and temporal scales. Equations governing the evolution of weakly nonlinear mean perturbations are derived under the assumption that the α-effect is insignificant in the leading-order (e.g. due to a symmetry of the system). The mean-field equations generalise the standard equations of hydromagnetic convection: New terms emerge – a second-order linear operator representing the combined eddy diffusivity and quadratic terms associated with the eddy advection. If the perturbed CHM regime is nonsteady and insignificance of the α-effect in the system does not rely on the presence of a spatial symmetry, the combined eddy diffusivity operator also involves a nonlocal pseudodifferential operator. If the perturbed CHM state is almost symmetric, α-effect terms appear in the mean-field equations as well. Near a point of a symmetry-breaking bifurcation, cubic nonlinearity emerges in the equations. All the new terms are in general anisotropic. A method for evaluation of their coefficients is presented; it requires solution of a significantly smaller number of auxiliary problems than in a straightforward approach.     

Three-dimensional velocity model of the crust of the Bohemian Massif and its effects on seismic tomography of the upper mantle

We have compiled a representative three-dimensional P-velocity model of the crust of the Bohemian Massif (BM) to provide a basis for removing effects of the crustal structure in teleseismic tomography of the upper mantle. The model is primarily based on recently published 2D velocity models from findings of wide-angle refraction and near-vertical reflection seismic profiles of CELEBRATION 2000, ALP 2002, and SUDETES 2003 experiments. The best fitting 3D model of the BM crust (NearNeighbour model) is complemented by velocities according to the reference Earth model at sites where data are sparse, which precludes creating artificial heterogeneities that are products of interpolation method. To test the model, we have performed tomographic inversions of the P-wave travel times measured during the BOHEMA II experiment and compared the results obtained with and without crustal corrections. The tests showed that the presented crustal model decreases magnitudes of velocity perturbations leaking from the crust to the mantle in the western part of the BM. The tomographic images also indicated a highvelocity anomaly in the lower crust or just beneath the crust in the Brunovistullian unit. Such anomaly is not described by our model of the crust since no seismic profile intersects this part of the unit. The tests also indicated that crustal corrections are of the great importance especially for interpretations of the uppermost mantle down to depths of about 100 km.     

Global Crust-Mantle Density Contrast Estimated from EGM2008, DTM2008, CRUST2.0, and ICE-5G

We compute globally the consolidated crust-stripped gravity disturbances/anomalies. These refined gravity field quantities are obtained from the EGM2008 gravity data after applying the topographic and crust density contrasts stripping corrections computed using the global topography/bathymetry model DTM2006.0, the global continental ice-thickness data ICE-5G, and the global crustal model CRUST2.0. All crust components density contrasts are defined relative to the reference crustal density of 2,670 kg/m³. We demonstrate that the consolidated crust-stripped gravity data have the strongest correlation with the crustal thickness. Therefore, they are the most suitable gravity data type for the recovery of the Moho density interface by means of the gravimetric modelling or inversion. The consolidated crust-stripped gravity data and the CRUST2.0 crust-thickness data are used to estimate the global average value of the crust-mantle density contrast. This is done by minimising the correlation between these refined gravity and crust-thickness data by adding the crust-mantle density contrast to the original reference crustal density of 2,670?kg/m³. The estimated values of 485 kg/m³ (for the refined gravity disturbances) and 481?kg/m³ (for the refined gravity anomalies) very closely agree with the value of the crust-mantle density contrast of 480?kg/m³, which is adopted in the definition of the Preliminary Reference Earth Model (PREM). This agreement is more likely due to the fact that our results of the gravimetric forward modelling are significantly constrained by the CRUST2.0 model density structure and crust-thickness data derived purely based on methods of seismic refraction.     

Spatial and Spectral Analysis of Refined Gravity Data for Modelling the Crust–Mantle Interface and Mantle-Lithosphere Structure

We analyse spatial and spectral characteristics of various refined gravity data used for modelling and gravimetric interpretation of the crust–mantle interface and the mantle-lithosphere structure. Depending on the purpose of the study, refined gravity data have either a strong or weak correlation with the Moho depths (Moho geometry). The compilation of the refined gravity data is purely based on available information on the crustal density structure obtained from seismic surveys without adopting any isostatic hypothesis. We demonstrate that the crust-stripped relative-to-mantle gravity data have a weak correlation with the CRUST2.0 Moho depths of about 0.02. Since gravitational signals due to the crustal density structure and the Moho geometry are subtracted from gravity field, these refined gravity data comprise mainly the information on the mantle lithosphere and sub-lithospheric mantle. On the other hand, the consolidated crust-stripped gravity data, obtained from the gravity field after applying the crust density contrast stripping corrections, comprise mainly the gravitational signal of the Moho geometry, although they also contain the gravitational signal due to anomalous mass density structures within the mantle. In the absence of global models of the mantle structure, the best possible option of computing refined gravity data, suitable for the recovery/refinement of the Moho interface, is to subtract the complete crust-corrected gravity data from the consolidated crust-stripped gravity data. These refined gravity data, that is, the homogenous crust gravity data, have a strong absolute correlation of about 0.99 with the CRUST2.0 Moho depths due to removing a gravitational signal of inhomogeneous density structures within the crust and mantle. Results of the spectral signal decomposition and the subsequent correlation analysis reveal that the correlation of the homogenous crust gravity data with the Moho depths is larger than 0.9 over the investigated harmonic spectrum up to harmonic degree 90. The crust-stripped relative-to-mantle gravity data correlate substantially with the Moho depths above harmonic degree 50 where the correlation exceeds 0.5.