Statistical Classification of Different Petrographic Varieties of Aggregates by Means of Near and Mid Infrared Spectra

The increasing interest of the construction aggregates industry in reducing production costs and the costs resulting from improper use of construction materials leads to the question whether it is possible to statistically identify some rock variants by their reflectivity of near-infrared and mid-infrared light. Infrared spectroscopy allows quantitative and qualitative analysis of minerals in a reliable manner, whereas the classification of rocks is complicated by the fact that the optic behavior of minerals forming the rock often appears muted. In addition, minor constituents may dominate the spectrum. Furthermore the relevant spectra form high dimensional data, which are extremely difficult to analyse statistically, especially when curves are very similar. Common methods of multivariate statistics for this type of data, used in chemometric studies, followed by linear discriminant analysis, do not lead to acceptable classification error rates. In this paper wavelets are used in order to reduce dimensionality. As wavelets are better able to mirror local behavior of curves, they are more suitable for selecting characteristic features. The approximation is analyzed in terms of its classification properties using Mahalanobis distance or flexible discriminant analysis.     

What is a forest? Competing meanings and the politics of forest classification in Thung Yai Naresuan Wildlife Sanctuary, Thailand

Based on a case study in a Thai forest reserve, this article compares two modes of ‘reading’ the forest - official and local forest classification systems - and discusses how they imply different ideas about the forest, and how these competing knowledges interact with the politics of forest governance. Forest classification conventions are shown to slip, as ‘facts’ about the forest, from their origins in extraction-oriented forestry to the realm of conservation. Through a comparison of conventional vegetation classifications used in the state’s governance of the Thung Yai Naresuan Wildlife Sanctuary in Thailand, with the classificatory systems of resident Pwo Karen communities, this paper examines the slippage of conventional classifications through various uses and the emphases placed by competing representations of the forest within the context of conservation politics in Thailand. It was found that conventional classifications continued to prioritise the silvicultural potential of trees within a conservation context, downplaying other notions of forests - such as their importance to livelihoods and as lived spaces - which are present in Karen classifications.     

Living Shorelines Support Nearshore Benthic Communities in Upper and Lower Chesapeake Bay

Human population growth and sea-level rise are increasing the demand for protection of coastal property against shoreline erosion. Living shorelines are designed to provide shoreline protection and are constructed or reinforced using natural elements. While living shorelines are gaining popularity with homeowners, their ability to provide ecological services (e.g., habitat provision and trophic transfer) is not well understood, and information is needed to improve coastal and resource management decision-making. We examined benthic community responses to living shorelines in two case-study subestuaries of Chesapeake Bay using a before-after control-impact study design. At Windy Hill, a bulkhead was removed and replaced by three tombolos, sand fill, and native marsh vegetation. At Lynnhaven, 25 m of eroding marsh shoreline was stabilized with coir logs, sand fill, and native marsh vegetation. Communities of large (>?3 mm) infauna adjacent to living shorelines at both locations tended to increase in biomass by the end of the study period. Community compositions changed significantly following living shoreline construction at Windy Hill, reflecting a trend toward higher density and biomass of large bivalves at living shorelines compared to pre-construction. Increasing trends in density and biomass of clams and simultaneously decreasing density and decreasing trends in biomass of polychaetes suggest a transition toward stable infaunal communities at living shorelines over time, though longer-term studies are warranted.     

Stability of Titanium Dioxide Nanoparticle Agglomerates in Transitional Waters and Their Effects Towards Plankton from Lagoon of Venice (Italy)

The present study explores the effect of salinity and dissolved organic carbon (DOC) gradients on the stability and reactivity of titanium dioxide nanoparticle (TiO₂-NP) agglomerates in ambient water from the Lagoon of Venice and their possible effect on nauplii sampled at the same locations. In all ambient water samples, TiO₂-NPs formed rapidly micrometre-sized agglomerates. The increase in the salinity and concomitant decrease in DOC content induced the formation of larger agglomerates, with z-average hydrodynamic diameter increasing with TiO₂-NP concentration and exposure duration. Under the studied conditions, ζ-potential exhibited negative values. In line with agglomeration results, enhancement of the salinity and lower DOC resulted in less negative ζ-potential with close to 0 values in the dispersions of 100 mg L^?1 TiO₂-NPs in sea water. Two-hour exposure to micrometre-sized agglomerates of TiO₂-NPs resulted in an increase in the fluorescence of propidium iodide (PI) stained nauplii in comparison with unexposed controls, but had no effect at 24-h exposure. The increase in nauplii-associated PI fluorescence was more noticeable in dispersions containing 100 mg L^?1 than those containing 10 mg L^?1 TiO₂-NPs, suggesting membrane permeability alteration in a concentration-dependent manner. However, the PI staining results have to be interpreted with caution because of the possible dye binding to the nauplii surface without penetration of cellular membrane. The effect of TiO₂-NPs on nauplii was more pronounced at higher salinity and decreased with increasing DOC concentrations at 2 h, while no trends were found at 24-h exposure, as well as exposure to 100 mg L^?1 TiO₂-NPs.     

Modification of the Natural Slake Test and Assessment of Slaking Behavior of a Shale from Malaysia Under Rainfall

Geotechnical and Geological Engineering - The durability of clay-bearing rocks has been a concern to the construction industry. Extensive research have been conducted to determine the durability of...     

Commingled Fluids in Abandoned Boreholes: Proximity Analysis of a Hidden Liability

The interactions between old abandoned wellbores of suspect well integrity with hydraulic fracturing (HF), enhanced oil recovery (EOR), or salt water disposal (SWD) operations can result in upward leakage of deep aqueous liquids into overlying aquifers. This potential for upward fluid migration is largely unquantified as monitoring abandoned wells is rarely done, and leakage may go unnoticed especially when in deeper aquifers. This study performs a proximity analysis between old abandoned wells and HF, EOR, and SWD wells, and identifies commingled old abandoned wellbores, which are those wells where groundwater may flow from one aquifer to one or more other aquifers, to identify the locations with the greatest potential for upward aqueous fluid migration at three study sites in the Western Canadian Sedimentary Basin. Our analysis indicates that at all three study sites there are several locations where HF, EOR, or SWD operations are located in close proximity to a given old abandoned well. Much of this overlap occurs in formations above typically produced hydrocarbon reservoirs but below exploited potable aquifers, otherwise known as the intermediate zone, which is often connected between abandonment plugs in old abandoned wells. Information on the intermediate zone is often lacking, and this study suggests that unanticipated alterations to groundwater flow systems within the intermediate zone may be occurring. Results indicate the need for more field-based research on the intermediate zone.     

The role of experimental work in hydrological sciences – insights from a community survey

This opinion paper summarizes the results of an online survey on the role of experimental work in the hydrological sciences. The 20 survey questions covered various topics, such as advancements, needs, potentials and challenges in the hydrological sciences, and also touched on the issue of data sharing and data publication. A total of 336 hydrologists with both modelling and experimental backgrounds participated.     

Seafloor change detection using multibeam echosounder backscatter: case study on the Belgian part of the North Sea

To characterize seafloor substrate type, seabed mapping and particularly multibeam echosounding are increasingly used. Yet, the utilisation of repetitive MBES-borne backscatter surveys to monitor the environmental status of the seafloor remains limited. Often methodological frameworks are missing, and should comprise of a suite of change detection procedures, similarly to those developed in the terrestrial sciences. In this study, pre-, ensemble and post-classification approaches were tested on an eight km² study site within a Habitat Directive Area in the Belgian part of the North Sea. In this area, gravel beds with epifaunal assemblages were observed. Flourishing of the fauna is constrained by overtopping with sand or increased turbidity levels, which could result from anthropogenic activities. Monitoring of the gravel to sand ratio was hence put forward as an indicator of good environmental status. Seven acoustic surveys were undertaken from 2004 to 2015. The methods allowed quantifying temporal trends and patterns of change of the main substrate classes identified in the study area; namely fine to medium homogenous sand, medium sand with bioclastic detritus and medium to coarse sand with gravel. Results indicated that by considering the entire study area and the entire time series, the gravel to sand ratio fluctuated, but was overall stable. Nonetheless, when only the biodiversity hotspots were considered, net losses and a gradual trend, indicative of potential smothering, was captured by ensemble and post-classification approaches respectively. Additionally, a two-dimensional morphological analysis, based on the bathymetric data, suggested a loss of profile complexity from 2004 to 2015. Causal relationships with natural and anthropogenic stressors are yet to be established. The methodologies presented and discussed are repeatable and can be applied to broad-scale geographical extents given that broad-scale time series datasets become available.     

Empirical prediction of the ground shaking scenario for the Catania area

Simplified approaches for prediction of strong ground shaking, that can be efficiently implemented through a Geographical Information System (GIS), are applied to constructing earthquake scenarios for the Catania municipal area. Ground shaking maps in terms of peak ground acceleration and response spectral ordinates are developed both for a repetition of the catastrophic 1693 earthquake (M7.3), and for a lower energy event, like that which occurred in 1818 (M6.2). The maps account for amplification due to local site conditions. According to the commonly used attenuation relations, the local amplification is taken into account either in a simpler way or in a more detailed approach, derived from an extensive geotechnical zonation. The approximation introduced by the simpler methodology, to be used whenever accurate data are not available, is estimated by a comparison with damage distribution.