Permeability changes in layered sediments: impact of particle release

One of the mechanisms of sudden particle release from grain surfaces in natural porous media is a decrease in salt concentration of the permeating fluid to below the critical salt concentration. Particle release can cause a change in hydraulic conductivity of the matrix, either by washing out the fines and thus increasing the pore sizes or by the plugging of pore constrictions. The phenomenon of permeability changes as a result of particle detachment was investigated in a series of column experiments. Coarse and fine sediments from the Hanford Formation in southeast Washington were tested. Columns were subject to a pulse of highly saline solution (NaNO3) followed by a fresh water shock causing particle release. Outflow rates and changes in hydraulic head as well as electric conductivity and pH were monitored over time. No permeability decrease occurred within the coarse matrix alone. However, when a thin layer of fine sediment was embedded within the coarse material (mimicking field conditions at the Hanford site), permeability irreversibly decreased to 10% to 20% of the initial value. Evidence suggests that most of this permeability decrease was a result of particles detached within the fine layer and its subsequent clogging. An additional observation was a sudden increase in pH in the outflow solution, generated in situ during the fresh water shock. Because layered systems are common in natural settings, our results suggest that alteration between sodium solution and fresh water can lead to particle release and subsequently reduce the overall permeability of the matrix.     

The Role of Data Processing and Uncertainty Management in Seismic Hazard Evaluations: Insights from Estimates in the Garfagnana–Lunigiana Area (Northern Italy)

Significantly different estimates of seismic hazard may result for the same site as aneffect of different methodological choices underlying the adopted procedures. In orderto explore this aspect, two approaches devoted to probabilistic seismic hazard assessment are considered for the evaluation of hazard in a seismic area in Northern Italy. In particular, results of a standard procedure are compared with those obtained by an innovative approach. Fundamental features of this last methodology are the extensive use of intensity data relative to seismic effects observed at the site of interest during past earthquakes and the basic role attributed to the parameterisation of uncertainty which affects the considered pieces ofinformation. The analysis indicates that the new approach supplies results significantlydifferent from those obtained from standard methodology and that these differences strongly depend on strategies adopted for data processing and for the management of uncertainties which affect input parameters.     

BLU Estimators and Compositional Data

One of the principal objections to the logratio approach for the statistical analysis of compositional data has been the absence of unbiasedness and minimum variance properties of some estimators: they seem not to be BLU estimator. Using a geometric approach, we introduce the concept of metric variance and of a compositional unbiased estimator, and we show that the closed geometric mean is a c-BLU estimator (compositional best linear unbiased estimator with respect to the geometry of the simplex) of the center of the distribution of a random composition. Thus, it satisfies analogous properties to the arithmetic mean as a BLU estimator of the expected value in real space. The geometric approach used gives real meaning to the concepts of measure of central tendency and measure of dispersion and opens up a new way of understanding the statistical analysis of compositional data.     

Elliptical boundary of an intraplate volcanic field, Auckland, New Zealand

The outer vents in the Auckland Volcanic Field lie within 19 to 559 m (mean 224.75 m) of a ‘best-fit' ellipse with a 28.9-km-long major axis trending almost north–south, and a minor axis 16.5 km long. The ellipse has formed the outer boundary of the field since the inception of volcanism 140,000 years ago. We present the following testable hypotheses as an explanation of this pattern: The boundary is the expression of a corresponding elliptical source area at depth in the lithospheric mantle (possibly asthenosphere material trapped at this level). The ellipse may represent a depth contour on a very small upper mantle dome or of a lens intruding into a neck of an extensional structure. Alternatively it could be the boundary of a flat elliptical area where tensional stresses allow decompressional melting. The elliptical tensional region may either have developed in a releasing bend during strike-slip faulting along a fundamental lithosphere structure inherited from Mesozoic tectonics, associated with the NNW-trending Dun Mountain ophiolite belt, or may represent the tip of a fracture along which the Auckland Volcanic Province is propagating northward.     

Genesis of sulfide-rich chromite ores by the interaction between chromitite and pegmatitic olivine–norite dikes in the Potosí Mine (Moa-Baracoa ophiolitic massif, eastern Cuba)

The Potosí Mine is located in the Moa-Baracoa massif in the easternmost part of the Cuban Ophiolitic Belt. Chromite mineralization occurs within the mantle-crust transition zone. Two events of magma intrusion overprint the chromitite bodies: one gave rise to the crystallization of pegmatitic olivine-norite dikes, and the other produced pegmatitic gabbro dikes. Sulfide-poor chromite ores, brecciated chromite ores, and sulfide-rich chromite ores can be distinguished in the different chromitite bodies. Sulfide-poor ores represent more than 80 vol% of the chromitites. This type occurs far from the zones intruded by pegmatitic gabbro dikes and shows petrographic and chemical features similar to other chromitite bodies described in the Moa-Baracoa massif. Brecciated chromite ores occur within pegmatitic gabbro dikes. In this type, chromite crystals occur included within chromian diopside and plagioclase. These silicates often contain droplet-like sulfide aggregates. Sulfide-rich ores are spatially associated to the contacts between sulfide-poor chromite and pegmatitic olivine-norite dikes. These ores mainly consist of recrystallized (coarse) chromite with interstitial pyrrhotite, pentlandite, cubanite, and chalcopyrite. Chromite from sulfide-rich ores exhibits TiO₂, FeO, V₂O₃, MnO, and especially, Fe₂O₃ contents, higher than those of chromite from brecciated ores and much higher than those of chromite from sulfide-poor ores. The sulfide-rich ores are PGE-rich (up to 1,113 ppb of total PGE), and show nearly flat chondrite-normalized PGE patterns, slightly above 0.1 times chondritic values. Mineralogical and chemical data indicate that the chromite ores of the Potosí Mine were modified by the intrusions of olivine-norite and gabbro dikes. The interaction between pre-existing sulfide-poor chromite ores and the intruding volatile-rich silicate melts produced strong brecciation, partial dissolution, and recrystallization (coarsening) of chromite. The sulfide assemblage formed by fractionation of the immiscible sulfide melt segregated from the volatile-rich silicate melt that generated the pegmatitic olivine-norite. The segregation of the sulfide melt can be interpreted as the consequence of chemical interaction between intruding melts and the host chromite. The variable extent of this interaction produced chromite ores with variable sulfide ratios. The magmatic nature of the sulfide mineralization is supported by sulfur isotope data, which range from -0.4 to +0.9‰. Sulfide melt collected incompatible PGE (Rh, Pt, Pd) to produce the typical flat chondrite-normalized pattern of sulfide-rich chromite ores.     

Sedimentation processes in an impoundment,Union lake,New Jersey

A small (3 75 km²) impoundment. Union Lake, on the Maurice River in southern New Jersey contains fine-grained sediment and organic material being transported through the surface water system Sedimentation is slow and rates calculated from¹³⁷Cs-dated cores indicate a decrease through time from 2 6 mm/yr to 0 57 mm/yr Sediment from shallow areas (<3 m) consists of winnowed preimpoundment fluvial sand, whereas sediment from deeper areas (>3 m) is dy composed of diatoms, organic matter, and silt- and clay-sized mineral grains Sediment distribution is controlled by water moving from the river entrance southward toward the outlet and by wind-generated water motion from shallow areas fringing the shore toward deeper portions of the impoundment     

Vertical distribution of phytoplankton in a stratified estuary

We present a fine vertical distribution of physico-chemical parameters and phytoplankton density around the halocline (freshwater/seawater interface) in the Krka estuary on the East coast of the Adriatic Sea. Suspended matter, surfactant activity, surface active aggregates, particulate organic carbon and phaeophytin all show largest concentrations in the 20–50 cm thick interface layer. The highest concentration of chlorophyll-a is found on the upper boundary of the interface and it is a consequence of majority of viable freshwater phytoplankton cells that accumulate there. The phytoplankton accumulates selectively in the interface: larger size fractions accumulate faster than smaller ones. In particular, nanoplanakton accumulates the least. The visible interface is also populated by dead phytoplankton cells. Most of the freshwater phytoplankton dies and decomposes in the interface, as revealed by a small chlorophyll-a/phaeophytin ratio, and it represents the main source of surface active dissolved and particulate organic matter. Marine flagellates migrate and divide in the interface, while some species likeProrocentrum micans andSyracosphera sp. are also found in the upper freshwater layer.