Efficacy of Coagulants and Ballast Compounds in Removal of Cyanobacteria (<Emphasis Type="Italic">Microcystis</Emphasis>) from Water of the Tropical Lagoon Jacarepaguá (Rio de Janeiro,Brazil)

Eutrophication is considered the most important water quality problem in freshwaters and coastal waters worldwide promoting frequent occurrence of blooms of potentially toxic cyanobacteria. Removal of cyanobacteria from the water column using a combination of coagulant and ballast is a promising technique for mitigation and an alternative to the use of algaecides. In laboratory, we tested experimentally the efficiency of two coagulants, polyaluminium chloride (PAC) and chitosan (made of shrimp shells), alone and combined with two ballasts: red soil (RS) and the own lagoon sediment, to remove natural populations of cyanobacteria, from an urban brackish coastal lagoon. PAC was a very effective coagulant when applied at low doses (≤8 mg Al L^?1) and settled the cyanobacteria, while at high doses (≥16 mg Al L^?1) large flocks aggregated in the top of test tubes. In contrast, chitosan was not able to form flocks, even in high doses (>16 mg L^?1) and did not efficiently settle down cyanobacteria when combined with ballast. The RS itself removed 33–47 % of the cyanobacteria. This removal was strongly enhanced when combined with PAC in a dose-dependent matter; 8 mg Al L^?1 was considered the best dose to be applied. The lagoon sediment alone did not promote any settling of cyanobacteria but removal was high when combined with PAC. Combined coagulant and ballast seems a very efficient, cheap, fast and safe curative measure to lessen the harmful cyanobacteria bloom nuisance in periods when particularly needed, such as around the 2016 Olympics in Jacarepaguá Lagoon.     

Zinc-rich and copper-bearing amphiboles from sulfide-free ore occurrences of the Pelagonian Massif,Republic of North Macedonia

Mineralogy and Petrology - This paper describes specific features of isomorphism of unusual amphiboles containing up to 23&nbsp;wt% ZnO and up to 1.3&nbsp;wt% CuO from sulfide-free...     

Kriging Regionalized Positive Variables Revisited: Sample Space and Scale Considerations

Frequently, regionalized positive variables are treated by preliminarily applying a logarithm, and kriging estimates are back-transformed using classical formulae for the expectation of a lognormal random variable. This practice has several problems (lack of robustness, non-optimal confidence intervals, etc.), particularly when estimating block averages. Therefore, many practitioners take exponentials of the kriging estimates, although the final estimations are deemed as non-optimal. Another approach arises when the nature of the sample space and the scale of the data are considered. Since these concepts can be suitably captured by an Euclidean space structure, we may define an optimal kriging estimator for positive variables, with all properties analogous to those of linear geostatistical techniques, even for the estimation of block averages. In this particular case, no assumption on preservation of lognormality is needed. From a practical point of view, the proposed method coincides with the median estimator and offers theoretical ground to this extended practice. Thus, existing software and routines remain fully applicable.     

Influence of a permeable sand layer on the mechanism of backward erosion piping using 3D pipe depth measurements

Backward erosion piping (BEP) poses a threat to the stability of water-retaining structures. This can lead to severe erosion and collapse of embankments. A novel economically appealing measure against BEP is the coarse sand barrier (CSB). The CSB is a trench filled with coarse sand that is placed below the blanket layer on the landward side of the embankment, which prevents the pipe from developing upstream when it encounters the CSB. Inclusion of a CSB creates a vertically layered sand, which is the situation that can also exist in practice but is different from traditional BEP tests with one homogeneous sand. This paper presents new observations and measurements in medium-scale laboratory tests. 3D measurements of the pipe depth and dimensions are presented and analysed. This analysis indicates how the pipe dimensions evolve during the piping process and shows the erosion mechanism for BEP in vertically layered sands. The findings demonstrate the significance of three-dimensional study of the pipe rather than two dimensions. The pipe depth, width and depth-to-width ratios at the pipe tip in critical erosion stages are measured and presented. In the presented tests, two different erosion behaviours (stepwise pipe progression until failure and straight failure) are found and analysed with respect to possible influential parameters. Higher head drops and flow rates are found in tests with straight failure at the stage before progression. A linear relationship between the hydraulic conductivity contrast (k_c) and the critical head drops (h_c) is found and observations are used to investigate deviations from the line.

     

Influence of the Madden Julian Oscillation on precipitation and surface air temperature in South America

The regional influence of the Madden–Julian oscillation (MJO) on South America is described. Maps of probability of weekly-averaged rainfall exceeding the upper tercile were computed for all seasons and related statistically with the phase of the MJO as characterized by the Wheeler–Hendon real-time multivariate MJO (RMM) index and with the OLR MJO Index. The accompanying surface air temperature and circulation anomalies were also calculated. The influence of the MJO on regional scales along with their marked seasonal variations was documented. During December–February when the South American monsoon system is active, chances of enhanced rainfall are observed in southeastern South America (SESA) region mainly during RMM phases 3 and 4, accompanied by cold anomalies in the extratropics, while enhanced rainfall in the South Atlantic Convergence Zone (SACZ) region is observed in phases 8 and 1. The SESA (SACZ) signal is characterized by upper-level convergence (divergence) over tropical South America and a cyclonic (anticyclonic) anomaly near the southern tip of the continent. Impacts during March–May are similar, but attenuated in the extratropics. Conversely, in June–November, reduced rainfall and cold anomalies are observed near the coast of the SACZ region during phases 4 and 5, favored by upper-level convergence over tropical South America and an anticyclonic anomaly over southern South America. In September–November, enhanced rainfall and upper-level divergence are observed in the SACZ region during phases 7 and 8. These signals are generated primarily through the propagation of Rossby wave energy generated in the region of anomalous heating associated with the MJO.     

Energy use, climate change and folk psychology: Does sustainability have a chance? Results from a qualitative study in five European countries

Citizens’ support for policies that aim to curb carbon emissions and energy use is often seen as informed by their values, attitudes and perceptions of the environmental problem in question. We argue that we also need to understand how people conceptualise policies and the governance approaches underpinning them to be able to judge the likely acceptance of policy change.In this study, we draw on qualitative interviews (n = 202) from five European countries to explore citizens’ views on governance approaches to stimulate behavioural change in the field of resource use, including regulations, price changes, collective action, technological change and education.We found that many of our interviewees referred to generalised characteristics of humankind and contemporary society to back up their arguments for or against specific governance approaches. In particular, many interviewees concurred that people in general were so self-centred, driven by habit and money- and consumption-oriented that only strict regulations, drastic price changes and technological innovation could possibly achieve widespread behavioural change. As a consequence, such ‘folk psychologies’ can have substantial impact not only on public acceptance, but also on the success of policy measures that aim to reduce citizens’ resource use.     

Summer precipitation variability over South America on long and short intraseasonal timescales

A dipole pattern in convection between the South Atlantic convergence zone and the subtropical plains of southeastern South America characterizes summer intraseasonal variability over the region. The dipole pattern presents two main bands of temporal variability, with periods between 10 and 30 days, and 30 and 90 days; each influenced by different large-scale dynamical forcings. The dipole activity on the 30–90-day band is related to an eastward traveling wavenumber-1 structure in both OLR and circulation anomalies in the tropics, similar to that associated with the Madden–Julian oscillation. The dipole is also related to a teleconnection pattern extended along the South Pacific between Australia and South America. Conversely, the dipole activity on the 10–30-day band does not seem to be associated with tropical convection anomalies. The corresponding circulation anomalies exhibit, in the extratropics, the structure of Rossby-like wave trains, although their sources are not completely clear.     

The Impact of Land-Surface Parameter Properties and Resolution on the Simulated Cloud-Topped Atmospheric Boundary Layer

A method to simulate characteristics of wind speed in the boundary layer of tropical cyclones in an idealized manner is developed and evaluated. The method can be used in a single-column modelling set-up with a planetary boundary-layer parametrization, or within large-eddy simulations (LES). The key step is to include terms in the horizontal velocity equations representing advection and centrifugal acceleration in tropical cyclones that occurs on scales larger than the domain size. Compared to other recently developed methods, which require two input parameters (a reference wind speed, and radius from the centre of a tropical cyclone) this new method also requires a third input parameter: the radial gradient of reference wind speed. With the new method, simulated wind profiles are similar to composite profiles from dropsonde observations; in contrast, a classic Ekman-type method tends to overpredict inflow-layer depth and magnitude, and two recently developed methods for tropical cyclone environments tend to overpredict near-surface wind speed. When used in LES, the new technique produces vertical profiles of total turbulent stress and estimated eddy viscosity that are similar to values determined from low-level aircraft flights in tropical cyclones. Temporal spectra from LES produce an inertial subrange for frequencies \(\gtrsim \)0.1 Hz, but only when the horizontal grid spacing \(\lesssim \)20 m.