Isotopic evidence (He,B, C) for deep fluid and mud mobilization from mud volcanoes in the Caucasus continental collision zone

The Caucasian orogenic wedge formed as a consequence of the closure of the Tethyan Ocean, and numerous fields of active mud volcanoes pepper the area adjacent to the Black and Caspian Seas. Stable isotope ratios of boron, helium, and carbon have been measured for gas, fluid and sediment samples from active mud volcanoes of Taman Peninsula and Georgia to estimate the sources and mobilization depths of the fluid phase and mud. Boron concentrations in mud volcano fluids were found to be 5–35× higher than seawater. Fluid isotope ratios vary between ¹¹B=22 and 39, while isotope ratios of the smectite- and illite-rich extruded mud are considerably depleted in heavy ¹¹B (¹¹B=–8 to +7). B contents of these muds are ~8× higher than modern marine sediments. This suggests that liquefaction prior to mud volcanism was accompanied by both B enrichment and isotope fractionation, most likely at an intermediate depth mud reservoir at 2–4 km.The hydrocarbon-generating source beds to the mud volcanoes are located at 7 to >10 km depth in the folded Maikop Formation and are of proposed Oligocene–Miocene age. The most likely mechanism is re-hydration of these shales by both hydrocarbons and a geochemically mature fluid from greater depth within the orogenic wedge. Such a deep fluid source is supported by our results from gas analyses, which imply an admixture of minor amounts (less than 1%vol) of ³He (Georgia), thermogenic ¹³C in methane as well as "ultraheavy" ¹³C in CO₂ (both Taman and Georgia). The overall results attest active local flow of geochemically different fluids along deep-seated faults penetrating the two study areas in the Caucasian orogenic wedge, with the waters as well as the gases coming from below the Maikop Formation.     

Postglacial relative sea-level change and stratigraphy of raised coastal basins on Kola Peninsula, northwest Russia

A relative sea-level curve for the Holocene is constructed for Polyarny on the Kola Peninsula, northwest Russia. The curve is based on 18 radiocarbon dates of isolation contacts, identified from lithological and diatomological criteria, in nine lake basins situated between 12 and 57 m a.s.l. Most of the lakes show a conformable, regressive I–II–III (marine–transitional–freshwater) facies succession, indicating a postglacial history comprising an early (10,000–9000 radiocarbon years BP) phase of rapid, glacio-isostatically induced emergence (5 cm year⁻¹) and a later phase (after 7000 years BP,) having a moderate rate of emergence (<0.5 cm year⁻¹). Three lakes together record a phase of very low rate of emergence or slight sea-level rise at a level of 27 m a.s.l., between 8500 and 7000 years BP, which correlates with the regional Tapes transgression. Pollen stratigraphy in the highest lake shows that the area was deglaciated before the Younger Dryas and that previously reconstructed Younger Dryas glacier margins along the north Kola coast lie too far north.     

An experimental study of the isotopic enrichment in Ar, Kr, and Xe when trapped in water ice

The isotopic enrichment of argon, krypton, and xenon, when trapped in water ice, was studied experimentally. The isotopes were found to be enriched according to their (m1/m2)1/2 ratio. These enrichment factors could be useful for comparison among the uncertain cosmic or solar isotopic ratios, the hopeful in situ cometary ratio, and those in Earth's atmosphere, in the context of cometary delivery of volatiles to Earth.     

Thunderstorms on Jupiter

The presence of a considerable acetylene concentration on Jupiter, despite the fast rate of its photolytic hydrogenation, provides strong evidence for the operation of frequent and powerful thunderstorms in the Jovian atmosphere. Whereas acetylene regeneration can occur only during thunderstorms, the photolytically destroyed ammonia can be regenerated both in thunderstorms and in the low and hot atmospheric levels. A rate of Earthlike lightning strokes 10⁴ times larger than on Earth is inferred from the calculated rate of acetylene's photolytic destruction. The rate of acetylene production by thunder shock waves and the products obtained from its photolytic hydrogenation can account for the large ethane concentration and the absence of ethylene. The yellow-brown acetylene polymer and the ruby-red polymers, obtained from thunder-produced hydrogen cyanide or cyanogen with ammonia, are likely contributor to the Jovian coloration.     

Dynamics of the chemical evolution of Earth's primitive atmosphere

The course of evolution of Earth's primitive reducing atmosphere is shown to possibly have been determined to a large extent by the effect of thunder shock waves, which is comparable to the effect of solar uv radiation. The major chemical reactions occurring during a thunderstorm in the troposphere were pyrolysis of hydrocarbons, their oxidation by water vapor and their reaction with molecular nitrogen. These reactions were studied by the single-pulse shock tube technique and their rates as well as their product distributions were determined.The greenhouse effect of water vapor and acetylene enhanced oxidation by water vapor and prevented the accumulation of large graphite and polymer deposits on the Earth's surface. This is in accordance with their absence on the contemporary Earth. Changes in the frequency and power of thunderstorms, within reasonable limits, affected the rate of evolution but caused only small changes in the concentration profiles of HCN and aldehydes, which are essential for further chemical evolution in the oceans. The surface temperature and relative hydrogen concentration are shown to be of prime importance in determining the course and outcome of atmospheric evolution.     

Acetylene photopolymers in Jupiter's stratosphere

Laboratory data on the rate of photolytic polymerization of acetylene, highly diluted with hydrogen, at the pressure range of the Jovian stratosphere is presented. It is shown that this rate is sufficient to maintain the stratospheric aerosol haze which was observed on Jupiter by Smith et al. (1977, Icarus30).     

First experimental studies of large samples of gas-laden amorphous “cometary” ices

In a unique machine, the first of its kind, large (200 cm² × 10 cm) samples of gas-laden amorphous ice were prepared at 80 K and 10⁻⁵ Torr. The sample consisted of a fluffy agglomerate of 200-μm ice grains, similar to what is presumed to be the structure of comet nuclei. The sample was heated from above by IR radiation. The properties studied were gas content in the ice and its emanation from the ice upon warming and bearing on the gas/water vapor ratio observed in cometary comae vs this ratio in cometary nuclei and the effect of internal trapped gas on the thermal conductivity of the ice and the density and mechanical properties of pure ice vs gas-laden ice. These findings might have significance for the interpretation of comet observations, the forthcoming ESA’s Rosetta space mission to Comet 46P/Wirtanen in 2012, and to other comet missions.     

Gas release in comet nuclei

The evolution of a comet nucleus is investigated, taking into account the crystallization process by which the gas trapped in the ice is released to flow through the porous ice matrix. The equations of conservation of the energy and of the masses of ice and gas are solved throughout the nucleus, to obtain the evolution of the temperature, gas pressure and density profiles. A spherical nucleus composed of cold, porous amorphous ice, with 10% of CO trapped in it, serves as initial model. Several values of density (porosity) and pore size are considered. For each combination of parameters the model is evolved for 20-30 revolutions in comet P/Halley's orbit. Two aspects of the release of gas upon crystallization are analyzed and discussed: (a) the resulting continuous outward flux with high peaks at the time of crystallization, which is a cyclic process in the low-density models and sporadic in the high-density ones; (b) the internal pressures obtained down to depths of a few tens to approximately 200 m (depending on parameters), that are found to exceed the compressional strength of cometary ice. As a result, both cracking and explosions of the overlying ice layer and ejection of gas and ice/dust grains are expected to follow crystallization. They should appear as outbursts or sudden brightening of the comet. The model of 0.2 g cm-3 density is found to reproduce quite well many of the light-curve and activity characteristics of comet P/Halley.     

Titan's aerosols: Comparison between our model and DISR findings

Our model [Dimitrov, V., Bar-Nun, A., 1999. A model of energy dependent agglomeration of hydrocarbon aerosol particles and implication to Titan's aerosol. J. Aerosol. Sci. 30(1), 35-49] describes the experimentally found polymerization of C₂H₂ and HCN to form aerosol embryos, their growth and adherence to form various aerosols objects [Bar-Nun, A., Kleinfeld, I., Ganor, E., 1988. Shape and optical properties of aerosols formed by photolysis of C₂H₂, C₂H₄ and HCN. J. Geophys. Res. 93, 8383-8387]. These loose fractal objects describe well the findings of DISR on the Huygens probe [Tomasko, M.G., Bézard, B., Doose, L., Engel, S., Karkoschka, E., 2008. Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere. Planet. Space Sci., this issue, doi:10.1016/j.pss.2007]. These include (1) various regular objects of R=(0.035-0.064)×10⁻⁶ m, as compared with DISR's 0.05×10⁻⁶ m; (2) diverse low and high fractal structures composed of random combinations of various regular and irregular objects; (3) the number density of fractal particles is 6.9×10⁶ m⁻³ at Z=100 km, as compared with DISR's finding of 5.0×10⁶ m⁻³ at Z=80 km; (4) the number of structural units per higher fractals in the atmosphere at Z∼100 km is (2400-2700), as compared with DISR's 3000, and their size being of R=(5.4-6.4)×10⁻⁶ m will satisfy this value and (5) condensation of CH₄ on the highly fractal structures could begin at the altitude where thin methane clouds were observed, filling somewhat the new open fractal structures.