Observations on New Approaches for the Determination of Platinum-Group Elements, Gold and Silver in Different Geochemical Samples from Siberia and the Far East

Some recent experiments on the determination of Au and the platinum-group elements (PGE) in geochemical samples are reviewed. Emphasis is given to the determination of ultra-low levels of PGE concentrations in resistant matrices, including chromites, molybdenites and ultrabasic ores. The problems and features of PGE determination in samples of various chemical composition are considered. For each sample type studied, a series of sample preparation techniques are proposed. These techniques included acid digestion, fusion with sodium peroxide, cold sintering with an oxidizing mixture of Na₂O₂+ Na₂CO₃ and also oxidizing fluorination with bromine trifluoride. A new approach for preparing geochemical material prior to digestion, based on mechano-chemical activation with simultaneous hyperfine grinding, is proposed and studied. The instrumental determination of PGE contents was carried out directly by AAS from extracted organic phases. It was found that a combination of digestion processes was required to achieve geochemical background levels of Au and PGE concentrations with the following detection limits: Pd, Rh - 1 ng g⁻¹, Pt, Ru - 10 ng g⁻¹, Au - 0.2 ng g⁻¹, Ag - 0.1 ng g^−1. The uncertainty in PGE and Au determination in geochemical samples is dependent on metal concentration, and also on their distribution in samples. The total analytical uncertainty of the proposed method is between 15-30%.     

The distribution of trace metals in Florida Bay sediments

The distribution of trace metals based on surface sediments collected at 40 stations across Florida Bay was done in June, November and February 2000-2001. Concentrations of Sc, V, Ba, Cd, Cr, Co, Cu, Pb, Mn, Ni, Zn, Al and Mg were determined by ICP-MS, and the total Fe was determined by spectrophotometry. Organic carbon (OC), nitrogen (N), and calcium carbonate (CaCO3) were also measured. Eleven of 13 metals showed a similar distribution pattern for the various months studied. Maximum concentrations of metals were lower than those found in most estuarine systems and were concentrated in the north-central and western zones of the Bay. The Mn and Fe concentrations, unlike the other metals, gradually decreased from north (Everglades) to south (Florida Keys). Some metals (Ni, Zn, Cu, Cr, Pb and Ba) associated with petroleum use showed high concentrations at stations near the Tavernier marina. Florida Bay sediments are predominately CaCO3 (65.9-92.5%). The greatest value for OC (5.5%) and the lowest value of CaCO3 (65.9%) were found in the western zone. Trace metal distribution patterns are similar to the OC and N in the sediments. There was a strong correlation between most metals (V>Cu>Ni>Cr>Al>Co>Ba>Zn>Pb>Mg) and the percentage of OC. The maximum C/N values (9-12) were observed at the stations with the highest OC, where dense colonies of seagrass are found and most of the metals are concentrated. All metals except Mg, Mn and Co showed a strong correlation with Al and the fine fraction of the sediments (aluminosilicates) associated with continental input and river runoff.     

Effects of climate, invasive species and anthropogenic impacts on the growth of the seagrass Posidonia oceanica (L.) Delile in Liguria (NW Mediterranean Sea)

Eight shallow water Posidonia oceanica meadows were sampled in June 1999 along 300 km of the Ligurian coast and were compared through shoot density and lepidochronology. The growth of the seagrass was examined in the light of climate fluctuations and local stresses, colonisation by alien, invasive alga Caulerpa taxifolia, and effects of the oil spill from the tanker "Haven", and other anthropogenic impacts. Both shoot density and lepidochronology pointed to a generalised state of regression of all the meadows. The analysis of long-term growth curves of the rhizomes showed a positive trend parallel to the increase of air temperature. Two main groups of meadows were individuated on the basis of growth curve similarity. The first included four meadows, namely Ventimiglia, Imperia, Noli and Prelo, that were characterised by average values of rhizome growth of 8-9.1 mmyear(-1) and shoot density greater than 200 shootsm(-2). Although the Imperia meadow was the only one where the alien invasive alga C. taxifolia was found, it did not show differences for rhizome growth in comparison to the other meadows. The second group was formed by meadows that had suffered past anthropogenic impacts: Arenzano and Monterosso al Mare. They showed higher rhizome growth rates (9.4-10.6 mmyear(-1)) and shoot densities between 200 and 100 shootsm(-2). At Arenzano, where "Haven" oil was stranded in April 1991, no rhizome older than 8 years was found, thus confirming the shoot mortality induced by the oil spill event. The two last meadows exhibited growth curves very different from all the others: Portovenere, is a shallow meadow where P. oceanica merely survives in an extremely degraded situation with highest rhizome growth rate (12 mmyear(-1)), the other, Riva Trigoso, is the only meadow implanted on rock and had the lowest growth rates (7.1 mm year(-1)).     

Women as individuals and members of minority groups: how to reconcile human rights and the values of cultural pluralism

The paper represents an attempt to understand how, in a democratic and pluralistic state, it is possible to reconcile the values of individual freedom with those granted to minority groups. In this perspective, the paper argues that, without questioning the importance of differentiated cultural rights that allow cultural minorities to be on an equal footing with the mainstream society, women’s rights cannot be ignored. Instead, rights for women are not exclusive of any particular culture or society, being indeed one of the human rights common to all groups of people, those rights which attest to the existence of a bond among individuals as members of the human community.     

Linking two centuries of tree growth and glacier dynamics with climate changes in Kamchatka

Glaciers around the world retreated as the climate warmed substantially. For the majority of alpine and arctic areas, however, the lack of meteorological data over a long period makes it difficult to build long-term climate and glacial fluctuation relationships, emphasizing the importance of natural proxy archives. Here we use the 230-year record of stem radial growth of birch trees (Betula ermanii) from the treeline forests above the receding glaciers in eastern maritime Kamchatka to analyse temporal variations of climate as well as glacial advance and retreat. Glaciers in Kamchatka Peninsula represent the southern limit of glaciation in far eastern Eurasia, which makes them prone to global warming. Using instrumental climate data (1930–1996) from local meteorological stations, we find that the July temperature had most prominent positive impact on birch growth. On the contrary, smaller ring increments are associated with the positive summer and net annual ice mass balance of Koryto Glacier. The prevailing trend of higher summer temperatures and lower snowfall over the past 70 years has enhanced tree growth while causing the glacier’s surface to lower by about 35 m and its front to retreat by about 490 m. Assuming these same relationships between climate, tree growth, and glacier mass balance also existed in the past, we use tree rings as a proxy record of climatically induced temporary halts in the glacier’s retreat over the past two centuries, which in total was over 1,000 m. Both direct observations and tree ring proxies indicate several prolonged warm periods (1990s, 1960s, 1930–1940s, 1880–1900s) interspersed with cooler periods (1984–1985, 1970–1976, 1953–1957, 1912–1926, 1855–1875, 1830–1845, 1805–1820 and 1770–1780) when the glacier re-advanced, creating several consecutive terminal moraine ridges. We conclude that birch tree-rings are suitable for assessing tree growth/climate/glacial relationships over a longer timescale in maritime Kamchatka.     

New data on earthquake focal mechanisms in the Laptev Sea region of the Arctic-Asian seismic belt

We consider 16 earthquakes with M_w?=?4.2–5.2 that occurred in the south-eastern part of the Laptev Sea shelf, Lena River Delta, and North Verkhoyanye (Russia) in 1990–2014. Focal mechanisms, scalar seismic moments, moment magnitudes, and hypocentral depths of the seismic events have been calculated from the data on amplitude spectra of surface waves and P wave first-motion polarities. The obtained results sufficiently implement the existing dataset on reliable earthquake source parameters for the study region and prove the change of the stress-strain state of the crust from extension on the Laptev Sea shelf to compression on the continent providing finer spatial details of the deformation field in the transition zones such as Buor-Khaya Bay and the Lena River Delta.     

Evaluation of DNA Damage in the Marine Mussel Crenomytilus grayanus as a Genotoxic Biomarker of Pollution

Marine pollution affects all life processes in aquatic organisms. The genotoxic effect of pollution on the mussel Crenomytilus grayanus was assessed. Bivalves were collected from the ‘clean'(Vostochnaya Cove) and polluted(Nakhodka Bay) areas in the Peter the Great Bay. The degree of DNA damage in C. grayanus was determined by alkaline comet assay as mean percentage of DNA in tail, and the genetic damage index was calculated. Our results indicate that almost one-third of DNA in cells of gills and digestive gland of C. grayanus inhabiting the Nakhodka Bay had destructive changes compared to the individuals of this species from the Vostochnaya Cove. This study has shown that chronic pollution of the aquatic environment causes destructive changes to DNA in gill and digestive gland cells of C. grayanus.     

Responses of a Northern Adriatic Ampelisca-Corbula community to seasonality and short-term hydrological changes in the Po river

During the 20th century, increased nutrient inflow has increased the frequency and intensity of eutrophication events in the North-western Adriatic Sea. More recently, evidence of a reduction in the Po river flow and a recovery of the benthic environment were reported. We examined the role played by Po river regime and seasonality in determining the temporal pattern of macrozoobenthos variation: samples were collected from a site located 10-12km off Cesenatico during two years from October 2004 to September 2006, when the mean Po discharge remained exceptionally low. 88 taxa were found, and the community was dominated by few species: Ampelisca diadema, Lumbrineris latreillii, Corbula gibba, Aricidea claudiae, Levinsenia gracilis and Nucula nucleus account for about 80% of total abundances. The density of these species exhibited a marked seasonal variability. Moreover, the total abundance and the density of the sensitive species, A. diadema, were negatively affected by several disturbance events (hypoxic conditions, frequent storms and an anomalous winter flood) that occurred between November 2005 and March 2006. The reduction of C. gibba and the increase of A. diadema densities observed in the investigated period, and verified recently by other authors could be related to the reduction in river inputs as a consequence of climatic changes.     

Organic waste impact of capture-based Atlantic bluefin tuna aquaculture at an exposed site in the Mediterranean Sea

A variety of pelagic and benthic parameters were measured at an aquaculture farm used for the fattening of Atlantic bluefin tuna (Thunnus thynnus) which is located at an exposed site (700 m from the coast, average bottom depth of 45 m and average current speed of 6 cm s⁻¹) in the Mediterranean Sea. The objective was to test whether modern off-shore tuna fattening industries can exert a sustainable organic waste impact on the receiving environment as has been reported for the offshore culture of more traditional Mediterranean species such as sparids. In the water column, the concentration of phytopigments, organic matter, heterotrophic bacteria and the taxonomic abundance of mesozooplankton (at the species level) were assessed. In the sediment, we assessed the concentration of reduced sulphur pools, phytopigments, organic matter, heterotrophic bacteria and the taxonomic abundance of meiofauna (at the taxa level) and nematodes (at the genus level). For most parameters, we found no substantial differences between farm and control sites. Deviations of farm values from control values, when they occurred, were small and did not indicate any significant impact on either the pelagic and benthic environment. Deviations were more apparent in the benthic compartment where lower redox potential values, higher bacterial production rates and a change in nematode genus composition pointed out to early changes in the sediment's metabolism. In addition, indigenous potential pathogenic bacteria showed higher concentration at the fish farm stations and were a warning of an undesirable event that may become established following aquaculture practice in oligotrophic environments. The overall data from this study provide extensive experimental evidence to support the sustainability of modern offshore farming technology in minimizing the hypertrophic-dystrophic risks associated with the rapidly-expanding tuna-fattening industry in the Mediterranean Sea.     

A piecewise curve-fitting technique for vertical oceanographic profiles and its application to density distribution

A unified method of approximation, extrapolation, and objective layering is offered for processing vertical oceanographic profiles. The method is demonstrated using seawater density and consists of adjustable splitting of each individual profile into N vertical layers based on tentative, piecewise linear homogeneous approximation with specified accuracy and a final fitting of an N-layered analytical model to data. A set of 3N coefficients of the model includes one density value at the sea surface; N−1 depths of layer interfaces; and N pairs of coefficients that describe a profile shape within the n-th layer—an asymptotic density value (a key parameter for extrapolation) and a vertical scale of maximum density variability (related to vertical gradient). Several distinctive characteristics of the technique are: (1) It can be used for the analysis of the vertical structure of individual profiles when N is an unknown parameter, and spatial interpolation when N should be equal for all profiles. (2) A justified downward extrapolation of incomplete data is possible with the model, especially if historical deepwater profiles are available. (3) Layer interfaces, as well as other coefficients, are derived with only one fitting to the entire profile. (4) The technique, using its general formulation, can serve as a parent for developing various types of models. The simpler step-like (with hyperbolic or exponential approximation) and more complicated smooth (continuous in gradient space) models were designed and tested against a large number of density profiles from the Sea of Okhotsk and the Gulf of California. Comparison of parametric, z-levels and isopycnal averaging was done for the region off the northeastern coast of Sakhalin.