A nutrient loading budget for Biscayne Bay, Florida

The water quality in Biscayne Bay has been significantly affected by past and continuing coastal and watershed development. The nutrient concentrations in the Bay have been dramatically changed by the conversion of natural creeks and sheet flow freshwater inputs to rapid and episodic canal inputs from the large and rapidly expanding Miami metropolitan area. This study is an evaluation of nutrient loadings to Biscayne Bay for 1994-2002 from canal, atmospheric, and groundwater sources. Dissolved inorganic nitrogen (DIN, as nitrate, nitrite, and ammonium) and total phosphorus (TP) loadings by the canals were influenced by their geographic locations relative to discharge amount, watershed land use, stormwater runoff, and proximity to landfills. Annual budgets showed that canals contributed the bulk of N loading to the bay as 1687.2 metric ton N yr(-1) (88% total load). Direct atmospheric DIN load for Biscayne Bay was only 231.7 ton N yr(-1), based on surface area. Of the canal DIN load, nitrate+nitrite (NO(x)(-)) loading (1294.5 ton N yr(-1)) made up a much greater proportion than that of ammonium (NH(4)(+), 392.6 ton N yr(-1)). In the urbanized north and central Bay, canal DIN load was evenly split between NO(x)(-) and NH(4)(+). However, in the south, 95% of the DIN load was in the form of NO(x)(-), reflecting the more agricultural land use. Contrary to N, canals contributed the only 66% of P load to the bay (27.5 ton P yr(-1)). Atmospheric TP load was 14 ton Pyr(-1). In the north, canal P load dominated the budget while in the south, atmospheric load was almost double canal load. Groundwater inputs, estimated only for the south Bay, represented an important source of N and P in this zone. Groundwater input of N (141 ton N yr(-1)) was about equal to atmospheric load, while P load (5.9 ton P yr(-1)) was about equal to canal load.     

Experimental studies of Ta2O5 and columbite–tantalite solubility in fluoride solutions from 300 to 550°C and 50 to 100 MPa

It is well established that the fractionation of Li–F granitic magmas at depth leads to the accumulation of flux elements such as F and Li, and metal cations such as Ta and Nb in residual melts. However, it remains to be determined whether magmatic fractionation is sufficient to concentrate Nb and Ta into economically significant quantities, and what role hydrothermal–metasomatic processes play in the formation of such ore deposits. In the literature, reliable data about the solubility of Ta and Nb in hydrothermal solutions is missing or incomplete. This study provides a quantitative experimental estimation of the possible contribution from hydrothermal processes in Ta enrichment in cupolas of albitized and greisenized Li–F granite. Experimental studies of Ta₂O₅ and columbite–tantalite (Mn,Fe)(Nb,Ta)₂O₆ solubility were carried out in fluoride solutions consisting of HF, NaF, KF, and LiF. At low fluoride concentrations (0.01 and 0.1 m), Ta₂O₅ solubility at 550°C and 100 MPa under Co–CoO oxidizing conditions is low (near 10^?5–10^?4 m) in all fluoride solutions (HF, NaF, KF, LiF). At high fluoride concentrations (1 and 2 m) the highest Ta₂O₅ concentrations (10^?1 m) were detected in HF solutions. In KF, NaF, and LiF solutions, the Ta₂O₅ solubility is also high (10^?3–10^?2 m). The dependence of columbite–tantalite (Nb₂O₅-59 wt. %, Ta₂O₅-18 wt. %) solubility as a function of solution composition, T, and P has also been investigated. Tantalum and Nb concentrations have the highest values in HF solutions at reduced conditions (up to 10^?3 to 10^?2 m Ta in 1 m HF). In 1 m NaF solutions, the concentrations of Nb and Ta are, respectively, 2.5 and 3 orders of magnitude less than those in the 1 m HF solutions. Solubility of Ta and Nb in KF solutions has intermediate values. It is established that in NaF and KF solutions the dependence of solubility on pressure is distinctly negative. The Nb and Ta contents increase with increasing concentrations of HF and KF in solution, however, they do not change with increasing NaF concentration. In NaHCO₃, Na₂CO₃, and HCl solutions columbite–tantalite solubility is low. Even in 1 m chloride solutions the content is within the limits of 10^?5 m for Nb and 10^?6 to 10^?8 m for Ta. We conclude that hydrothermal transport of Ta and Nb is possible only in concentrated fluoride solutions.     

The XMM-Newton Bright Serendipitous Survey: First Extragalactic Results

We present here some initial results from the ongoing XMM-Newton bright serendipitous survey. The survey is aimed at selecting and spectroscopically identifying a large and statistically representative sample of bright (f _x ≳ 7× 10⁻¹⁴ c.g.s) serendipitous X-ray sources in the 0.5–4.5 keV energy band (BSS) and a complementary (smaller) sample in the 4.5–7.5 keV energy band (HBSS). The work is partly based on observations obtained with XMM-Newton, an ESA science mission with instruments and contributors directly founded by ESA member states and the USA(NASA) and on observations collected at TNG. The TNG telescope is operated on the island of La Palma by the Centro Galileo Galilei of the INAF in the Spanish Observatorio del Roque de Los Muchachos of the Instituto de Astrofísica de Canarias. On behalf of the XMM-Newton Survey Science Center.     

Determination of Phobos’ rotational parameters by an inertial frame bundle block adjustment

A functional model for a bundle block adjustment in the inertial reference frame was developed, implemented and tested. This approach enables the determination of rotation parameters of planetary bodies on the basis of photogrammetric observations. Tests with a self-consistent synthetic data set showed that the implementation converges reliably toward the expected values of the introduced unknown parameters of the adjustment, e.g., spin pole orientation, and that it can cope with typical observational errors in the data. We applied the model to a data set of Phobos using images from the Mars Express and the Viking mission. With Phobos being in a locked rotation, we computed a forced libration amplitude of \(1.14^\circ \pm 0.03^\circ \) together with a control point network of 685 points.     

Climate change impacts on invasive potential of pink hibiscus mealybug, Maconellicoccus hirsutus (Green), in Chile

Maconellicoccus hirsutus (Green) (Hemiptera:Pseudoccidae) is an important pest in many countries being responsible for considerable economic loses. Although it is not currently present in Chile, the chance that it could be accidentally introduced rises with the list of infested countries increasing over the last years. In addition, climate change projections indicate that a larger region would fit as potential habitat for this pest, allowing it to persist over time and colonize a larger proportion of the Chilean territory. In this study the geographic distribution and the number of generations this mealybug would develop in Chile were determined, under current temperatures and under two projected climatic scenarios. Cumulative degree days were calculated for current and future scenarios using a lower temperature threshold of 14.5 °C, with 624.5 degree-days as the thermal requirement for the species to complete one generation. The results show that under current climate conditions M. hirsutus could develop up to three generations in the north of the country (i.e. 18° South) and one generation in the region near 37° South. Under future scenarios’ conditions the pest could develop up to five generations in the north, and one generation around the 42° South. Present climate conditions in Chile would allow the establishment of the pink hibiscus mealybug, if the pest enters the country. Climate change conditions would allow the potentially invaded area to expand south, and would promote the development of more generations per year of the mealybug in the studied territory.     

The special climate change fund: origins and prioritisation assessment

Abstract

A central issue in tackling climate change is to understand to what extent different short-term mitigation strategies are consistent with long-term stabilization targets. The present article aims at cross-comparing emission paths derived by plausible short-term policies against those implied by long-term climate targets, comparing, for example, differences in peak periods. Short-term policies considered are, for instance, Kyoto-type targets with or without participation by the USA and/or by developing countries. Long-term targets focus instead on stabilization of CO₂ concentrations, radiative forcing and the increase in atmospheric temperature relative to pre-industrial levels. In order to account for the uncertainty surrounding the climate cycle, for each long-term goal multiple paths of emission—the most probable, the optimistic and the pessimistic projections—are considered in the comparison exercise. Comparative analysis is performed using the FEEM-RICE model, a regional economy—climate model. The results suggest that some early policy action should take place for short-term emissions to be compatible with long-term targets. In particular, the Kyoto-type regimes appear to be on a compatible emission path, at least up to the second commitment period. However, this is no longer the case when assuming a pessimistic realization of the uncertain climate parameters.     

Treatment of ground-motion predictive relationships for the reference seismic hazard map of Italy

In the framework of the 2004 reference seismic hazard map of Italy the amplitude of the strong-motion (expressed in terms of Peak Horizontal Acceleration with 10% probability of non-exceedence in 50 years, referred to average hard ground conditions) was computed using different predictive relationships. Equations derived in Italy and in Europe from strong-motion data, as well as a set of weak and strong-motion based empirical predictive relationships were employed in a logic tree procedure, in order to capture the epistemic uncertainty affecting ground-motion attenuation. This article describes the adjustments and conversions required to eliminate the incompatibilities amongst the relations. Particularly significant are distance conversions and style-of-faulting adjustments, as well as the problems related to the use of regional relations, such as the selection of a reference depth, the quantification of random variability and the strong-motion prediction. Moreover, a regional attenuation relationship specific for volcanic areas was also employed, allowing a more realistic evaluation of seismic hazard, as confirmed by the attenuation of macroseismic intensities.     

Flare-related changes in the profiles of six photospheric spectral lines

The profiles of six photospheric absorption spectral lines (Fei 5250 Å, Fei 5324 Å, Fei 5576 Å, Cai 5590 Å, Cai 6103 Å and Fei 6165 Å), measured in the kernel of a 2N solar flare and in a quiet-Sun area, were compared. The observations were carried out with an echelle spectrograph of the Crimean Astrophysical Observatory. It was shown that, compared to the quiet-Sun profiles, the flare profiles are shallower in the line core and are less steep in the wings. Therefore, measurements of the longitudinal magnetic field made with a magnetograph system which uses the Cai 6103 Å  spectral line, can be underestimated by 18–25% in areas of bright H ribbons of a moderate solar flare. Modeling of the solar photosphere performed by using a synthesis method showed that, in a solar flare, the enhanced core emission seems to be related to heating of the photosphere by the flare, whereas the decrease of the slope of the wings was presumably caused by the inhomogeneity of the photospheric magnetic field.     

Technology innovation and diffusion in “less than ideal” climate policies: An assessment with the WITCH model

This paper examines the dynamics of innovation in low-carbon energy technologies distinguishing between research and development and technology diffusion as a response to alternative climate policies. We assess the implications of second-best policies that depart from the assumption of immediate and global participation and of full technology availability. The analysis highlights the heterogeneous effects of climate policy on different energy R&D programs and discusses the contribution of important determinants such as carbon price and policy stringency, policy credibility, policy and technological spillovers and absorptive capacity.