Iron and Manganese Minerals in Suspended Matter from the Barents Sea

The mineralogy of suspended matter from surface and bottom waters is studied at two sites in the Barents Sea. Along with terrigenous minerals, the suspended matter samples contain authigenic mineral phases of iron and manganese oxyhydroxides. Mn-feroxyhite, Fe-vernadite, goethite, and proto-ferrihydrite were identified in samples from surface waters, whereas birnessite and nonferruginous vernadite were registered in samples from bottom waters. The formation of suspended manganese minerals in bottom waters is explained by an additional Mn supply from underlying reduced sediments during their early diagenesis and oxygen depletion in the near-bottom nepheloid layer. Bacteria are supposed to take part in the authigenic mineral formation.     

Spatial distribution of the phytoplankton in the White Sea during atypical domination of dinoflagellates (July 2009)

The species composition and biomass of phytoplankton, concentrations of chlorophyll a (Chl a) and nutrients, and accompanying hydrophysical conditions have been studied in the White Sea on July 6–11, 2009. The temperature of the surface water layer was lower than the multiyear average in July. Dinoflagellates dominated in the entire studied area; this was not the typical event for July. We suggest that domination of dinoflagellates was caused by low water temperature, when the nutrient regeneration rate was insufficient to support diatom growth. The abundance of microalgae and the structure of the phytoplankton community depended on the water structure. Variations in the phytoplankton community structure were caused not by substitution of specific species but rather by variability of the abundance of a single species, Heterocapsa triquetra. The highest phytoplankton biomass has been recorded in weakly stratified waters, where tidal mixing supplied the income of inorganic nutrients. The income of nutrients to the photic layer was limited in the stratified waters of Dvina Bay during the summer low-water period, so the phytoplankton abundance was low. We suggest that the lens of surface desalinated water presumably originated from the outlet of the Dvina River was registered in the central part of the White Sea.     

Distribution and composition of suspended particulate matter in the Atlantic Ocean: Direct measurements and satellite data

The main purpose of this work is to study the real distribution and spatial–temporal variations of suspended particulate matter and its main components in surface waters of the Atlantic Ocean on the basis of direct and satellite measurements for development of new and perfection of available algorithms for converting satellite data. The distribution fields of suspended particulate matter were calculated and plotted for the entire Atlantic Ocean. It is established that its distribution in the open ocean is subordinate to the latitudinal climatic zonality. The areas with maximum concentrations form latitudinal belts corresponding to high-productivity eutrophic and mesotrophic waters of the northern and southern temperate humid belts and with the equatorial humid zone. Phytoplankton, the productivity of which depends primarily on the climatic zonality, is the main producer of suspended particulate matter in the surface water layer.     

Contents,seasonal variations,and forms of migration of major and minor elements in surface waters in the area of the Tyrnyauz Tungsten–Molybdenum Combine (TTMC) and adjacent areas (Kabardino-Balkarian Republic,Russian Federation) and actions for recovery of the ecological environment

Anomalous concentrations of numerous major and minor elements significantly exceeding the threshold limit values (TLV) for drinking water were registered in the area of the Tyrnyauz Tungsten–Molybdenum Combine (TTMC). The maximal excess of the TLV (by one or two orders of magnitude) were obtained for Mo (up to 11 mg/L), W (4.4 mg/L), As (1.5 mg/L), Mn (8.4 mg/L), and Tl (up to 3.3 μg/L) in water of the Bolshoi Mukulan Brook flowing through the mines and three brooks flowing out from the base of the embankment of the tailing store no. 1. They are the major pollutants for water of the Baksan River. Upon flowing out to the plain, water of the Baksan River shows significant excess of the TLVs (in summer) for Al, Fe, Mn, Be, Si, Ti, Tl, and Hg.     

New monoaromatic steroids in organic matter of the apocatagenesis zone

According to the materials of geochemical study in the core of the ultradeep hole SV-27 of aromatic fractions of bitumoids of the Vilyui syneclise (East Siberia) by the method of chromatography–mass spectrometry, starting from the depth of >5000 m, four diastereomers of previously unknown hydrocarbons, which become predominant in the fraction at a depth of ～6500 m, were distinguished. Similar hydrocarbons were found in organic matter of Upper Paleozoic rocks of the Kharaulakh anticlinorium in the Verkhoyansk folded area. According to the intense molecular ion m/z 366 and the character of the basic fragmental ions (m/z 238, 309, and 323), the major structure of the compounds studied was determined as 17-desmethyl-23-methylmonoaromatic steroid C₂₇. The absence of such steroids in oil of the Vilyui syneclise shows that deep micro-oils did not participate in the formation of oil fringes of gas condensate deposits of the region.     

Structure of the South Pole-Aitken lunar basin

The hypsometric map and the basin height profiles, for the first time relying upon a spherical daturence surface, have been constructed based on the generalization of the heights measured within the hemisphere including the ring structure of the South Pole-Aitken basin. The distribution of the major chemical elements (Fe and Th), depending upon the structure height levels, has been obtained. The relationship between these lunar rock indicators and the height levels of the rock preferential distribution has been revealed. The outer basin ring has been distinguished and the ring structure of the central basin depression has been revealed against a combined hypsometric and geochemical background. A total basin diameter of about 3500 km has been reliably determined for the first time. A unique feature of the basin structure consists in that the arrangement of the basin inner rings does not show a central circular symmetry, which can indicate that a hypothetical impactor moved along the trajectory (or orbit) oriented almost normally to the ecliptic plane. In combination with the revealed very small depth-diameter ratio in the initial basin structure, this circumstance makes it possible to put forward the hypothesis that a comet impact produced the South Pole-Aitken basin.     

Spinner dolphins Stenella longirostris off south-west Mauritius: abundance and residency

Spinner dolphins Stenella longirostris longirostris off the south-west coast of Mauritius are subject to ongoing anthropogenic disturbance in the form of daily dolphin tourism, which has intensified since 1998. Abundance of this species was estimated using photo-identification data and mark-recapture analysis. Between April 2008 and June 2010, identification photographs were collected from dolphins occurring along a 30 km length of the coast of south-west Mauritius. A total of 250 groups were encountered over 229 survey days. Mark-recapture analyses were performed on a photographic dataset of more than 8 000 good- and excellent-quality images and 83 animals were identified as distinctively marked individuals. The majority (85.5%) were seen more than once and resightings indicated a resident population. The compiled version of SOCPROG 2.4 was used to investigate the lagged identification rate. The fitted model supported a mostly resident population with additional animals moving in and out of the study area. The estimated abundance of the total population in the study area ranged between 138 and 399 individuals. Our results can be used for monitoring the population for fluctuations and for encouraging both the enforcement of laws regarding dolphin watching and the development of further means of management needed to ensure the long-term presence of this population.     

Seasonal and interannual variability of oceanographic conditions in the southwestern part of the Sea of Okhotsk

The seasonal variability of oceanographic conditions in the southern part of the Sea of Okhotsk is described based on long-term mean temperature T and salinity S from observations along a standard oceanographic section Cape Aniva-Cape Dokuchaev (May–November). It is shown that the Soya Current is relatively weak in spring, with low temperature and salinity gradients along the section. The Sea of Okhotsk low-salinity water mass is observed in the upper layer. It was formed as a result of melting of a large amount of ice brought here with the East Sakhalin Current from the northwestern part of the Sea of Okhotsk. A cold intermediate layer (CIL) at depths of 50–150 m extends along the entire section. The cold intermediate layer core with a temperature at the edge of the Sakhalin shelf of about ?1.3°C is retained during a period of maximum warming in August; however, in October–November the intensified flow of the East Sakhalin Current (up to 50 cm/s) results in a situation when relatively warm low-salinity waters, connected with the Amur River runoff, dissipate CIL. The results of 12 surveys conducted by the Sakhalin Research Institute for Fisheries and Oceanography in 1998–2004 show significant deviations of T and S [10] in different years from the calculated values. Generally, maximum anomalies (ΔT > 4°C and ΔS > 0.55‰) are observed in the surface layer. Their values and statistical significance decrease with depth. However, the situation is opposite in some cases. The maximum deviation from normal was observed in June 1999, when warm and salt waters were located much further seaward from the Kunashir shelf, which is most likely connected with the Soya Current meandering.