Spectra of the Black-Sea tsunamis

We perform the analysis of the time spectra of four tsunamis generated in the Black Sea by the earthquakes of 26.07.1927, 11.09.1927, 26.12.1939, and 12.07.1966. For the analysis of the spectra, we used digitized marigrams obtained for 12 points of the Black-Sea coast. The obtained spectra are, as a rule, multimode and have 1–4 spectral maxima. One maximum corresponds to the periods typical of tsunami waves and the other maxima correspond to the oscillations of the sea level with lower frequencies. It seems likely that the events of tsunami are accompanied by low-frequency oscillations of the level caused by the atmospheric forcing, seiches, or other factors. In numerous cases, the oscillations from the predominant energy range lie outside the characteristic range of periods of the tsunami waves. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 5, pp. 21–30, September–October, 2007.     

Radiative association in Li+H revisited: the role of quasi-bound states

The role in radiative association of narrow resonances arising from quasi-bound levels is examined. For the rate coefficient the contribution from such levels is readily calculated in terms of the Einstein A -coefficient from bound rovibrational levels generated using a suitable alternative boundary condition. By locating systematically all the quasi-bound levels, an enhancement by more than an order of magnitude of the rate coefficient for Li(2s) + H(1s) association above about 600 K is obtained. The effect on the LiH abundance in the early Universe is no more than an increase of a factor of 3 for limited ranges of values of the redshift. For the Li(2p) state the effect of narrow resonances appears to have been taken into account in previous calculations.     

Flow behind an attached shock wave in a radiating gas

A simple method is used to determine the curvature of an attached shock wave and the flow variable gradients behind the shock curve at the tip of a straight-edged wedge placed symmetrically in a supersonic flow of a radiating gas near the optically thin limit. The shock curvature and the flow variable gradients along the wedge at the tip are computed for a wide range of upstream flow Mach numbers and wedge angles. Several interesting results are noted; in particular, it is found that the effect of an increase in the upstream flow Mach number or the radiative flux is to enhance the shock wave curvature which, however, decreases with an increase in the specific heat ratio or the wedge angle.     

An Upper Limit on Sunspot Activity During the Maunder Minimum

We have estimated the upper and lower limits of sunspot activity, in terms of active day fraction during the Maunder minimum (1645–1710), using raw information on individual daily observations (Hoyt and Schatten, 1998). Establishing the relation between the sunspot activity and active day fraction after 1850, we evaluate the upper limit of annual group sunspot number during the deep Maunder minimum (1645–1700) which does not exceed 4. The earlier finding of a dominant 22-year periodicity during the Maunder minimum is verified and shown to be robust. Also we confirm that the start of the Maunder minimum was very abrupt.     

Assimilation of altimetry data in the numerical model of the circulation in the Black Sea: The model numerical experiments

The numerical algorithm of the Kalman optimum filtration generalized for the case of three-dimensional fields and a multicomponent vector of the ocean state, with level measurements discrete over space and time being available, is given. The results of model numerical experiments on the assimilation of data on the Black Sea level are given. An attempt to estimate the effect of the time interval of data input on the results of field reconstruction was made.Translated by Mikhail M. Trufanov.     

Stratigraphic architecture of the fluvio-lacustrine deposits, Bathan Formation, Al-Rehaili area, North Jeddah, Saudi Arabia

A siliciclastic-dominated succession (～11 m thick) underlying Harrat Rahat, belonging to the Miocene–Pliocene Bathan Formation is recently exposed at Al-Rehaili area, North Jeddah, Saudi Arabia. It covers a wide spectrum of grain sizes varying from clay-rich mudstones to cobble grade conglomerate and consists of a variety of facies vary from fluvial to marginal and open lacustrine deposited in a half-graben basin formed along the eastern margin of the extensional Red Sea Basin. Field-based sedimentologic investigation enables to identify ten facies grouped into three facies associations (A–C). The depositional history is subdivided into two stages. The first stage represents deposition in gravel to sand-dominated fluvial system sourced from a southern source and grade northward into lacustrine delta and open lacustrine setting. The second stage on the other hand includes deposition of fluvial channels running in E–W direction with attached bank sand bar. Sequence stratigraphic interpretations of the lacustrine deposits enable to identify three unconformity-bounded sequences (SQ_1–3). The basal sequence is incomplete, consisting of three aggradationally to progradationally stacked delta plain and delta front parasequences. The second sequence is sharply and erosively overlying a red paleosol bed that defines the upper boundary of the first sequence. It includes two system tracts; upward-fining and deepening lacustrine offshore mudstones of the transgressive system tracts unconformably overlain by red paleosol of the regressive systems tracts. The top of this sequence is delineated at the sharp transgressive surface of erosion at the base of delta mouth bar deposits of sequence 3. Changes in the accommodation and sedimentation rates by basin subsidence under the influence of tectonics and sediment compaction and loading as well as climatic oscillation between semi-arid to arid conditions were the major controls on the fluvio-lacustrine sedimentation and their facies distribution. Tectonic reorganization of the drainage system resulted in the formation of E–W flowing fluvial streams in the second stage.     

Influence of the saffman force,lift force,and electric force on sand grain transport in a wind–sand flow

Quasi-horizontal trajectories of salting sand grains were found using high-speed video-recording in the desertified territory of the Astrakhan region. The sizes and displacement velocities of the saltating sand grains were determined. A piecewise logarithmic approximation of the wind profile in a quasi-stationary wind–sand flow is suggested, which is consistent with the data of observations and modeling. It was established that, in the regime of stationary saltation, the wind profile in the lower saltation layer of the wind–sand flow depends only slightly on the wind profile variations in the upper saltation layer. The vertical profiles of the horizontal wind component gradient in a quasi-stationary wind–sand flow were calculated and plotted. It was shown using high-speed video recording of the trajectory of a sand grain with an approximate diameter of 95 μm that the weightlessness condition in the desertified territory of the Astrakhan region in a stationary wind–sand flow is satisfied at a height of approximately 0.15 mm. The electric parameters of a wind–sand flow, which can provide for compensation of the force of gravity by the electric force, were estimated. In particular, if the specific charge of a sand grain is 100 μC/kg, the force of gravity applied to the sand grain can be compensated by the electric force if the vertical component of the electric field in a wind–sand flow reaches approximately 100 kV/m. It was shown that the quasi-horizontal transport of sand grains in the lower millimeter saltation layer observed in the desertified territory can be explained by the joint action of the aerodynamic drag, the force of gravity, the Saffman force, the lift force, and the electric force.     

Dissolution/precipitation kinetics of boehmite and gibbsite: Application of a pH-relaxation technique to study near-equilibrium rates

The dissolution and precipitation rates of boehmite, AlOOH, at 100.3 °C and limited precipitation kinetics of gibbsite, Al(OH)₃, at 50.0 °C were measured in neutral to basic solutions at 0.1 molal ionic strength (NaCl + NaOH + NaAl(OH)₄) near-equilibrium using a pH-jump technique with a hydrogen-electrode concentration cell. This approach allowed relatively rapid reactions to be studied from under- and over-saturation by continuous in situ pH monitoring after addition of basic or acidic titrant, respectively, to a pre-equilibrated, well-stirred suspension of the solid powder. The magnitude of each perturbation was kept small to maintain near-equilibrium conditions. For the case of boehmite, multiple pH-jumps at different starting pHs from over- and under-saturated solutions gave the same observed, first order rate constant consistent with the simple or elementary reaction: .

This relaxation technique allowed us to apply a steady-state approximation to the change in aluminum concentration within the overall principle of detailed balancing and gave a resulting mean rate constant, (2.2 ± 0.3) × 10⁻⁵ kg m⁻² s⁻¹, corresponding to a 1σ uncertainty of 15%, in good agreement with those obtained from the traditional approach of considering the rate of reaction as a function of saturation index. Using the more traditional treatment, all dissolution and precipitation data for boehmite at 100.3 °C were found to follow closely the simple rate expression:

R_net,boehmite=10^-5.485{m_OH^-}{1-exp(ΔG_r/RT)}, with R_net in units of mol m⁻² s⁻¹. This is consistent with Transition State Theory for a reversible elementary reaction that is first order in OH⁻ concentration involving a single critical activated complex. The relationship applies over the experimental ΔG_r range of 0.4–5.5 kJ mol⁻¹ for precipitation and −0.1 to −1.9 kJ mol⁻¹ for dissolution, and the pH_m ≡ −log(mH⁺) range of 6–9.6. The gibbsite precipitation data at 50 °C could also be treated adequately with the same model:R_net,gibbsite=10^-5.86{m_OH^-}{1-exp(ΔG_r/RT)}, over a more limited experimental range of ΔG_r (0.7–3.7 kJ mol⁻¹) and pH_m (8.2–9.7).     

Magma evolution and the formation of porphyry Cu–Au ore fluids: evidence from silicate and sulfide melt inclusions

Silicate and sulfide melt inclusions from the andesitic Farallón Negro Volcanic Complex in NW Argentina were analyzed by laser ablation ICPMS to track the behavior of Cu and Au during magma evolution, and to identify the processes in the source of fluids responsible for porphyry-Cu-Au mineralization at the 600 Mt Bajo de la Alumbrera deposit. The combination of silicate and sulfide melt inclusion data with previously published geological and geochemical information indicates that the source of ore metals and water was a mantle-derived mafic magma that contained approximately 6 wt.% H₂O and 200 ppm Cu. This magma and a rhyodacitic magma mixed in an upper-crustal magma chamber, feeding the volcanic systems and associated subvolcanic intrusions over 2.6 million years. Generation of the ore fluid from this magma occurred towards the end of this protracted evolution and probably involved six important steps: (1) Generation of a sulfide melt upon magma mixing in some parts of the magma chamber. (2) Partitioning of Cu and Au into the sulfide melt (enrichment factor of 10,000 for Cu) leading to Cu and Au concentrations of several wt.% or ppm, respectively. (3) A change in the tectonic regime from local extension to compression at the end of protracted volcanism. (4) Intrusion of a dacitic magma stock from the upper part of the layered magma chamber. (5) Volatile exsolution and resorption of the sulfide melt from the lower and more mafic parts of the magma chamber, generating a fluid with a Cu/Au ratio equal to that of the precursor sulfide. (6) Focused fluid transport and precipitation of the two metals in the porphyry, yielding an ore body containing Au and Cu in the proportions dictated by the magmatic fluid source. The Cu/S ratio in the sulfide melt inclusions requires that approximately 4,000 ppm sulfur is extracted from the andesitic magma upon mixing. This exceeds the solubility of sulfide or sulfate in either of the silicate melts and implies an additional source for S. The extra sulfur could be added in the form of anhydrite phenocrysts present in the rhyodacitic magma. It appears, thus, that unusually sulfur-rich, not Cu-rich magmas are the key to the formation of porphyry-type ore deposits. Our observations imply that dacitic intrusions hosting the porphyry–Cu–Au mineralization are not representative of the magma from which the ore-fluid exsolved. The source of the ore fluid is the underlying more mafic magma, and unaltered andesitic dikes emplaced immediately after ore formation are more likely to represent the magma from which the fluids were generated. At Alumbrera, these andesitic dikes carry relicts of the sulfide melt as inclusions in amphibole. Sulfide inclusions in similar dykes of other, less explored magmatic complexes may be used to predict the Au/Cu ratio of potential ore-forming fluids and the expected metal ratio in any undiscovered porphyry deposit.Editorial handling: B. Lehmann