Hydrodynamic and geochemical conditions of the formation of stratiform Zn-Pb ore mineralization by chloride solutions

Ore mineralization is formed by postsedimentary (concentrated by evaporation to stage SW2) chloride brines metamorphosed in hydrogeochemical systems that are closed with respect to CO₂, evolve according to “calcic” trend, and have high 2mCa²⁺ > mHCO ₃ ^? + 2mCO ₃ ^2? ratios. In these situations at high R/W ratios (10–100) and temperatures (100–200°C), these brines concentrate ore elements (Zn, Pb, Fe, and Mn) that are geochemical analogues of Ca. The sulfide precipitation of these elements occurs under the effect of carbonate rocks at the abiogenic sulfate reduction of S(VI) of the original brines at low Eh values, which are created in carbonate rocks at higher (>100°C) temperatures. This origin of sulfide mineralization is intensified at decreasing R/W ratios during the dilution of the original brines by elision waters and an increase in the temperature. The hydrodynamics of these ore-forming brines is controlled by the elision hydrogeological regime, which is defined in hydrogeological structures by the geostatic pressure. The brines migrate into the zones of geochemical barriers during the relaxation of hydrogeological structures toward their equilibrium hydrostatic state. Hydrogeological structures, optimal for the precipitation of ore mineralization, are hydrodynamically active and able to maintain a steady (during 10⁵-10⁶ years) inflow of ore-forming brines into the zones of geochemical barriers and the maximum number of water-exchange cycles at these barriers. Modern analogues of these structures are miogeosyncline foredeeps with Cl-Na-Ca chloride brines with high concentrations of ore elements and overall flow rates ranging from 0.n to n m³/year. Stagnate hydrogeological platform structures in hydrostatic equilibrium cannot ensure water exchange needed for ore formation, and, hence, the brines of these structures are not able to deposit the ore elements contained in them, in spite of the high concentrations of these elements.     

Age of Detrital Zircons from Sandstones of the Mesozoic Flysch Formation in the South Anyui Suture Zone (Western Chukotka)

The South Anyui fold zone (western Chukotka) is considered a suture zone related to closure of the South Anyui oceanic basin and collision of Eurasia with the Chukotka–Arctic Alaska microcontinent in the Early Cretaceous. The existence of a compensatory sedimentation basin (foredeep) during folding in the terminal Jurassic–initial Cretaceous remains debatable. This work presents first data on age estimates of detrital zircons from Upper Mesozoic terrigenous sequences of the South Anyui suture zone obtained by the fission-track method. The distal flysch of presumably Late Jurassic age and the proximal flysch of probably Late Triassic age were sampled in the Uyamkanda River basin. The fission-track dating showed that sandstones from the flysch sections contain detrital zircons of two different-age populations. Young zircon populations from sandstones of distal turbidites in the upper course of the Uyamkanda River (two samples) are 149 ± 10.2 and 155.4 ± 9.0 Ma old (Late Jurassic), whereas those from coarse-grained proximal turbidites sampled in the lower course of the Uyamkanda River (one sample) is 131.1 ± 7.5 Ma old (Early Cretaceous). The data obtained indicate that the Late Mesozoic folding in the South Anyui suture zone was accompanied by the formation of a marginal sedimentary basin. Sediments accumulated in this basin compose tectonic nappes that constitute a fold–thrust structure with the northern vergence.     

Directionality of surface high-frequency geoacoustic emission during deformational disturbances

Changes in the directionality of surface high-frequency geoacoustic emission during periods of deformational disturbances on the diurnal time scale prior to strong seismic events on Kamchatka have been investigated. It has been shown that while the emission intensity grows by over an order of magnitude, sharp maxima appear in the direction of longitudinal acoustic oscillations. Based on their position, the orientation of the major compression axis can be determined, whose chaotic motion exhibits two metastable states around the direction to the epicenter of the earthquake.     

Swelling behaviour of expansive soil treated with fly ash–GGBS based binder

In this article, the potential of a binder developed by admixing fly ash and ground granulated blast furnace slag (GGBS) to stabilise expansive soils is evaluated. Laboratory tests included determination of free swell index, swell potential and swelling pressure tests of the soil/binder mixtures at different mixing ratio. The test results showed decrease in the swelling behaviour of the soil with increase in binder content. The percent swell–time relationship was observed to fit the hyperbolic curves enabling us to predict the ultimate percent swell from few initial test results. Addition of 1% of lime to the binder showed further improvement in reducing swelling. A good linear relationship is established between percent oedometer swell and modified free swell index (MFSI) for soil/binder mixtures without lime but the same has not been observed in the presence of lime. The compressibility characteristics of the soil/binder mixtures reduced nominally with increase in binder content but in the presence of lime, the compressibility reduced significantly. Binder used in this study has been found to be effective and economic to stabilise expansive soils with lesser amount of chemical additives such as lime.     

Elasticity of tetragonal end-member majorite and solid solutions in the system Mg4Si4O12-Mg3Al2Si3O12

 The adiabatic elastic moduli of polycrystalline En₅₀Py₅₀ and En₈₀Py₂₀ majorite-garnet solid solutions (where En=4MgSiO₃, Py=Mg₃Al₂Si₃O₁₂) and the end-member En₁₀₀ tetragonal majorite were determined at ambient conditions using Brillouin spectroscopy. The adiabatic bulk modulus, K, and shear modulus, μ, of En₅₀Py₅₀ were found to be K=173.1 (20) and μ=92.3 (10) GPa, and are indistinguishable from those of the end-member pyrope, Py₁₀₀. The moduli of the more majorite-rich samples are significantly lower and are virtually identical to each other (K=162.6(11) and μ=85.7(7) for En₈₀Py₂₀; K=166(5) and μ=88(2) for En₁₀₀). In combination with previously reported moduli for this system, we conclude that both K and μ are constant over the compositional range from Py₁₀₀ to a majorite content of about 70–80%, whereupon the moduli decrease substantially. For compositions ranging from En₈₀Py₂₀ to the end-member majorite, the moduli are also approximately independent of composition, but at a lower value. An alternative model with a continuous decrease in moduli with increasing majorite content cannot be excluded, within the uncertainties of existing measurements. The contrast in moduli between aluminous pyrope garnet and Al-free majorite are small compared with the modulus changes accompanying the pyroxene – majorite phase transformation. Received August 16, 1995 /Revised, accepted January 12, 1996     

PVA-maxima and their connection to cloud systems in satellite images and to precipitation

Summary PVA-maxima can be a contributor to upward motion; there-fore cloudiness and precipitation can be expected there. This is investigated from several viewpoints: grey shade evaluations of false colour satellite images are done, frequencies of precipitation events for PVA maxima and grey shade intervals are investigated, precipitation amounts within the PVA maxima path are compared to a surroundings and the predictability from the ECMWF model is proved. Several results could be derived: PVA maxima are accompanied by brighter grey shade intervals and a higher precipitation probability than surrounding areas; for the brightest grey shade intervals a probability for precipitation of 60–70% can be stated; the path of the PVA maxima is an area of more precipitation than in the surroundings; ECMWF forecasts are able to predict the PVA maxima and their location very well but tend to underestimate the precipitation amounts on the PVA maxima path.With 9 Figures     

The Water Vapour Continuum: Brief History and Recent Developments

The water vapour continuum is characterised by absorption that varies smoothly with wavelength, from the visible to the microwave. It is present within the rotational and vibrational–rotational bands of water vapour, which consist of large numbers of narrow spectral lines, and in the many ‘windows’ between these bands. The continuum absorption in the window regions is of particular importance for the Earth’s radiation budget and for remote-sensing techniques that exploit these windows. Historically, most attention has focused on the 8–12?μm (mid-infrared) atmospheric window, where the continuum is relatively well-characterised, but there have been many fewer measurements within bands and in other window regions. In addition, the causes of the continuum remain a subject of controversy. This paper provides a brief historical overview of the development of understanding of the continuum and then reviews recent developments, with a focus on the near-infrared spectral region. Recent laboratory measurements in near-infrared windows, which reveal absorption typically an order of magnitude stronger than in widely used continuum models, are shown to have important consequences for remote-sensing techniques that use these windows for retrieving cloud properties.     

Shallow seismic refraction analysis: Application to studying the active North Sakhalin fault

Results are presented from a seismic refraction survey (P-S waves) carried out in different years on recent faults of North Sakhalin. Structural features of the near-surface zone of active faults with different types of tectonic motions and their imaging in seismic fields are demonstrated. Criteria for estimating the activity of the studied tectonic disruption are proposed.     

Late Quaternary marine terraces in the Mediterranean coastal area of Syria: Geochronology and neotectonics

In order to provide new data on the neotectonics and geodynamic properties of western Syria, studies of marine terraces have been carried out. The most attention was paid to the lower terraces in the range of 3–5 to 30–35 m above sea level, because they have more complete distributions along the shore. The lower terraces were examined along the coastal area from Tartus to Latakia, and along the carbonate cliff on Arwad Island. Seven ²³⁰Th/U dates for these terraces are in the range of 85–130 ka, suggesting the age interval of the last interglacial (MIS 5). New dates on the lower terraces provide a basis for stratigraphical and geomorphological interpretation as well as neotectonic reconstruction. According to the geomorphological data and lithological composition of those terraces, two main uplifted blocks can be established. One coincides with the Latakia block, and another corresponds to the western margin of the Banias volcanic plateau. These blocks are divided by a subsided structure corresponding to the Nahr el Kebir graben. The amplitude of neotectonic uplifting in the Latakia and Banias blocks reaches 15–20 m for the Late Pleistocene.     

On features of structure of bottom gravity current frontal zone

The results of qualitative laboratory and numerical experiments on two-dimensional non-linear model are described, aiming at an investigation of the structure of the front of bottom gravity current. Non-coincidence of frontal interfaces in density and velocity fields within the bottom gravity current leading (frontal) part is stated on the base of comparative analysis of numerical and laboratory experiments. This fact is experimentally confirmed by field example of marine water inflow into a brackish lagoon. The density gradient along the stream line is shown to be an additional effective criterion for the localization of the frontal zone.