Competing impact of anthropogenic emissions and meteorology on the distribution of trace gases over Indian region

The spatial distribution of trace gases exhibit large spatial heterogeneity over the Indian region with an elevated pollution loading over densely populated Gangetic Plains (IGP). The contending role and importance of anthropogenic emissions and meteorology in deciding the trace gases level and distribution over Indian region, however, is poorly investigated. In this paper, we use an online regional chemistry transport model (WRF/Chem) to simulate the spatial distribution of trace gases over Indian region during one representative month of only three meteorological seasons namely winter, spring/summer and monsoon. The base simulation, using anthropogenic emissions from SEAC⁴RS inventory, is used to simulate the general meteorological conditions and the realistic spatial distribution of trace gases. A sensitivity simulation is conducted after removing the spatial heterogeneity in the anthropogenic emissions, i.e., with spatially uniform emissions to decouple the role of anthropogenic emissions and meteorology and their role in controlling the distribution of trace gases over India. The concentration levels of Ozone, CO, SO₂ and NO₂ were found to be lower over IGP when the emissions are uniform over India. A comparison of the base run with the sensitivity run highlights that meteorology plays a dominant role in controlling the spatial distribution of relatively longer-lived species like CO and secondary species like Ozone while short-lived species like NO_X and SO₂ are predominantly controlled by the spatial variability in anthropogenic emissions over the Indian region.     

Subject Index

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Subject Index     

Analytical model for screening potential CO<Subscript>2</Subscript> repositories

Assessing potential repositories for geologic sequestration of carbon dioxide using numerical models can be complicated, costly, and time-consuming, especially when faced with the challenge of selecting a repository from a multitude of potential repositories. This paper presents a set of simple analytical equations (model), based on the work of previous researchers, that could be used to evaluate the suitability of candidate repositories for subsurface sequestration of carbon dioxide. We considered the injection of carbon dioxide at a constant rate into a confined saline aquifer via a fully perforated vertical injection well. The validity of the analytical model was assessed via comparison with the TOUGH2 numerical model. The metrics used in comparing the two models include (1) spatial variations in formation pressure and (2) vertically integrated brine saturation profile. The analytical model and TOUGH2 show excellent agreement in their results when similar input conditions and assumptions are applied in both. The analytical model neglects capillary pressure and the pressure dependence of fluid properties. However, simulations in TOUGH2 indicate that little error is introduced by these simplifications. Sensitivity studies indicate that the agreement between the analytical model and TOUGH2 depends strongly on (1) the residual brine saturation, (2) the difference in density between carbon dioxide and resident brine (buoyancy), and (3) the relationship between relative permeability and brine saturation. The results achieved suggest that the analytical model is valid when the relationship between relative permeability and brine saturation is linear or quasi-linear and when the irreducible saturation of brine is zero or very small.     

A modified mix-differenced approach for estimating multi-GNSS real-time satellite clock offsets

A modified mixed-differenced approach for estimating multi-GNSS real-time clock offsets is presented. This approach, as compared to the earlier presented mixed-differenced approach which uses epoch-differenced and undifferenced observations, further adds a satellite-differenced process. The proposed approach, based on real-time orbit products and a mix of epoch-differenced and satellite-differenced observations to estimate only satellite clock offsets and tropospheric zenith wet delays, has fewer estimated parameters than other approaches, and thus its implementing procedure is efficient and can be performed and extended easily. To obtain high accuracy, the approach involves three steps. First, the high-accuracy tropospheric zenith wet delay of each station is estimated using mixed-differenced carrier phase observations. Second, satellite clock offset changes between adjacent epochs are estimated using also mixed-differenced carrier phase observations. Third, the satellite clock offsets at the initial epoch are estimated using satellite-differenced pseudorange observations. Finally, the initial epoch clock results and clock offset changes are concatenated to obtain the clock results of the current epoch. To validate the real-time satellite clock results, multi-GNSS post-processing clock products from IGS ACs were selected for comparison. From the comparison, the standard deviations of the GPS, GLONASS, BeiDou and Galileo systems clock results are approximately 0.1–0.4 ns, except for the BeiDou GEO satellites. The root mean squares are about 0.4–2.3 ns, which are similar to those of other international real-time products. When the clock estimates were assessed based on a pseudo-kinematic PPP procedure, the positioning accuracies in the East, North and Up components reach 5.6, 5.5 and 7.6 cm, respectively, which meet the centimeter level and are comparable to the application of other products.     

On the topographic bias in geoid determination by the external gravity field

The topographic bias is defined as the error/bias committed by continuing the external gravity field inside the topographic masses by a harmonic function. We study the topographic bias given by a digital terrain model defined by a spherical template, and we show that the topographic bias is given only by the potential of an inner-zone cap, and it equals the bias of the Bouguer shell, independent of the size of the cap. Then we study the effect on the real Earth by decomposing its topography into a template, and we show also in this case that the topographic bias is that of the Bouguer shell, independent of the shape of the terrain. Finally, we show that the topographic potential of the terrain at the geoid can be determined to any precision by a Taylor expansion outside the Earth’s surface. The last statement is demonstrated by a Taylor expansion to fourth order.     

Spatial inhomogeneity of variations in the <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript> layer critical frequencies under the conditions of winter 1995

The daily samples of the hourly measurements of the foF2 critical frequency, obtained on January 5–21, 1995, at the midlatitude and high-latitude automated ionospheric stations (geographic latitude higher than 60°), are considered. The {fo} sets are transformed into the {δfoF2} sets of relative variations, for which asymmetry (A) and excess (E) are calculated. The selected stations are grouped into 20 pairs of automated ionospheric stations (AISs) located at distances of 200–10 000 km from one another. Sign estimates of the cross-correlation coefficients between the sets of 16 A and E values for different pairs of stations are used. Two types of structures of the statistical invariant spatial distribution are established: the structures with a scale of about 300 km, invariant with respect to latitude, and with a scale of about 6000 km (for only high latitudes).     

Lidar observations and formation mechanism of the structure of stratospheric and mesospheric aerosol layers over Kamchatka

Lidar observations during 2007–2008 in Kamchatka revealed aerosol layers in the upper stratosphere at heights of 35–50 km and in the mesosphere at heights of 60–75 km. It is well known that forces of gas-kinetic nature, i.e., photophoretic forces, act on aerosol particles that absorb solar radiation and terrestrial IR radiation; these forces can counteract the gravitational force and even lead to the levitation of these particles at particular heights. The accumulation of particles at these heights may lead to the formation of aerosol layers. We calculated these forces for the conditions of lidar observations in Kamchatka. Aerosol layers were observed at heights where particle levitation can occur. Thus, the stratospheric and mesospheric aerosol layers, detected at heights of 30–50 and 60–75 km, respectively, may be due to the effect of the photophoretic force on aerosol particles.     

The particle background of the <Emphasis Type="Italic">X-IFU</Emphasis> instrument

In this paper we are going to review the latest estimates for the particle background expected on the X-IFU instrument onboard of the ATHENA mission. The particle background is induced by two different particle populations: the so called “soft protons” and the Cosmic rays. The first component is composed of low energy particles (< 100s keV) that get funnelled by the mirrors towards the focal plane, losing part of their energy inside the filters and inducing background counts inside the instrument sensitivity band. The latter component is induced by high energy particles (> 100 MeV) that possess enough energy to cross the spacecraft and reach the detector from any direction, depositing a small fraction of their energy inside the instrument. Both these components are estimated using Monte Carlo simulations and the latest results are presented here.     

Strange quark matter attached to string cloud in Bianchi type-III space time

We have obtained Bianchi type-III cosmological model with strange quark matter attached to the string cloud in general relativity. For solving the Einstein’s field equations the relation [C=A ⁿ ] between metric coefficients C and A is used. Also, some physical and kinematic properties of the model are discussed.The results are analogous to results obtained by Yilmaz (Gen. Rel. Grav. 38:1397–1406, 2006).