Iodine-rich waters involved in supergene enrichment of the Mantos de la Luna argentiferous copper deposit,Atacama Desert,Chile

Recent studies have suggested the involvement of highly saline deep formation waters that modified preexisting Cu assemblages to form atacamite during supergene oxidation of Cu deposits in the Atacama region. In this report, we document the occurrence of (Ag–I) inclusions hosted by supergene chalcocite from Mantos de la Luna, an argentiferous Upper Jurassic stratabound Cu deposit in the Coastal Range of northern Chile. The presence of this unusual mineral assemblage indicates that iodargyrite precipitated from reducing iodine-rich waters, suggesting that the fluids involved in supergene enrichment of Cu deposits in the Coastal Range were more complex than previously thought. This suggests the prevalence of hyperarid conditions during the latest stages of supergene enrichment of the Mantos de la Luna Cu deposit in the Atacama region, supporting the notion that supergene enrichment processes in hyperarid areas are dynamic in nature and do not exclusively require the presence of meteoric water.     

A high‐resolution pollen and geochemical analysis of late Holocene human impact and vegetation history in southern Cumbria,England

The historic era, which in Cumbria begins with the Roman invasion of AD 71, is a frequently neglected period in palaeoecological research, but its study can bring benefits in improving knowledge of landscape history and in understanding the significance and limitations of palaeoecological records. Pollen and geochemical data are presented for late Holocene records from Deer Dyke and Hulleter Mosses in southern Cumbria. The records show initially low levels of anthropogenic impact, followed by a phase of forest clearance and mixed agriculture from the 7th to 11th centuries AD. The timing of these clearances suggests that they were initially Anglo‐Saxon in origin, rather than Norse. Further clearances in the 16th century AD are interpreted as a response to monastic dissolution and late Tudor population pressures; the landscapes reached their contemporary form following extensive clearances in the 17th century AD. Silicon and titanium concentrations at Deer Dyke Moss were used to reconstruct past levels of atmospheric dust loading, which is broadly related to soil erosion. Geochemical influx was found to peak during periods of landscape transition rather than from established land use. This relationship with pollen data is thought to reflect the predominantly low levels of anthropogenic impact in the region, which changes as substantial woodland clearances during the 16th century AD and continuous land use pressure since then have greatly increased the supply of airborne dust. Copyright © 2008 John Wiley & Sons, Ltd.     

Bottom microtopography as a factor responsible for variations in the thickness of the Turonian-Coniacian sequence in the Melovoe-Nizhnyaya Bannovka area (Saratov Region)

The Turonian-Coniacian carbonate sequence outcropping in the Melovoe-Nizhnyaya Bannovka area (Saratov region) is described along with the characterization of its geomorphologic, sedimentologic, and sequence-stratigraphy aspects and accompanying isopach maps. A sedimentation model is proposed for explaining factors responsible for variations in the thickness of the sequence.     

Hydrogeology and sustainable future groundwater abstraction from the Agua Verde aquifer in the Atacama Desert,northern Chile

The hyper-arid conditions prevailing in Agua Verde aquifer in northern Chile make this system the most important water source for nearby towns and mining industries. Due to the growing demand for water in this region, recharge is investigated along with the impact of intense pumping activity in this aquifer. A conceptual model of the hydrogeological system is developed and implemented into a two-dimensional groundwater-flow numerical model. To assess the impact of climate change and groundwater extraction, several scenarios are simulated considering variations in both aquifer recharge and withdrawals. The estimated average groundwater lateral recharge from Precordillera (pre-mountain range) is about 4,482 m³/day. The scenarios that consider an increase of water withdrawal show a non-sustainable groundwater consumption leading to an over-exploitation of the resource, because the outflows surpasses inflows, causing storage depletion. The greater the depletion, the larger the impact of recharge reduction caused by the considered future climate change. This result indicates that the combined effects of such factors may have a severe impact on groundwater availability as found in other groundwater-dependent regions located in arid environments. Furthermore, the scenarios that consider a reduction of the extraction flow rate show that it may be possible to partially alleviate the damage already caused to the aquifer by the continuous extractions since 1974, and it can partially counteract climate change impacts on future groundwater availability caused by a decrease in precipitation (and so in recharge), if the desalination plant in Taltal increases its capacity.     

Comparison between cell-centered and nodal-based discretization schemes for linear elasticity

In this paper, we study newly developed methods for linear elasticity on polyhedral meshes. Our emphasis is on applications of the methods to geological models. Models of subsurface, and in particular sedimentary rocks, naturally lead to general polyhedral meshes. Numerical methods which can directly handle such representation are highly desirable. Many of the numerical challenges in simulation of subsurface applications come from the lack of robustness and accuracy of numerical methods in the case of highly distorted grids. In this paper, we investigate and compare the Multi-Point Stress Approximation (MPSA) and the Virtual Element Method (VEM) with regard to grid features that are frequently seen in geological models and likely to lead to a lack of accuracy of the methods. In particular, we look at how the methods perform near the incompressible limit. This work shows that both methods are promising for flexible modeling of subsurface mechanics.     

A simple approach to evaluating leakage through thin impervious element of high embankment dams

Internal erosion is the most common reason which induces failure of embankment dams besides overtopping. Relatively large leakage is frequently concentrated at defects of impervious element, and this will lead to eventual failure. The amount of leakage depends not only on integrity of impervious element, but also on dam height, shape of valley, shape of impervious element and water level in reservoir. The integrity of impervious element, which represents the relative level of seepage safety, is not easy to be determined quantitatively. A simple method for generalization of steady seepage state of embankment dams with thin impervious element is proposed in this paper. The apparent overall value of permeability coefficient for impervious element can be obtained by this method with reasonable accuracy and efficiency. A defect parameter of impervious element is defined as an index to characterize seepage safety of embankment dams. It equals the ratio of the apparent overall value of permeability coefficient to the measured value in laboratory for intact materials. Subsequently, seepage safety of three dams is evaluated and the evolution of defect level of impervious element of dams is investigated. It is proved that the newly proposed method in this paper is feasible in the evaluation of relative seepage safety level of embankment dams with thin impervious element.     

Metal island growth and dynamics on molybdenite surfaces

In order to understand the adsorption mechanism of metal atoms to semiconducting surfaces, we have studied, as a model system, the vapor phase adsorption of Ag, Au, and Cu on the (001) surface of molybdenite (MoS₂) and the subsequent surface diffusion of these adsorbates. Our scanning tunneling microscopy (STM) images show that, depending on the type of metal atom that is adsorbed, islands of a characteristic size (2 nm for Ag, 8 to 10 nm for Cu, two distinct sizes of 2 nm and 8 to 10 nm for Au), shape (well rounded in the lateral extension) and thickness (one monolayer for Ag, 1 to 1.5 nm for Cu) are formed during the initial stages of deposition. Whole islands are observed to surface diffuse without loss of size or shape. Despite the relatively large size of the copper islands on molybdenite, these islands surface diffuse extensively, suggesting that the Cu-S interaction is weak. Surface diffusion is only hindered once individual islands start to coalesce. As copper islands accumulate, the size and shape of the original islands can still be recognized, supporting the conclusion that these characteristics are constant and that monolayer growth occurs by the aggregation of islands across the surface.The strength and the nature of the Ag-S(MoS₂) bond were further investigated by using molecular orbital calculations, ultraviolet photoelectron spectroscopy (UPS) and scanning tunneling spectroscopy (STS). By applying quantum mechanical approaches using a two-dimensional periodic molybdenite slab and hexagonal MoS₂ clusters of different sizes with metal atoms adsorbed to them, it is possible to calculate the electron transfer between the mineral surface and the metal atom as well as the adsorption energy as a function of surface coverage. In addition, we used the results from the quantum mechanical runs to derive empirical potentials that model the characteristics of the forces within the crystal, within the adsorbed islands, and the metal and mineral surface. The combination of quantum mechanical calculations and empirical force field calculations explain the electronic structure and the highest stability of Ag islands that have seven atoms in diameter, which exactly agrees with the size of experimentally observed islands. UPS results also suggest that a specific new state is formed (approximately 4.5 eV into the valence band) which may describe the Ag-S bond because it does not occur in pure silver or molybdenite.This study shows how the combination of microscopic (STM), spectroscopic (STS, UPS), compositional (X-ray photoelectron spectroscopy, XPS) and molecular modeling (quantum mechanical and empirical) techniques is a useful approach to understand the nature of the metal to sulfide bond. Further insights may be gained concerning the natural association of certain metals with sulfides.     

Chlorine variations in the magma of Soufrière Hills Volcano, Montserrat: Insights from Cl in hornblende and melt inclusions

The Soufrière Hills Volcano in Montserrat erupts a Cl-rich, porphyritic andesite. HCl degassing accompanies eruption and is dependent on the growth rate of the lava dome. The magma contains hornblende phenocrysts that show repetitive zoning in most elements, including Cl. On the basis of the zoning data, (Cl/OH) ratios in the melt, calculated from partitioning data, increase rimward through each zone, indicating that the phenocrysts formed under conditions of varying (Cl/OH)_m. An empirical relationship between A-site occupancy in the hornblende and temperature implies that crystallisation of each zone is also accompanied by increasing temperature. Each zone ends at a resorption horizon, and crystallisation recommences at lower temperature and (Cl/OH)_m. Melt inclusion H₂O and Cl contents for the 8th January 2007 explosive eruption can be explained by closed-system degassing with D_Cl^fl-m between 5 and 30, or by open-system degassing accompanied by a small amount of crystallisation. However, neither simple closed-system degassing nor convective circulation of magma can explain the positive correlation of (Cl/OH)_m with temperature. We suggest that the zoning can be caused by accumulation of CO₂-rich vapour in the andesite, probably as a result of mafic magma injection into the chamber. Decreasing H₂O fugacity and/or increasing Cl_m result in increasing (Cl/OH)_m while heat transferred with the volatiles causes the rise in temperature. Intermittently, the accumulated fluid is lost to the surface, possibly as a result of renewed eruptive activity. This model requires the CO₂-rich fluid to be decoupled from the magma, consistent with previous observations of continuous CO₂ emissions at the surface.     

Crystal fractionation and partial melting in the petrogenesis of a Proterozoic high-MgO volcanic suite,Ungava, Québec

There is little concensus on the relative importance of crystal fractionation and differential partial melting to the chemical diversity observed within most types of volcanic suites. A resolution to this controversy is best sought in suites containing high MgO lavas such as the Chukotat volcanics of the Proterozoic Cape Smith foldbelt, Ungava, Quebec. The succession of this volcanic suite consists of repetitive sequences, each beginning with olivine-phyric basalt (19-12 wt% MgO), grading upwards to pyroxene-phyric basalt (12-8 wt% MgO) and then, in later sequences, to plagioclase-phyric basalt (7-4 wt% MgO). Only the olivine-phyric basalts have compositions capable of equilibrating with the upper mantle and are believed to represent parental magmas for the suite. The pyroxene-phyric and plagioclase-phyric basalts represent magmas derived from these parents by the crystal fractionation of olivine, with minor chromite, clinopyroxene and plagioclase. The order of extrusion in each volcanic sequence is interpreted to reflect a density effect in which successively lighter, more evolved magmas are erupted as hydrostatic pressure wanes. The pyroxene-phyric basalts appear to have evolved at high levels in the active part of the conduit system as the eruption of their parents was in progress. The plagioclase-phyric basalts may represent residual liquids expelled from isolated reservoirs along the crust-mantle interface during the late stages of volcanic activity.A positive correlation between FeO and MgO in the early, most basic olivine-phyric basalts is interpreted to reflect progressive adiabatic partial melting in the upper mantle. Although this complicates the chemistry, it is not a significant factor in the compositional diversification of the volcanic suite. The preservation of such compositional melting effects, however, suggests that the most basic olivine-phyric basalts represent primitive magmas. The trace element characteristics of these magmas, and their derivatives, indicate that the mantle source for the Chukotat volcanics had experienced a previous melting event.