Weathering process at the natural fission reactor of Bangombé

 The uranium deposits in the basin of Franceville (Gabon) host the only natural fission reactors known in the world. Unique geological conditions favoured a natural fission reaction 2 Ga ago. This was detected by anomalous isotopic compositions of uranium and rare earth elements (REE), which are produced by the fission reaction. In total, 16 reactor zones were found. Most of them are mined out. The reactor zone of Bangombé, is only 10–11 m below the surface. This site has been influenced by surface weathering processes. Six drill cores have been sampled at the site of the reactor zone of Bangombé during the course of the study and only one drill core (BAX 08) hit the core of the reactor. From these data and previous drilling campaigns, the reactor size is estimated to be 10 cm thick, 2–3 m wide and 4–6 m long. The migration of fission products can be traced by the anomalous isotope ratios of REE because of the fission process. The ¹⁴⁹Sm/¹⁴⁷Sm ratio close to the reactor zone is only 0.28 (normal: 0.92) because of the intense neutron capture of ¹⁴⁹Sm and subsequent transmutation, whereas ¹⁴⁷Sm is enriched by the fission reaction. Similar changes in isotopic patterns are detectable on other REE. The isotope ratios of Sm and Nd of whole rock and fracture samples surrounding the reactor indicate that fission-genic REE migrated only a few decimetres above and mainly below the reactor zone. Organic matter (bitumen) seems to act as a trap for fission-genic REE. Additional REE-patterns show less intense weathering with increasing depth in the log profile and support a simple weathering model. Received: 26 November 1999 · Accepted: 2 May 2000     

Characterization of soil's structural crust by spectral reflectance in the SWIR region (1.2–2.5 μm)

Structural crust is a thin layer formed on the soil surface after a rainstorm. The crust is the result of a physical segregation and rearrangement of soil particles in a way that affects some of the soil properties, such as infiltration, runoff and soil erosion. In practice, there is no rapid, in situ method for monitoring, assessing and mapping crust intensity and quality. In this study, a controlled spectral investigation of the structural crust across the NIR–SWIR spectral region was conducted on three selected Israeli soils, to study the potential of reflectance radiation to detect structural crust in soils. Two major factors served as the driving forces for this study: (1) there is no valid method for in situ assessment of the crust's characteristics in the agriculture field, and (2) the crust might bias thematic remote sensing of soils, because the thin layer of crust blocks photon–matter interaction, which represents the relevant soil body. Through the use of a laboratory rainfall simulator and a sensitive spectrometer, it was revealed that for three selected soils, significant spectral differences occurred between the crust and its bulk soil. The spectral information was found to be related to changes in particle size distribution and texture at the surface of the soil. This conclusion was based on indications of absorption of OH in clay lattice, OH in adsorbed water and CO₃ in carbonates. It was concluded that the structural crust is a phenomenon that should not be ignored by remote-sensing users. In fact, in the field of agriculture, the spectral properties of crust can be used as tools for estimating the crust's intensity.     

Relationships between Campi Flegrei and Mt. Somma volcanism: evidence from melt inclusions in clinopyroxene phenocrysts from volcanic breccia xenoliths

Summary We present compositions of reheated melt inclusions in clinopyroxene phenocrysts from three mafic xenoliths in Breccia Museo, Campi Flegrei, Italy. Melt inclusion compositions are remarkably different from the compositions of known contemporary Campi Flegrei lavas, being significantly enriched in K₂O and depleted in Na₂O. Some differences are also evident in FeO^* (total Fe as FeO) and TiO₂ contents. The clinopyroxene phenocrysts could not have crystallised from Campi Flegrei magmas. We suggest that they originated from a volcanic system genetically very similar to, and possibly linked with, the >14 ka volcanic system of Mt. Somma, another Campanian volcano ∼ 30 km east from Campi Flegrei, from which Vesuvius subsequently developed. This result indicates a close relationship (or link) between the two volcanic systems which have until now been considered separate. We speculate that the link was established prior to eruption of the Neapolitan Yellow Tuff (NYT) (∼ 12 ka). The xenoliths were derived from a volcanic system older than the host breccias themselves. We suggest that this older volcanism had close similarities with the volcanism of the older products of Mt. Somma (∼25 ka). Received March 20, 2000; accepted November 2, 2000     

Pre-collisional high pressure metamorphism and nappe tectonics at active continental margins: a numerical simulation

The evolution of a subduction channel and orogenic wedge is simulated in 2D for an active continental margin, with P-T paths being displayed for selected markers. In our simulation, subduction erosion affects the active margin and a structural pattern develops within a few tens of millions of years, with four zones from the trench into the forearc: (i) an accretionary complex of low grade metamorphic sedimentary material, (ii) a wedge of nappes with alternating upper and lower crustal provenance, and minor interleaving of oceanic or hydrated mantle material, (iii) a megascale melange composed of high pressure (HP) and ultra-high pressure (UHP) metamorphic rocks extruded from the subduction channel, and (iv) the upward tilted frontal part of the remaining lid. The P–T paths and time scales correspond to those typically recorded in orogenic belts. The simulation shows that HP/UHP metamorphism of continental crust does not necessarily indicate collision, but that the material can be derived from the active margin by subduction erosion and extruded from the subduction channel beneath the forearc during ongoing subduction.     

Deep-ocean vertical noise directionality

The structure of beam noise measured at the output of a vertical array in a range dependent ocean basin was investigated using the modified wide-angle parabolic equation (PE). Noise sources were distributed throughout the basin, and the field due to each noise source at an array located in the midbasin was calculated. The response of the array to the superposition of the noise sources was found by beamforming. An efficient and direct approach that superimposes the noise sources on the PE field as the field is marched toward the array was developed. Downslope calculations of the midbasin vertical directionality were made between 50 and 400 Hz with this technique. Use of a geoacoustic model shows that the bottom behaves as a low-pass filter     

Depositional and post‐depositional history of warm stage deposits at Knocknacran,Co. Monaghan,Ireland: implications for preservation of Irish last interglacial deposits

Organic‐rich deposits, uncovered during overburden removal from mantled gypsum karst at Knocknacran opencast gypsum mine, Co. Monaghan, are the best candidate to date for a last interglacial record in Ireland. The two till and organic‐rich deposits (preserved at different quarry elevations) were emplaced on to a Tertiary dolerite surface during high‐energy flood events and subsequently folded and faulted by movement towards sinkholes in underlying gypsum. Uranium–thorium disequilibrium dating suggests that the organic‐rich deposits in the upper section were hydrologically isolated at ca. 41 ka and those in the lower section at ca. 86 ka. Interpretation of the pollen content, although tentative because of the depositional and post‐depositional history of the material, suggests that the organic material originated in a warm stage possibly warmer than the post‐Eemian interstadials. The unusual setting of preservation may indicate that in situ, last interglacial deposits have generally been removed by erosion in Ireland. Copyright © 2004 John Wiley & Sons, Ltd.     

Slumping and shallow faulting related to the presence of salt on the Continental Slope and Rise off North Carolina

Seismic reflection profiles and long- and medium-range sidescan sonar were used to investigate a salt diapir complex and area of slope instability near the base of the Continental Slope off North Carolina. Within the area of investigation three diapirs are bounded on their upslope side by a scarp 60 m high and 50 km long. The slope above the scarp is characterized by a series of shallow rotational normal faults. The bottom below the scarp is furrowed by slide tracks, which were probably carved by large blocks that broke off the scarp face and slid downslope leaving rubble and scree lobes.Extensive slumping in this area appears to be a result of uplift and faulting associated with salt intrusion, which has fractured and oversteepened the slope leading to instability and failure. Sharply defined slide tracks suggest that slope failure above the breached diapir complex is a continuing process, in contrast to much of the surrounding slope area where few instability features were observed.